A pre-processing electrodialysis process for adjusting the proportion of constituents of mixed salt electrolytes for the production of various chemicals, or for facilitating precipitation through passing the feed through an electrodialysis cell operated with a relatively small salinity step increase, resulting in changed proportionality of constituent anions and cations in the dilute product or the concentrate product.
C22B 3/22 - Traitement ou purification de solutions, p. ex. de solutions obtenues par lixiviation par des procédés physiques, p. ex. par filtration, par des moyens magnétiques
A pre-processing electrodialysis process for adjusting the proportion of constituents of mixed salt electrolytes for the production of various chemicals, or for facilitating precipitation through passing the feed through an electrodialysis cell operated with a relatively small salinity step increase, resulting in changed proportionality of constituent anions and cations in the dilute product or the concentrate product.
C22B 3/22 - Traitement ou purification de solutions, p. ex. de solutions obtenues par lixiviation par des procédés physiques, p. ex. par filtration, par des moyens magnétiques
An improved spacer for use in electrodialysis and electrodeionization stacks can provide close contact between the spacer mesh and its adjacent ion exchange membranes, reducing the water flow cross-section through the cell. This in turn can lead to higher flow velocities and increased flow turbulence between ion exchange membranes, thereby reducing membrane polarization effects and increasing the limiting current density. The improved spacer can be combined with a voluminous spacer gasket for receiving a volume of electroactive media, the voluminous spacer gasket comprising an outer gasket edge having an open central area for receiving the electroactive media, and holes on the top and bottom of the outer gasket edge whose dimensions match the holes on the spacer.
An improved spacer for use in electrodialysis and electrodeionization stacks can provide close contact between the spacer mesh and its adjacent ion exchange membranes, reducing the water flow cross-section through the cell. This in turn can lead to higher flow velocities and increased flow turbulence between ion exchange membranes, thereby reducing membrane polarization effects and increasing the limiting current density. The improved spacer can be combined with a voluminous spacer gasket for receiving a volume of electroactive media, the voluminous spacer gasket comprising an outer gasket edge having an open central area for receiving the electroactive media, and holes on the top and bottom of the outer gasket edge whose dimensions match the holes on the spacer.
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
Non-gas emitting electrodes having a very high surface area, high electric capacitance, and low electric resistance are integrated with silver and/or silver chloride for use in electrodialysis/electrodeionization cells, or in any other system requiring the generation of electric fields through electrolyte solutions, and are capable generating an electric field for extensive periods of time without generation of gases, and without the occurrence of electrode reactions. Each electrode is highly porous and highly conductive, such as a carbon aerogel electrode, and thus has a very large internal surface area, which is coated, deposited, or otherwise covered with silver and/or silver chloride. This combination supercapacitor and pseudocapacitor electrode can sustain electrode reactions for longer periods of time, and at much higher current densities, as compared to conventional (solid) silver/silver chloride electrodes.
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
C23C 18/08 - Revêtement chimique par décomposition soit de composés liquides, soit de solutions des composés constituant le revêtement, ne laissant pas de produits de réaction du matériau de la surface dans le revêtementDépôt par contact par décomposition thermique caractérisée par le dépôt d'un matériau métallique
H01G 11/86 - Procédés de fabrication de condensateurs hybrides ou EDL ou de leurs composants spécialement adaptés pour les électrodes
An improved spacer and a process for the manufacture thereof for use in electrodialysis and electrodeionization stacks. The spacer can provide reduced leakage and improved sealing between stack compartments, as well as reduced output product loss and reduced energy consumption per unit volume of output product.
An improved spacer and a process for the manufacture thereof for use in electrodialysis and electrodeionization stacks. The spacer can provide reduced leakage and improved sealing between stack compartments, as well as reduced output product loss and reduced energy consumption per unit volume of output product.
C02F 1/461 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par électrolyse
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
8.
Non-gas-emitting electrodes for use in electrodialysis and electrodionization desalination systems
Non-gas emitting electrodes having a very high surface area, high electric capacitance, and low electric resistance are integrated with silver and/or silver chloride for use in electrodialysis/electrodeionization cells, or in any other system requiring the generation of electric fields through electrolyte solutions, and are capable of generating an electric field for extensive periods of time without generation of gases, and without the occurrence of water splitting electrode reactions. Each electrode is highly porous and highly conductive, such as a carbon aerogel electrode, and thus has a very large internal surface area, which is infused with silver and/or silver chloride. This combination supercapacitor and pseudocapacitor electrode can sustain electrode reactions for longer periods of time, and at much higher current densities, as compared to conventional (solid) silver/silver chloride electrodes.
B01D 61/48 - Appareils à cet effet ayant un ou plusieurs compartiments remplis d'un matériau échangeur d'ions
C23C 18/08 - Revêtement chimique par décomposition soit de composés liquides, soit de solutions des composés constituant le revêtement, ne laissant pas de produits de réaction du matériau de la surface dans le revêtementDépôt par contact par décomposition thermique caractérisée par le dépôt d'un matériau métallique
C25D 3/46 - Dépôt électrochimiqueBains utilisés à partir de solutions d'argent
C25D 7/00 - Dépôt électrochimique caractérisé par l'objet à revêtir
9.
PROCESS AND APPARATUS FOR HIGH RECOVERY IN ELECTRODIALYSIS AND ELECTRODEIONIZATION SYSTEMS
Electrodeionization and electrodialysis systems which eliminate or substantially prevent the feed water from entering the concentrating compartments, for improving the recovery of product water as well as improving the current efficiency. Electro-osmotically generated flows of water entering from the diluting compartments of the stack constitutes the majority of concentrate feed, leading to the production of high purity, desalinated waters in the diluting compartments and highly concentrate solutions in the concentrate compartments.
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
10.
PROCESS AND APPARATUS FOR HIGH RECOVERY IN ELECTRODIALYSIS AND ELECTRODEIONIZATION SYSTEMS
Electrodeionization and electrodialysis systems which eliminate or substantially prevent the feed water from entering the concentrating compartments, for improving the recovery of product water as well as improving the current efficiency. Electro-osmotically generated flows of water entering from the diluting compartments of the stack constitutes the majority of concentrate feed, leading to the production of high purity, desalinated waters in the diluting compartments and highly concentrate solutions in the concentrate compartments.
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
A device and process for the separate removal of oppositely charged ions from electrolyte solutions and recombining them to form new chemical compositions. The invention provides the ability to create multiple ion flow channels and then form new chemical compositions therefrom. The process is accomplished by selectively combining oppositely charged ions of choice from different electrolyte solutions via the capacitive behavior of high electrical capacitance electrodes confined in insulated containers. Industrial plants employing the inventive process can have the flexibility to produce needed industrial chemical compounds such as Soda Ash, Caustic Soda, hydrochloric acid and chlorine gas, based on market demand, and can be located near points of consumption to significantly reduce transportation costs.
C25B 9/23 - Cellules comprenant des électrodes fixes de dimensions stablesAssemblages de leurs éléments de structure avec des diaphragmes comprenant des membranes échangeuses d'ions dans ou sur lesquelles est incrusté du matériau pour électrode
C25B 9/70 - Assemblages comprenant plusieurs cellules
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
12.
CAPACITIVE ELECTROKINETIC DEWATERING OF SUSPENSIONS
Capacitive electrokinetic densification, decontamination and dewatering of suspensions and soils can be performed while controlling and/or preventing chemical and pH changes in the densified material and extracted water. High electrical capacitance electrodes or Electric Double Layer Capacitor (EDLC) electrodes are used which can operate without redox reactions occurring on their surfaces until their developed voltage reaches the standard electrode potential of the electrode. Water-retaining, flexible covers for the EDLC electrodes have drainage and filtering capabilities and are made of a fabric which allows the passage of ions, water and electricity therethrough and facilitate continuous electrical contact between the EDLC electrode and the surrounding suspension.
C02F 1/46 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
13.
PROCESS AND APPARATUS FOR OSMOTIC FLOW CONTROL IN ELECTRODIALYSIS SYSTEMS
An electrodialysis process and apparatus is presented for improving the current efficiency of salty water desalination. The process includes reducing the osmotic and the electro-osmotic flow of water from diluate compartments to concentrate compartments, and between electrode compartments and adjacent compartments, by confinement and hydraulic isolation of their contents in constant volume compartments, so that the tendency of waters entering from diluate compartments to concentrate compartments leads to pressure buildup in the concentrate compartments, reducing the transfer of product desalinated water to the concentrate waste.
An electrodialysis process and apparatus is presented for improving the current efficiency of salty water desalination. The process includes reducing the osmotic and the electro-osmotic flow of water from diluate compartments to concentrate compartments, and between electrode compartments and adjacent compartments, by confinement and hydraulic isolation of their contents in constant volume compartments, so that the tendency of waters entering from diluate compartments to concentrate compartments leads to pressure buildup in the concentrate compartments, reducing the transfer of product desalinated water to the concentrate waste.
B01D 69/00 - Membranes semi-perméables destinées aux procédés ou aux appareils de séparation, caractérisées par leur forme, leur structure ou leurs propriétésProcédés spécialement adaptés à leur fabrication
15.
Process and apparatus for osmotic flow control in electrodialysis systems
An electrodialysis process and apparatus is presented for improving the current efficiency of salty water desalination. The process includes reducing the osmotic and the electro-osmotic flow of water from diluate compartments to concentrate compartments, and between electrode compartments and adjacent compartments, by confinement and hydraulic isolation of their contents in constant volume compartments, so that the tendency of waters entering from diluate compartments to concentrate compartments leads to pressure buildup in the concentrate compartments, reducing the transfer of product desalinated water to the concentrate waste.
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
A device and process are disclosed for the separate removal of oppositely charged ions from electrolyte solutions and recombining them to form new chemical compositions. The invention provides the ability to create multiple ion flow channels and then form new chemical compositions therefrom. The process is accomplished by selectively combining oppositely charged ions of choice from different electrolyte solutions via the capacitive behavior of high electrical capacitance electrodes confined in insulated containers.
B01D 57/00 - Séparation, autre que la séparation de solides, non entièrement couverte par un seul groupe ou sous-classe, p. ex.
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
C25B 1/00 - Production électrolytique de composés inorganiques ou de non-métaux
A device and process are disclosed for the separate removal of oppositely charged ions from electrolyte solutions and recombining them to form new chemical compositions. The invention provides the ability to create multiple ion flow channels and then form new chemical compositions therefrom. The process is accomplished by selectively combining oppositely charged ions of choice from different electrolyte solutions via the capacitive behavior of high electrical capacitance electrodes confined in insulated containers.
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
C25B 1/00 - Production électrolytique de composés inorganiques ou de non-métaux
An apparatus and process for electrophoretic and electro-osmotic densification, decontamination and dewatering of suspensions includes the use of high electrical capacitance electrodes for capacitive generation of electric fields. Polarity reversals between the capacitor electrodes prevent faradic electrolysis and corrosion reactions at the electrodes, and water wettable, flexible linings for the electrodes, having drainage and filtering capabilities, can also be used as interceptor drains positioned adjacent and in full electric contact with the electrodes, as well as within the suspension as flow path dividers.
An apparatus and process for electrophoretic and electro-osmotic densification, decontamination and dewatering of suspensions includes the use of high electrical capacitance electrodes for capacitive generation of electric fields. Polarity reversals between the capacitor electrodes prevent faradic electrolysis and corrosion reactions at the electrodes, and water wettable, flexible linings for the electrodes, having drainage and filtering capabilities, can also be used as interceptor drains positioned adjacent and in full electric contact with the electrodes, as well as within the suspension as flow path dividers.
A device and method for penetrating the Coulomb barrier is disclosed, An electrode is positioned within a hollow shell, the shell enclosing an inner space containing a fusion reactive fuel such as deuterium. The inner space with the fuel is coaxially centered about the electrode, and a confinement layer made of a high dielectric strength material is located at the outer edge of the inner space, on the inside surface of the spherical shell. A high voltage power source charges the electrode, which causes a tightly packed fusion fuel nucleus cloud such as a deuteron cloud to form on the inner face of the confinement layer, facilitating coulomb barrier penetration. Using the device of the invention, conditions can also be created which enable Coulomb barrier penetration by firing nuclei towards the cloud of nuclei by applying high voltage pulses to the electrode.
A device and process are disclosed for the separate removal of oppositely charged ions from electrolyte solutions and recombining them to form new chemical compositions. The invention provides the ability to create multiple ion flow channels and then form new chemical compositions therefrom. The process is accomplished by selectively combining oppositely charged ions of choice from different electrolyte solutions via the capacitive behavior of high electrical capacity electrodes confined in insulated containers.
C02F 1/469 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par des procédés électrochimiques par séparation électrochimique, p. ex. par électro-osmose, électrodialyse, électrophorèse
22.
APPARATUS AND PROCESS FOR SEPARATION AND SELECTIVE RECOMPOSITION OF IONS
A device and process are disclosed for the separate removal of oppositely charged ions from electrolyte solutions and recombining them to form new chemical compositions. The invention provides the ability to create multiple ion flow channels and then form new chemical compositions therefrom. The process is accomplished by selectively combining oppositely charged ions of choice from different electrolyte solutions via the capacitive behavior of high electrical capacity electrodes confined in insulated containers.
brevets
