Abrégé

Disclosed is a method for preparing bio-oil, which can be used as bio heavy fuel oil and bio marine oil, from a fatty acid with high acid value. The method for preparing bio-oil comprises the steps of: inputting materials comprising glycerine and a fatty acid into respective material input ports positioned in the center of a column-type reactor and esterification reacting the material comprising glycerine and fatty acid in each tray of a reaction area, thereby producing glyceride and water; obtaining the produced glyceride through a lower part of the reactor; and vaporizing the water produced by the reaction, moving the water (vapor) to a distillation area in an upper part of the reactor to separate the water from active components comprised in the vapor, allowing the separated active components to flow into the reaction area, and removing the separated water (vapor) through the upper part of the reactor.

Classes IPC  ?

• C11C 3/02 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse par estérification des acides gras avec la glycérine
• C10G 3/00 - Production de mélanges liquides d'hydrocarbures à partir de matières organiques contenant de l'oxygène, p. ex. huiles, acides gras
• C10L 1/02 - Combustibles carbonés liquides à base essentielle de composants formés uniquement de carbone, d'hydrogène et d'oxygène
• C11B 3/12 - Raffinage des graisses ou huiles par distillation
• C11B 13/02 - Obtention de graisses, huiles ou acides gras à partir de résidus des résidus de savonnerie

Abrégé

In the present invention, disclosed is a method for producing low-viscosity dimer acid having a low content of aromatic dimer acid. The dimer acid production method provides a method for producing dimer acid, comprising the steps of: preparing fatty acid raw materials having a polyunsaturated fatty acid content of 25 wt% or less relative to 100 wt% of unsaturated fatty acids, by hydrolyzing and distilling vegetable oils selected from the group consisting of palm oil, palm kernel oil and PFAD (Palm Fatty Acid Distillate); synthesizing dimer acid by polymerizing the fatty acid raw materials; and isolating the dimer acid by distilling the reactant containing the synthesized dimer acid.

Classes IPC  ?

• C07C 51/44 - SéparationPurificationStabilisationEmploi d'additifs par changement de l'état physique, p. ex. par cristallisation par distillation
• C07C 51/47 - SéparationPurificationStabilisationEmploi d'additifs par traitement solide-liquideSéparationPurificationStabilisationEmploi d'additifs par absorption-adsorption chimique
• B01J 27/232 - Carbonates
• B01J 21/16 - Argiles ou autres silicates minéraux
• B01J 35/00 - Catalyseurs caractérisés par leur forme ou leurs propriétés physiques, en général

Abrégé

Disclosed is a method for preparing bio-oil, which can be used as bio heavy fuel oil and bio marine oil, from a fatty acid with high acid value. The method for preparing bio-oil comprises the steps of: inputting materials comprising glycerine and a fatty acid into respective material input ports positioned in the center of a column-type reactor and esterification reacting the material comprising glycerine and fatty acid in each tray of a reaction area, thereby producing glyceride and water, wherein the column-type reactor has the plurality of trays installed inside the reactor so as to form a plurality of compartments in the vertical direction inside the reactor, openings are formed in the plurality of trays to connect the compartments which are vertically adjacent, and the openings of the adjacent compartments are alternately formed in a crisscrossing manner; obtaining the produced glyceride through a lower part of the reactor; and vaporizing the water produced by the esterification reaction, moving the water in a vapor state to a distillation area in an upper part of the reactor to separate the water from active components (reaction material and bio-oil) comprised in the vapor, allowing the separated active components to flow into the reaction area, and removing the separated water through the upper part of the reactor in a vapor state. The acid value of the glyceride is 30 mgKOH/g or lower, and the esterification reaction is performed at a reaction temperature of 200 to 250 ℃ and at ordinary pressure without using a catalyst.

Classes IPC  ?

• C10G 3/00 - Production de mélanges liquides d'hydrocarbures à partir de matières organiques contenant de l'oxygène, p. ex. huiles, acides gras
• C10L 1/02 - Combustibles carbonés liquides à base essentielle de composants formés uniquement de carbone, d'hydrogène et d'oxygène
• C11C 3/02 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse par estérification des acides gras avec la glycérine

Abrégé

Disclosed is a method for preparing fatty acid alkyl ester for bio-diesel fuels by reacting a raw material containing fat with water to prepare fatty acid, and then reacting the prepared fatty acid with alcohol. The method for preparing fatty acid alkyl ester for bio-diesel fuels includes the steps of: preparing fatty acid and glycerin by an hydrolysis reaction of a raw material containing fat and water at the temperature of 200 to 280° C. and the pressure of 30 to 80 bar; carrying out a phase separation of the fatty acid and the glycerin; and carrying out an esterification reaction of the separated fatty acid and alcohol at the temperature of 200 to 350° C. and the pressure of atmospheric pressure to 35 bar.

Classes IPC  ?

• C11C 3/00 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse
• C10L 1/02 - Combustibles carbonés liquides à base essentielle de composants formés uniquement de carbone, d'hydrogène et d'oxygène
• C07C 67/03 - Préparation d'esters d'acides carboxyliques par réaction d'un groupe ester avec un groupe hydroxyle
• C11C 1/04 - Préparation des acides gras à partir de graisses, huiles ou ciresRaffinage des acides gras à partir de graisses ou huiles par hydrolyse

Abrégé

A method for preparing fatty acid alkyl ester for bio-diesel fuel is disclosed wherein fatty acid, specifically fatty acid distillate reacts with alcohol. The method does not require the glycerin purification process, and has the superior conversion ratio of fatty acid. The method for preparing fatty acid alkyl ester for bio-diesel fuel comprises the step of carrying out a counter current type esterification reaction of fatty acid and alcohol in each tray of a counter current column reactor at a temperature of 200 to 350° C. and a pressure of 1 to 35 bar. Here the raw material of the fatty acid is fed to an upper part of the counter current column reactor and the alcohol is fed to a lower part of the counter current column reactor. The counter current column reactor has a number of trays which are installed horizontally to have a number of vertical compartments. Each of the number of trays has an opening part at one end thereof to communicate one compartment with an adjoining compartment. The opening parts of two adjoining trays are alternately installed with each other.

Classes IPC  ?

• C11C 3/04 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse par estérification des graisses ou des huiles
• B01J 8/00 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés
• C07C 67/08 - Préparation d'esters d'acides carboxyliques par réaction d'acides carboxyliques ou d'anhydrides symétriques avec le groupe hydroxyle ou O-métal de composés organiques
• C11C 1/08 - Raffinage
• C11C 3/00 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse
• B01J 8/04 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés avec des particules immobiles, p. ex. dans des lits fixes le fluide passant successivement à travers plusieurs lits

Abrégé

A method for preparing fatty acid alkyl ester for bio-diesels is disclosed, wherein fatty acid, specifically fatty acid distillate reacts with alcohol in the presence of metal catalyst instead of conventional acid or solid acid catalyst. The method does not require the glycerin purification process, and has the superior conversion ratio of fatty acid. The method for preparing fatty acid alkyl ester comprises the step of carrying out an esterification reaction of fatty acid raw material with alcohol in the presence of metal catalyst. Preferably, the esterification reaction is carried out at the temperature of 200 to 350° C. and the pressure of atmospheric pressure to 10 bar, and the metal catalyst is a compound containing metal selected from the group consisting of cobalt, iron, manganese, zinc, titanium and mixture thereof.

Classes IPC  ?

• C11B 3/00 - Raffinage des graisses ou huiles

Abrégé

A method and an apparatus for preparing fatty acid alkyl ester for bio-diesels are disclosed, wherein fatty acid, specifically fatty acid distillate reacts with alcohol, without a catalyst. The method does not require the purification process of the catalyst and glycerin, and has the superior conversion ratio of fatty acid. The method for preparing fatty acid alkyl ester for bio-diesel fuels comprises the step of esterifying fatty acid raw material with alcohol, under a temperature of 200 to 350° C. and a pressure of atmospheric pressure to 10 bar. The apparatus for preparing fatty acid alkyl ester for bio-diesel fuels, comprises: the first reactor for esterifying fatty acid raw material with alcohol under a temperature of 200° C. to 350° C. and a pressure of atmospheric pressure to 10 bar and for converting 80 to 90% of total fatty acid into fatty acid alkyl ester; and the second reactor for converting remaining fatty acid unconverted at the first reactor into fatty acid alkyl ester.

Classes IPC  ?

• C11C 3/00 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse

Produits et services

Biodiesel, fuels consisting of vegetable fats and oils.