Examples herein generally relate to sinter blend compositions for use in a sintering process that do not contain coke breeze (0.0% coke breeze), or contain only very small amounts of coke breeze. In particular, these sinter blend compositions are capable of repurposing a mixture of iron-making reverts, having high total and metallic iron levels that re-oxidize so as to become a replacement fuel source for the coke breeze typically used in sinter blend compositions for use in a sintering process, while still managing to produce a sinter with sufficient ISO tumble strengths.
Examples herein generally relate to sinter blend compositions for use in a sintering process that do not contain coke breeze (0.0% coke breeze), or contain only very small amounts of coke breeze. In particular, these sinter blend compositions are capable of repurposing mixture of iron-making reverts, having high total and metallic iron levels that re-oxidize so as to become a replacement fuel source for the coke breeze typically used in sinter blend compositions for use in a sintering process, while still managing to produce a sinter with sufficient ISO tumble strengths.
Method of reclaiming and inhibiting activation of DRI fines is disclosed comprising the steps of forming a moving stream or pile containing DRI pellets and DRI fines, coating the moving stream or the pile of DRI pellets and DRI fines with a coating material comprising an alkane mixture in the C15 to C40 range to form a coating on the DRI pellets and DRI fines and cause DRI fines to adhere together and to the DRI pellets to form a plurality of agglomerates, and moving the agglomerates of coated DRI pellets and coated DRI fines to a facility for use in making steel. The coating material may be applied to coat the DRI pellets and DRI fines at a rate between 0.2 and 2.0 gallons per ton of DRI processed. The coating material may be mineral oil.
C21B 13/00 - Fabrication de fer spongieux ou d'acier liquide par des procédés directs
C22B 1/244 - AgglutinationBriquetage avec des liants organiques
B05D 1/40 - Distribution des liquides ou d'autres matériaux fluides, appliqués par des éléments se déplaçant par rapport à la surface à couvrir
B05D 7/14 - Procédés, autres que le flocage, spécialement adaptés pour appliquer des liquides ou d'autres matériaux fluides, à des surfaces particulières, ou pour appliquer des liquides ou d'autres matériaux fluides particuliers à du métal, p. ex. à des carrosseries de voiture
C23F 15/00 - Autres méthodes pour prévenir la corrosion, l'entartrage ou les incrustations
A method of reclaiming and inhibiting activation of DRI including forming a moving stream or pile containing DRI pellets and DRI fines and applying to said DRI material a coating material optionally having a melting point between 70 and 200F and comprising at least one antioxidant and at least one a carboxylic material with at least one selected from the group consisting of coatable fatty acid and an esterified derivative thereof, forming a coating on the DRI pellets and DRI fines to cause the fines to adhere together and to the pellets to form a plurality of DRI agglomerates. The coating material may be selected from the group consisting of palm oil, coconut oil, combinations thereof, and ester derivatives thereof. The antioxidant in the coating material is selected from the group consisting of at least one of butylated hydroxytoluene, carotenoid, phytosterol, squalene, vitamin E, tocopherols, tocotrienols, and mixtures thereof.
A method of reclaiming and inhibiting activation of DRI including forming a moving stream or pile containing DRI pellets and DRI fines and applying to said DRI material a coating material optionally having a melting point between 70 and 200° F. and comprising at least one antioxidant and at least one a carboxylic material with at least one selected from the group consisting of coatable fatty acid and an esterified derivative thereof, forming a coating on the DRI pellets and DRI fines to cause the fines to adhere together and to the pellets to form a plurality of DRI agglomerates. The coating material may be selected from the group consisting of palm oil, coconut oil, combinations thereof, and ester derivatives thereof. The antioxidant in the coating material is selected from the group consisting of at least one of butylated hydroxytoluene, carotenoid, phytosterol, squalene, vitamin E, tocopherols, tocotrienols, and mixtures thereof.
C23F 11/00 - Inhibition de la corrosion de matériaux métalliques par application d'inhibiteurs sur la surface menacée par la corrosion ou par addition d'inhibiteurs à l'agent corrosif
C23F 14/00 - Prévention de l'entartrage ou des incrustations dans les appareils destinés à chauffer des liquides à des fins physiques ou chimiques
C23F 15/00 - Autres méthodes pour prévenir la corrosion, l'entartrage ou les incrustations
C22B 1/216 - FrittageAgglomération dans des fours tournants
A method for use in production of metallic iron nodules comprising providing a reducible mixture into a hearth furnace for the production of metallic iron nodules, where the reducible mixture comprises a quantity of reducible iron bearing material, a quantity of first carbonaceous reducing material of a size less than about 28 mesh of an amount between about 65 percent and about 95 percent of a stoichiometric amount necessary for complete iron reduction of the reducible iron bearing material, and a quantity of second carbonaceous reducing material with an average particle size greater than average particle size of the first carbonaceous reducing material and a size between about 3 mesh and about 48 mesh of an amount between about 20 percent and about 60 percent of a stoichiometric amount of necessary for complete iron reduction of the reducible iron bearing material.
A processed DRI material having an average surface roughness (Ra) of less than 1.5 μm is disclosed. A method and system for making processed DRI are also disclosed. One embodiment of the method and system may include assembling a rotatable chamber having an internal screen capable of supporting DRI during tumbling, with at least one opening in the chamber to permit fines to exit the chamber during tumbling, and delivering DRI into the chamber to tumble the DRI on the screen to remove fines from the DRI. Another embodiment of the method and system may include assembling a rotatable chamber having a feed end and an exit end, and having a screen therein capable of supporting DRI as the DRI moves through the chamber, and delivering DRI to the chamber and rotating the chamber to tumble the DRI while removing fines.
2 emissions is disclosed. The method includes: assembling a linear hearth furnace having entry and exit portions, at least a conversion zone and a fusion zone, and a moving hearth adapted to move reducible iron bearing material through the furnace on contiguous hearth sections; assembling a shrouded return substantially free of air ingress extending adjacent at least the conversion and fusion zones of the furnace through which hearth sections can move from adjacent the exit portion to adjacent the entry portion of the furnace; transferring the hearth sections from the furnace to the shrouded return adjacent the exit portion; reducing reducible material in the linear hearth furnace to metallic iron nodules; and transporting gases from at least the fusion zone to the shrouded return to heat the hearth sections while in the shrouded return.
C22B 5/00 - Procédés généraux de réduction appliqués aux métaux
F27D 99/00 - Matière non prévue dans les autres groupes de la présente sous-classe
C21B 13/10 - Fabrication de fer spongieux ou d'acier liquide par des procédés directs dans des fours à réverbère
F27D 17/00 - Dispositions pour l'utilisation de la chaleur perdueDispositions pour l'utilisation ou pour l'élimination des gaz résiduaires
F27B 9/02 - Fours dans lesquels la charge est déplacée mécaniquement, p. ex. du type tunnel Fours similaires dans lesquels la charge se déplace par gravité à trajets multiplesFours dans lesquels la charge est déplacée mécaniquement, p. ex. du type tunnel Fours similaires dans lesquels la charge se déplace par gravité à plusieurs chambresCombinaisons de fours
F27B 9/30 - Parties constitutives, accessoires ou équipement spécialement adaptés à ces types de fours
C21B 13/00 - Fabrication de fer spongieux ou d'acier liquide par des procédés directs
A method of production of metallic iron nodules comprises assembling a hearth furnace having a moveable hearth comprising refractory material and having a conversion zone and a fusion zone, providing a hearth material layer comprising carbonaceous material on the refractory material, providing a layer of reducible material comprising and iron bearing material arranged in discrete portions over at least a portion of the hearth material layer, delivering oxygen gas into the hearth furnace to a ratio of at least 0.8:1 ponds of oxygen to pounds of iron in the reducible material to heat the conversion zone to a temperature sufficient to at least partially reduce the reducible material and to heat the fusion zone to a temperature sufficient to at least partially reduce the reducible material, and heating the reducible material to form one or more metallic iron nodules and slag.
A method for use in production of metallic iron nodules comprising providing a reducible mixture into a hearth furnace for the production of metallic iron nodules, where the reducible mixture comprises a quantity of reducible iron bearing material, a quantity of first carbonaceous reducing material of a size less than about 28 mesh of an amount between about 65 percent and about 95 percent of a stoichiometric amount necessary for complete iron reduction of the reducible iron bearing material, and a quantity of second carbonaceous reducing material with an average particle size greater than average particle size of the first carbonaceous reducing material and a size between about 3 mesh and about 48 mesh of an amount between about 20 percent and about 60 percent of a stoichiometric amount of necessary for complete iron reduction of the reducible iron bearing material.
A method for use in production of metallic iron nodules comprising providing a reducible mixture into a hearth furnace for the production of metallic iron nodules, where the reducible mixture comprises a quantity of reducible iron bearing material, a quantity of first carbonaceous reducing material of a size less than about 28 mesh of an amount between about 65 percent and about 95 percent of a stoichiometric amount necessary for complete iron reduction of the reducible iron bearing material, and a quantity of second carbonaceous reducing material with an average particle size greater than average particle size of the first carbonaceous reducing material and a size between about 3 mesh and about 48 mesh of an amount between about 20 percent and about 60 percent of a stoichiometric amount of necessary for complete iron reduction of the reducible iron bearing material.
A hearth furnace for producing metallic iron material has a furnace housing having a drying/preheat zone, a conversion zone, a fusion zone, and optionally a cooling zone, the conversion zone is between the drying/preheat zone and the fusion zone. A moving hearth is positioned within the furnace housing. A hood or separation barrier within at least a portion of the conversion zone, fusion zone or both separates the fusion zone into an upper region and a lower region with the lower region adjacent the hearth and the upper region adjacent the lower region and spaced from the hearth. An injector introduces a gaseous reductant into the lower region adjacent the hearth. A combustion region may be formed above the hood or separation barrier.
A processed DRI material having an average surface roughness (Ra) of less than 1.5 μm is disclosed. A method and system for making processed DRI are also disclosed. One embodiment of the method and system may include assembling a rotatable chamber having an internal screen capable of supporting DRI during tumbling, with at least one opening in the chamber to permit fines to exit the chamber during tumbling, and delivering DRI into the chamber to tumble the DRI on the screen to remove fines from the DRI. Another embodiment of the method and system may include assembling a rotatable chamber having a feed end and an exit end, and having a screen therein capable of supporting DRI as the DRI moves through the chamber, and delivering DRI to the chamber and rotating the chamber to tumble the DRI while removing fines.
A battery of stationary hearth furnaces, and method for using, for producing metallic iron nodules having a furnace having a stationary hearth, an inlet and an outlet; a heating chamber beneath the stationary hearth having heated fluids circulated thereto and heating reducible material on the stationary hearth; passageways circulating fluids, through ports from the furnace housing above the reducible material to the heating chamber beneath; burners and air inlets in the furnace and optionally in at least one passageway and a heating chamber for drying and heating the reducible material, driving off and burning volatile material, and forming metallic iron nodules; a loading device for loading reducible material and optionally hearth material onto the stationary hearth through the inlet; and a discharging device capable of discharging metallic iron nodules and optionally related material from the stationary hearth through the outlet.
2 between 1.4 and 1.8, forming agglomerates of the reducible mixture over a hearth material layer to protect the hearth, heating the agglomerates to a higher temperature above the melting point of iron to form nodules of metallic iron and slag material from the agglomerates by melting.
A method and system for producing metallic iron nuggets may include providing multiple layers of agglomerates, such as briquettes, balls and extrusions, of a reducible mixture of reducing material (such as carbonaceous material) and of a reducible iron bearing material (such as iron oxide) on a hearth material layer (such as carbonaceous material) and providing a coarse overlayer of carbonaceous material over at least some of the agglomerates. Heating the agglomerates of reducible mixture to 1425° C. or 1400° C. or 1375° C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.
A method for producing metallic iron including providing a hearth furnace having an entry end and a discharge end, a moveable hearth, and an exhaust stack positioned toward the entry end of the furnace, providing a carbonaceous hearth layer above the hearth, providing a layer of reducible material comprising reducing material and iron bearing material, delivering a flow of gases into the hearth furnace through burners, gas injection ports, or a combination thereof directing a flow of gases toward the entry end selected from combustible fuel, oxygen and carbon dioxide, oxygen and flue gas, oxygen and air, or a combination thereof to heat the furnace to a temperature sufficient to at least partially reduce the reducible material, increasing the velocity of the flow of gas to greater than 4 feet per second along the furnace, and heating the layer of reducible material to at least partially reduce the reducible material.
A method and system for making metallic iron nodules with reduced CO2 emissions is disclosed. The method includes: assembling a linear hearth furnace having entry and exit portions, at least a conversion zone and a fusion zone, and a moving hearth adapted to move reducible iron bearing material through the furnace on contiguous hearth sections; assembling a shrouded return substantially free of air ingress extending adjacent at least the conversion and fusion zones of the furnace through which hearth sections can move from adjacent the exit portion to adjacent the entry portion of the furnace; transferring the hearth sections from the furnace to the shrouded return adjacent the exit portion; reducing reducible material in the linear hearth furnace to metallic iron nodules; and transporting gases from at least the fusion zone to the shrouded return to heat the hearth sections while in the shrouded return.
A method of production of metallic iron nodules comprises assembling a hearth furnace having a moveable hearth comprising refractory material and having a conversion zone and a fusion zone, providing a hearth material layer comprising carbonaceous material on the refractory material, providing a layer of reducible material comprising and iron bearing material arranged in discrete portions over at least a portion of the hearth material layer; delivering oxygen gas into the hearth furnace to a ratio of at least 0.8:1 pounds of oxygen to pounds of iron in the reducible material to heat the conversion zone to a temperature sufficient to at least partially reduce the reducible material and to heat the fusion zone to a temperature sufficient to at least partially reduce the reducible mateπal, and heating the reducible material to form one or more metallic iron nodules and slag.
A method of recovering metallic iron from iron-bearing metallurgical waste in steelmaking comprising steps of providing an iron-bearing metallurgical waste containing more than 55 % by weight FeO and FeO equivalent and a particle size of at least 80 % less than 10 mesh, mixing the iron-bearing metallurgical waste with a carbonaceous material to form a reducible mixture where the carbonaceous material is between 80 and 110 % of the stoichiometric amount needed to reduce the iron-bearing waste to metallic iron, and as needed additions to provide a silica content between 0.8 and 8 % by weight and a ratio of CaO/SiO2 between 1.4 and 1.8, forming agglomerates of the reducible mixture over a hearth material layer to protect the hearth, heating the agglomerates to a higher temperature above the melting point of iron to form nodules of metallic iron and slag material from the agglomerates by melting.
A method and system for producing metallic iron nuggets may include providing multiple layers of agglomerates, such as briquettes, balls and extrusions, of a reducible mixture of reducing material (such as carbonaceous material) and of a reducible iron bearing material (such as iron oxide) on a hearth material layer (such as carbonaceous material) and providing a coarse overlayer of carbonaceous material over at least some of the agglomerates. Heating the agglomerates of reducible mixture to 1425 °C or 1400 °C or 1375 °C results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.
Method and system for producing metallic nuggets includes providing reducible mixture of reducing material (such as carbonaceous material) and reducible iron bearing material (such as iron oxide) that may be arranged in discrete portions, such as mounds or briquettes, on at least a portion of a hearth material layer (such as carbonaceous material). A coarse overlayer of carbonaceous material may be provided over at least some of the discrete portions. Heating the reducible mixture to 1425° C. or 1400° C. or 1375° C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.
A battery of stationary hearth furnaces, and method for using, for producing metallic iron nodules having a furnace having a stationary hearth, an inlet and an outlet; a heating chamber beneath the stationary hearth having heated fluids circulated thereto and heating reducible material on the stationary hearth; passageways circulating fluids, through ports from the furnace housing above the reducible material to the heating chamber beneath; burners and air inlets in the furnace and optionally in at least one passageway and a heating chamber for drying and heating the reducible material, driving off and burning volatile material, and forming metallic iron nodules; a loading device for loading reducible material and optionally hearth material onto the stationary hearth through the inlet; and a discharging device capable of discharging metallic iron nodules and optionally related material from the stationary hearth through the outlet.
C21B 11/08 - Fabrication de la fonte brute autrement que dans les hauts fourneaux dans des fours à réverbère
F27B 9/20 - Fours dans lesquels la charge est déplacée mécaniquement, p. ex. du type tunnel Fours similaires dans lesquels la charge se déplace par gravité caractérisés par le trajet de la charge pendant le traitementFours dans lesquels la charge est déplacée mécaniquement, p. ex. du type tunnel Fours similaires dans lesquels la charge se déplace par gravité caractérisés par le procédé de déplacement de la charge pendant le traitement la charge se déplaçant sur un trajet sensiblement rectiligne
F27B 15/02 - Parties constitutives, accessoires ou équipement spécialement adaptés à ces types de fours
24.
SYSTEM AND METHOD FOR COOLING AND REMOVING IRON FROM A HEARTH
A system and method for cooling and removing metallic iron and other aggregate from a moving hearth is provided. Cooling may be provided by a secondary cooling system and a spray cooling system in a cooling zone. The secondary cooling system may include an arrangement of coolant tubes for absorbing heat. A flow of nitrogen may be provided through the cooling zone. The spray cooling system may provide evaporative cooling. Aggregate removal may be provided by a magnetic removal system, a plow system, and a sweeper system. The magnetic removal system uses a magnetic device and a moving belt to remove iron materials. The plow system uses a plow to separate and remove aggregate from the moving hearth. The sweeper system may use a vacuum device to pull materials from the moving hearth.
A multiple moving hearth furnace (10) having a furnace housing (11) with at least two moving hearths (20) positioned laterally within the furnace housing, the hearths moving in opposite directions and each moving hearth (20) capable of being charged with at least one layer of iron oxide and carbon bearing material at one end, and being capable of discharging reduced material at the other end. A heat insulating partition (92) is positioned between adjacent moving hearths of at least portions of the conversion zones (13), and is capable of communicating gases between the atmospheres of the conversion zones of adjacent moving hearths. A drying/preheat zone (12), a conversion zone (13), and optionally a cooling zone (15) are sequentially positioned along each moving hearth (30) in the furnace housing (11).
C21B 15/00 - Autres procédés pour la fabrication de fer à partir de composés de fer
C21B 13/00 - Fabrication de fer spongieux ou d'acier liquide par des procédés directs
F27B 9/02 - Fours dans lesquels la charge est déplacée mécaniquement, p. ex. du type tunnel Fours similaires dans lesquels la charge se déplace par gravité à trajets multiplesFours dans lesquels la charge est déplacée mécaniquement, p. ex. du type tunnel Fours similaires dans lesquels la charge se déplace par gravité à plusieurs chambresCombinaisons de fours
A hearth furnace (10) for producing metallic iron material has a furnace housing (11) with a drying/preheat zone (12) capable of providing a drying/preheat atmosphere for reducible material, a conversion zone (13) capable of providing a reducing atmosphere for reducible material, a fusion zone (14) capable of providing an atmosphere to at least partially reduced metallic iron material, and optionally a cooling zone (15) capable of providing a cooling atmosphere for reduced material containing metallic iron material. A movable hearth (20) within the furnace housing (11) in a direction through the drying/preheat zone (12), then the conversion zone (13), then the fusion zone (14), and then the cooling zone (15). A separation barrier 30 is positioned within at least a portion of the conversion zone (13), the separation barrier (30) separating the conversion zone (13) into a combustion region (32) and a reducing region (31) with the reducing region (31) adjacent the hearth (20) and the combustion region (32) adjacent the reducing region (31) and spaced from the hearth (20).
A hearth furnace (10) for producing metallic iron material has a furnace housing (11) having a drying/preheat zone (12), a conversion zone (13), a fusion zone (14), and optionally a cooling zone (15), the conversion zone (13) is between the drying/preheat zone (12) and the fusion zone (14). A moving hearth (20) is positioned within the furnace housing (11). A hood (30) within at least a portion of the conversion zone (13) separates the conversion zone (13) into an upper region and a lower region with the lower region adjacent the hearth (20) and the upper region adjacent the lower region and spaced from the hearth (20). An injector introduces a gaseous reductant into the lower region adjacent the hearth (20).
Method and system for producing metallic nuggets includes providing reducible mixture of reducing material (such as carbonaceous material) and reducible iron bearing material (such as iron oxide) arranged in discrete portions, such as mounds or briquettes, on at least a portion of a hearth material layer (such as carbonaceous material). A coarse overlayer of carbonaceous material is provided over at least some of the discrete portions. Heating the discrete portions of reducible mixture to 1425 °C or 1400 °C or 1375 °C results in formation of an intermediate product of metallic iron nuggets and slag, and one or more metallic iron nuggets. The intermediate product with less than 5% mass MgO in the slag may have the ratio of percent by weight sulfur in the slag over percent sulfur in the metallic nuggets of at least about 12 or at least about 15. The metallic iron nuggets may have a sulfur content of less than 0.03%.
Method and system for producing metallic nuggets includes providing reducible mixture (e.g., reducible micro-agglomerates; reducing material and reducible iron bearing material; reducible mixture including additives such as a fluxing agent; compacts, etc.) on at least a portion of a hearth material layer. In one embodiment, a plurality of channel openings extend at least partially through a layer of the reducible mixture to define a plurality of nugget forming reducible material regions. Such channel openings may be at least partially filled with nugget separation fill material (e.g., carbonaceous material). Thermally treating the layer of reducible mixture results in formation of one or more metallic iron nuggets. In other embodiments, various compositions of the reducible mixture and the formation of the reducible mixture provide one or more beneficial characteristics.
Systems and methods for use in processing raw material (e.g., iron bearing material) include a linear furnace apparatus extending along a longitudinal axis between a charging end and a discharging end (e.g., the linear furnace apparatus includes at least a furnace zone positioned along the longitudinal axis). Raw material is provided into one or more separate or separable containers (e.g., trays) at the charging end of the linear furnace apparatus. The separate or separable containers are moved through at least the furnace zone and to the discharging end where the processed material is discharged resulting in one or more empty containers. One or more of the empty containers are returned to the charging end of the linear furnace apparatus to receive further raw material.
brevets
