AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Tammer, Martinus Catharinus
Van Den Berg, Michel
Ter Horst, Bjorn
Abrégé
n333n333233, and the fraction comprising crude phosphorous acid, thereby forming an aqueous solution comprising potassium phosphite, and (d) removing organic compounds from said aqueous solution.
C07C 51/60 - Préparation d'halogénures d'acides carboxyliques par conversion d'acides carboxyliques ou de leurs anhydrides en halogénures ayant la même partie acide carboxylique
C07C 213/04 - Préparation de composés contenant des groupes amino et hydroxy, amino et hydroxy éthérifiés ou amino et hydroxy estérifiés liés au même squelette carboné par réaction d'ammoniac ou d'amines avec des oxydes d'oléfines ou des halohydrines
C07C 215/40 - Composés contenant des groupes amino et hydroxy liés au même squelette carboné ayant des groupes hydroxy et des groupes amino liés à des atomes de carbone acycliques du même squelette carboné avec des atomes d'azote quaternisés liés à des atomes de carbone du squelette carboné
3.
PROCESS FOR PREPARING A POWDERY ORGANIC PEROXIDE FORMULATION
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Van Den Berg, Michel
Overkamp, Johannes Willibrordus Antonius
Talma, Auke Gerardus
Krosendijk, Edgard Everick
Abrégé
Process for preparing a powdery organic peroxide formulation, said process comprises the following steps: a) preparing a reaction mixture comprising: - 40-80 wt% water - 10-25 wt% of an acid chloride or chloroformate, - 1 -4 wt% hydrogen peroxide, - 2-8 wt% alkali metal hydroxide, - 1 -25 wt% of a phlegmatizer selected from the group consisting of ethylene glycol dibenzoate, phenyl benzoate, trimethylol propane tribenzoate, glyceryl tribenzoate, ethylene glycol ditoluate, 1,3-propanediol ditoluate, ethylene glycol 4-tert-butylbenzoate, ethylene glycol monobenzoate monotoluate, 2,3- butanediol dibenzoate, 4-methylphenyl benzoate acid ester, trimethylolpropane dibenzoate, and combinations thereof - 0.002-0.20 wt% of a surfactant, and - 0.25-5.0 wt% of an inert organic solvent, all percentages based on the weight of the reaction mixture, b) heating the reaction mixture at a temperature in the range 5-50°C.
C07C 409/34 - Composés peroxy le groupe —O—O— étant lié à deux groupes C=O appartenant tous les deux à des acides carboxyliques
C07C 409/38 - Composés peroxy le groupe —O—O— étant lié à un groupe C=O et à un atome de carbone, qui n'est pas substitué de plus par des atomes d'oxygène, c.-à-d. esters de peroxyacides
4.
FORMULATION OF DI(4-TERT-BUTYLCYCLOHEXYL) PEROXYDICARBONATE
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Te Nijenhuis, Marcellinus Antonius Maria
Woudenberg, Richard Herman
Abrégé
x(3-X)(3-X), wherein x=1 or 2), (ii) reducing said methyl gallium chloride with metallic aluminium to form methyl aluminium dichloride (MADC) and metallic gallium, and (iii) removing metallic gallium from the DMAC-containing composition.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Probst, Christian
Burkhardt, Volker
Klobes, Olaf
Abrégé
n2npn2nn2nm2mqm2mm2m2m-SH wherein each m is independently selected from integers in the range 1-8, preferably 1-6, and most preferably 1-3, and q ranges from 0 to 10, - at least one di-epoxide, and - optionally at least one branching agent selected from compounds having at least three terminal groups selected from epoxy and mercapto groups, wherein the molar ratio (DMDA+GDME)/DMDS is in the range 1.1-4.0.
C08G 75/00 - Composés macromoléculaires obtenus par des réactions créant dans la chaîne principale de la macromolécule une liaison contenant du soufre, avec ou sans azote, oxygène ou carbone
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Winkenwerder, Wyatt August
Band, Elliot Isaac
Abrégé
Disclosed is a continuous process for the oxidation of tertiary amines to provide an amine oxide composition.The process involves mixing a tertiary amine and an aqueous oxidizing agent in a spinning disk reactor and (1) diluting and/or digesting the product or (2) mixing the product in a second spinning disk reactor to provide a tertiary amine oxide having high yield and high purity.
B01J 19/18 - Réacteurs fixes avec éléments internes mobiles
C07C 213/08 - Préparation de composés contenant des groupes amino et hydroxy, amino et hydroxy éthérifiés ou amino et hydroxy estérifiés liés au même squelette carboné par des réactions n'impliquant pas la formation de groupes amino, de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés
C07C 217/06 - Composés contenant des groupes amino et hydroxy éthérifiés liés au même squelette carboné ayant des groupes hydroxy éthérifiés et des groupes amino liés à des atomes de carbone acycliques du même squelette carboné le squelette carboné étant acyclique et saturé ayant un seul groupe hydroxy éthérifié et un seul groupe amino liés au squelette carboné, qui n'est pas substitué par ailleurs
8.
PROCESS FOR THE TREATMENT OF A PHOSPHITE-CONTAINING WASTE STREAM
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Ter Horst, Bjorn
Klerk, Chantal
Dijkgraaf, Paulus Johannes Maria
Van Den Berg, Michel
Abrégé
Process for the treatment of a phosphite-containing waste stream, said process comprising the following steps: (a) optionally neutralizing the waste stream to a pH in the range 6.0-8.0, (b) adding the following compounds to the waste stream in any order of addition: (i) an oxidizing compound in order to oxidize said phosphite towards phosphate, (ii) an NH4+source, (iii) a Mg2+ source, thereby forming a precipitate, (c) followed by isolating the precipitate from the waste stream, wherein the process is conducted under atmospheric pressure and at a temperature not exceeding 90°C.
C02F 103/36 - Nature de l'eau, des eaux résiduaires ou des eaux ou boues d'égout à traiter provenant de l'industrie chimique non prévue dans les groupes provenant de la fabrication de composés organiques
C02F 1/66 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par neutralisationAjustage du pH
C02F 1/78 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par oxydation au moyen d'ozone
C02F 1/76 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par oxydation au moyen d'halogènes ou de composés halogénés
C02F 1/70 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par réduction
9.
THERMALLY EXPANDABLE MICROSPHERES PREPARED FROM BIO-BASED MONOMERS
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Nordin, Ove
Ekmarker, Anna
Waltersson, Evelina
Abrégé
122, separately from one another,isan alkyl group preferably with 1-4 carbon atoms, and wherein the copolymer contains 0-50 wt.% of vinyl aromatic comonomers, based on the total weight of the comonomers. The invention further provides expanded microspheres, which can be used in a variety of applications.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Vanderhoof, Matthew Michael
Rodrigues, Klin Aloysius
Pantha, Sajal
Bailey, Andrew James
Abrégé
Acid-swellable rheology modifier comprise a core-shell polymer, the core-shell polymer comprising a core polymer and a shell comprising at least one shell copolymer layer, at least one shell copolymer layer being at least partially cross-linked and containing a mole percent of crosslinking agent greater than the mole percent of crosslinking agent in the core polymer, wherein said core polymer and said at least one shell copolymer layer are each polymerized from a monomer mixture comprising a) one or more cationic ethylenically unsaturated monomers; b) one or more hydrophobic ethylenically unsaturated monomers; c) optionally one or more nonionic ethylenically unsaturated monomers; and d) optionally one or more associative monomers.Aqueous compositions comprising the acid-swellable rheology modifier include personal care formulations, agricultural formulations, paint formulations, coating formulations, laundry and fabric care formulations, household cleaning formulations, and industrial and institutional cleaning formulations.In one embodiment the core-shell polymer is substantially free of anionic monomers.
A61K 8/81 - Cosmétiques ou préparations similaires pour la toilette caractérisés par la composition contenant des composés organiques macromoléculaires obtenus par des réactions faisant intervenir uniquement des liaisons insaturées carbone-carbone
A61Q 19/10 - Préparations pour le nettoyage ou le bain
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Vanderhoof, Matthew Michael
Rodrigues, Klin Aloysius
Pantha, Sajal
Bailey, Andrew James
Vadillo, Damien Christian
Abrégé
Alkali-swellable rheology modifier comprise a core-shell polymer, the core-shell polymer comprising a core polymer and a shell comprising at least one shell copolymer layer, at least one shell copolymer layer being at least partially cross-linked and containing a mole percent of crosslinking agent greater than the mole percent of crosslinking agent in the core polymer, with the proviso that if the mole percent of crosslinking agent in the core polymer is zero, then either the core polymer is greater than 60 wt.% of the core-shell polymer; and/or the core polymer comprises at least one associative monomer;and/or at least one shell copolymer layer copolymer comprises at least one associative monomer; and/or the at least one shell copolymer layer that is at least partially cross-linked comprises greater than 3 mole.% crosslinking agent, based on the moles of monomers in that shell copolymer layer not counting the crosslinking agent.Aqueous compositions comprising the alkali-swellable rheology modifier include personal care formulations,healthcare formulations, agricultural formulations, paint formulations, coating formulations, laundry and fabric care formulations, household cleaning formulations, and industrial and institutional cleaning formulations.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Woudenberg, Richard Herman
Abrégé
3 3-xx33 in an Al/Ga molar ratio of at least 0.2, thereby forming a liquid formulation, followed by introducing said liquid formulation in a container.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Theeuwen, Conrardus Hubertus Joseph
De Wit, Paulus Pieter
Van Ingen, Gijsbert Adriaan
Staps, Franciscus Adrianus Ludovicus Maria
Abrégé
The present invention relates to methods for processing plant and/or micro-organism derived cellulose materials into rheology/structuring agents. More in particular, the present invention relates to methods wherein plant and/or micro-organism derived cellulose material is co-processed with carboxycellulose. The methods of the present invention provide a variety of benefits, in terms of process efficiency and scalability as well as in relation to the properties of the materials that are obtainable using these methods. For instance, it has been found that (highly) concentrated products produced using the method of the invention are easily (re)dispersible in water and aqueous systems to regain much of the cellulose component's original rheological performance.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
KONINKLIJKE COÖPERATIE COSUN U.A. (Pays‑Bas)
Inventeur(s)
De Wit, Paulus Pieter
Theeuwen, Conrardus Hubertus Joseph
Staps, Franciscus Adrianus Ludovicus Maria
Van Ingen, Gijsbert Adriaan
Abrégé
The present invention relates to a powder composition comprising a cellulose component and a carboxycellulose component. The present inventors surprisingly found that combinations of certain cellulose components and carboxycelluloses can be processed into a powder composition that is easily (re)dispersible in water and aqueous systems to regain much of the cellulose component's original rheological performance. It is believed that in the compositions of the invention, the cellulose component primarily serves to confer the desired rheological/structuring properties while the carboxycellulose primarily serves to enable the cellulose component to be converted into a powder composition with very low water content that can be dispersed without the application of high mechanical shear forces while regaining most or all of the cellulose component's performance. The invention also provides a method for producing the powder composition. Furthermore the invention relates to uses of the powder composition.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Talma, Auke Gerardus
Van Lare, Cornelis Elizabeth Johannus
Ahr, Mathieu Pierre
Leon Matheus, Maria Antonieta Leon
Renkema, Eilertdina Henderika
Kooijman, Cornelis
Abrégé
The present disclosure is directed to halogen-based flame retardants, their preparation and their use in polymers to impart flame retardancy. There is a demand for halogen-based flame retardant that are desirable in view of sustainability, i.e are biodegradable or non-biocumulative and non-toxic, but still provide the required flame retardancy. To this end the disclosure is directed to process for the preparation of a boron-free halogen-based flame retardant which is prepared by reacting halogeno-alkylcarboxylic acid containing at least two halogen atoms with an unsaturated and/or hydroxyl containing carrier molecule having at least three bonding sites for the halogeno-alkylcarboxylic acid per carrier molecule, the flame retardant per se, its use in polymers and a process for the preparation of flame retardant polymers comprising the flame retardant according to the disclosure.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Lewis, Andrew Clist
Baan, Willem Hendrikus
Abrégé
The present disclosure relates to a process to treat metal or mineral ores, wherein the metal or mineral ore is a metallic sulphide ore containing copper, gold, platinum, silver, nickel, molybdenum, arsenic sulphides, cobalt, zinc, lead, tin, antimony or combinations thereof,with a collector composition that includes a dimeric fatty nitrile. The dimeric fatty nitrile is prepared by a process that includes reacting a dimer fatty acid with ammonia at a temperature between about200 °C and about400 °C to form a dimeric amide and removing water from the dimeric amide to form the dimeric nitrile. The disclosure also relates to a collector composition containing the above dimeric fatty nitrile and at least one further collector or frother compound.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Spijkerman, Geesje Klasina
Jansen, Martin Hermanus Maria
Talma, Auke Gerardus
Den Braber, Antonie
Abrégé
Powder mixture comprising 20-80 wt% of one or more powdered organic peroxides selected from the group consisting of dibenzoyl peroxide and substituted dibenzoyl peroxides, 20-80 wt% of a powdered filler material, at least 60 wt%, thereof consisting of a solid inorganic flame retardant, and 0-20 wt% water.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Nordin, Ove
Jonsson, Magnus
Abrégé
12344, separately from one another, is selected from the group consisting of H and an alkyl group preferably with 1-4 carbon atoms. The invention further provides expanded microspheres, which can be used in a variety of applications.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Frijlink, Wilhelm Klaas
Van Der Schuur, Jan Martijn
Talma, Auke Gerardus
Beek, Waldo Joseph Elisabeth
Kamp, Hendrikus Johannes Maria
Abrégé
Process for enhancing the melt strength of polypropylene by extruding said polypropylene in a twin-screw extruder, under inert atmosphere, at a temperature between 150°C and 300°C, and in the presence of 0.1-3.0 wt %, based on the weight of the polypropylene, of a para-substituted dibenzoyl peroxide.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Anger, Leif Magnus Joakim
Stridh, Kjell
Berglund, Lars Erik
Zapf, Alexander
Abrégé
The present invention provides a new type of MEHEC with a DSmethyl from.5 to 2.5, a DSethyl from 0.005 to 0.15, and a MSalkylene-oxide from 0.005 to 0.2,and a very good biostability, which is particularly suitable for use in the building industry, a process for making such MEHEC, powders containing it, and the useof the MEHEC and powders containing it, particularly in the building industry.
C04B 28/02 - Compositions pour mortiers, béton ou pierre artificielle, contenant des liants inorganiques ou contenant le produit de réaction d'un liant inorganique et d'un liant organique, p. ex. contenant des ciments de polycarboxylates contenant des ciments hydrauliques autres que ceux de sulfate de calcium
C04B 28/14 - Compositions pour mortiers, béton ou pierre artificielle, contenant des liants inorganiques ou contenant le produit de réaction d'un liant inorganique et d'un liant organique, p. ex. contenant des ciments de polycarboxylates contenant des ciments de sulfate de calcium
C04B 40/00 - Procédés, en général, pour influencer ou modifier les propriétés des compositions pour mortiers, béton ou pierre artificielle, p. ex. leur aptitude à prendre ou à durcir
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Raaijmakers, Michiel Jozef Thomas
Ten Kate, Antoon Jacob Berend
Kantzer, Eike Nicolas
Veneman, Rens
Jovic, Slavisa
Edvinsson, Rolf Krister
Lake, Karl Fredrik
Van Dam, Hendrik
Ehlers, Ina
Tönnerfors, Sara Erika
Abrégé
The present invention relates to a process to convert the cyclic monourea of ethylene amine compounds (U-EA) into ethylene amine compound (EA) by performing a reactive separation step using a reaction mixture containing the cyclic monourea, wherein one cyclic monourea (U-EA) reacts with another cyclic monourea (U-EA) to transfer its urea unit thereto and the obtained ethylene amine compound (EA) without urea unit is separated from the reaction mixture.
C07D 233/36 - Un atome d'oxygène avec des radicaux hydrocarbonés, substitués par des atomes d'azote, liés aux atomes d'azote du cycle
C07C 209/62 - Préparation de composés contenant des groupes amino liés à un squelette carboné par clivage de liaisons carbone-azote, soufre-azote ou phosphore-azote, p. ex. hydrolyse d'amides, N-déalkylation d'amines ou de composés d'ammonium quaternaire
C07C 211/02 - Composés contenant des groupes amino liés à un squelette carboné ayant des groupes amino liés à des atomes de carbone acycliques d'un squelette carboné saturé acyclique
22.
REACTIVE SEPARATION PROCESS TO CONVERT CYCLIC ALKYLENE UREAS INTO THEIR CORRESPONDING ALKYLENE AMINES
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Veneman, Rens
Ten Kate, Antoon Jacob Berend
Lake, Karl Fredrik
Kantzer, Eike Nicolas
Jovic, Slavisa
Edvinsson, Rolf Krister
Ehlers, Ina
Van Dam, Hendrik
Raaijmakers, Michiel Jozef Thomas
Abrégé
The present invention relates to a process to convert cyclic alkylene ureas into their corresponding alkylene amines by reaction with an amine compound chosen from the group of primary amines or secondary amines that have a higher boiling point than the alkylene amines formed during the process, wherein the process is a reactive separation process and the reaction mixture contains less than 10 wt% of water on the basis of total weight of the reaction mixture.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Ten Kate, Antoon Jacob Berend
Raaijmakers, Michiel Jozef Thomas
Lake, Karl Fredrik
Kantzer, Eike Nicolas
Jovic, Slavisa
Edvinsson, Rolf Krister
Ehlers, Ina
Van Dam, Hendrik
Veneman, Rens
Abrégé
The invention pertains to a process for converting a feedstock comprising cyclic alkyleneureas into their corresponding alkyleneamines, comprising - a CO2 removal step in which cyclic alkyleneureas are converted into their corresponding alkyleneamines by reacting cyclic alkyleneureas in the liquid phase with water with removal of CO2, - an amine removal step wherein cyclic alkyleneureas are converted in a reactive separation process into their corresponding alkyleneamines by reaction with an amine compound selected from the group of primary amines or secondary amines which have a higher boiling point than the alkyleneamines formed during the process. It has been found that the combination of a CO2 removal step and an amine removal step makes it possible to convert alkyleneureas into the corresponding amines in an efficient manner in a high reaction rate.
C07C 209/62 - Préparation de composés contenant des groupes amino liés à un squelette carboné par clivage de liaisons carbone-azote, soufre-azote ou phosphore-azote, p. ex. hydrolyse d'amides, N-déalkylation d'amines ou de composés d'ammonium quaternaire
24.
TWO-STEP PROCESS FOR CONVERTING CYCLIC ALKYLENE UREAS INTO THEIR CORRESPONDING ALKYLENE AMINES
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Kantzer, Eike Nicolas
Lake, Karl Fredrik
Ehlers, Ina
Wernersson, Stig Mikael
Edvinsson, Rolf Krister
Van Dam, Hendrik
Ten Kate, Antoon Jacob Berend
Veneman, Rens
Raaijmakers, Michiel Jozef Thomas
Jovic, Slavisa
Abrégé
The invention pertains to a process for converting cyclic alkyleneureas into their corresponding alkyleneamines, comprising - in a first step converting cyclic alkyleneureas into their corresponding alkyleneamines by reacting cyclic alkyleneureas in the liquid phase with water with removal of CO2, so as to convert between 5 mole% and 95 mole% of alkyleneurea moieties in the feedstock to the corresponding amines, and - in a second step adding an inorganic base and reacting cyclic alkylene ureas remaining from the first step with the inorganic base to convert them partially or completely into their corresponding alkyleneamines. It has been found that the two-step process of the present invention makes it possible to still obtain a high conversion of cyclic alkyleneureas, while using substantially less strong inorganic base. The process according to the invention also shows a higher selectivity to amines than the prior art process.
C07C 209/62 - Préparation de composés contenant des groupes amino liés à un squelette carboné par clivage de liaisons carbone-azote, soufre-azote ou phosphore-azote, p. ex. hydrolyse d'amides, N-déalkylation d'amines ou de composés d'ammonium quaternaire
C07C 211/02 - Composés contenant des groupes amino liés à un squelette carboné ayant des groupes amino liés à des atomes de carbone acycliques d'un squelette carboné saturé acyclique
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Veneman, Rens
Ten Kate, Antoon Jacob Berend
Raaijmakers, Michiel Jozef Thomas
Jovic, Slavisa
Edvinsson, Rolf Krister
Kantzer, Eike Nicolas
Lake, Karl Fredrik
Ehlers, Ina
Van Dam, Hendrik
Abrégé
The invention relates to a process for manufacturing polyethyleneannine compounds selected from the group of polyethyleneamines and hydroxyethylethyleneamines comprising the steps of - in an adduction step providing a CO2 adduct of a starting compound comprising a - NH-CH2-CH2-NH- moiety or a -NH-CH2-CH2-OH moiety, or HO-CH2-CH2-OH, - in a reaction step reacting a hydroxy-functional compound selected from the group of ethanolamines and dihydroxyethane with an amine-functional compound, wherein at least part of the total of hydroxy-functional compounds and amine-functional compounds is provided in the form of a CO2 adduct, to form CO2 adduct of a product polyethyleneannine compound, - in an elimination step converting CO2 adduct of product polyethyleneannine compound to the corresponding product polyethylene amine compound, wherein a fraction comprising a recycle compound comprising a -NH-CH2-CH2-NH- moiety or a -NH-CH2-CH2-OH moiety, or HO-CH2-CH2-OH, or CO2 adducts thereof, is provided from the end of the reaction step or the elimination step to the adduction step or to the reaction step, the recycle compound having per molecule on average fewer of the total of -NH- CH2-CH2-NH- moieties and -NH-CH2-CH2-OH moieties than the product polyethyleneannine compound.
C07C 211/02 - Composés contenant des groupes amino liés à un squelette carboné ayant des groupes amino liés à des atomes de carbone acycliques d'un squelette carboné saturé acyclique
C07C 215/18 - Composés contenant des groupes amino et hydroxy liés au même squelette carboné ayant des groupes hydroxy et des groupes amino liés à des atomes de carbone acycliques du même squelette carboné le squelette carboné étant saturé et acyclique avec des groupes hydroxy et au moins deux groupes amino liés au squelette carboné
26.
PROCESS FOR CONVERTING CYCLIC ALKYLENE UREAS INTO THEIR CORRESPONDING ALKYLENE AMINES
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Ten Kate, Antoon Jacob Berend
Veneman, Rens
Van Dam, Hendrik
Edvinsson, Rolf Krister
Raaijmakers, Michiel Jozef Thomas
Kantzer, Eike Nicolas
Ehlers, Ina
Jovic, Slavisa
Lake, Karl Fredrik
Wernersson, Stig Mikael
Abrégé
The invention relates to a process for converting one or more cyclic ethylene ureas into corresponding ethylene amines and carbon dioxide. In the process, water is contacted with one or more cyclic alkylene urea compounds comprising one or more cyclic alkylene urea moieties in a reaction vessel at a temperature of 150 to 400°C, optionally in the presence of an amine compound selected from the group of primary amines, cyclic secondary amines and bicyclic tertiary amines. The mole ratio of water to cyclic alkylene urea moieties is in the range of from 0.1 to 20. In the reaction, at least a portion of the cyclic alkylene urea moieties are converted to corresponding alkylenediamine moieties and carbon dioxide, and the carbon dioxide is removed from the liquid reaction mixture in a stripping vessel by feeding a stripping fluid to the stripping vessel, and removing a carbon dioxide-containing stripping fluid.
C07C 209/62 - Préparation de composés contenant des groupes amino liés à un squelette carboné par clivage de liaisons carbone-azote, soufre-azote ou phosphore-azote, p. ex. hydrolyse d'amides, N-déalkylation d'amines ou de composés d'ammonium quaternaire
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Veneman, Rens
Ten Kate, Antoon Jacob Berend
Lake, Karl Fredrik
Adrian Meredith, Jenny Valborg Therese
Raaijmakers, Michiel Jozef Thomas
Jovic, Slavisa
Edvinsson, Rolf Krister
Van Dam, Hendrik
Kantzer, Eike Nicolas
Ehlers, Ina
Abrégé
The invention pertains to a process for manufacturing a cyclic urea adduct of an ethyleneamine compound, the ethyleneamine compound having a linear -NH-CH2-CH2-NH- group, the process comprising the steps of - in an absorption step contacting a liquid medium comprising an ethyleneamine compound having a linear -NH-CH2-CH2-NH- group with a CO2-containing gas stream at a pressure of 1 -20 bara, resulting in the formation of a liquid medium into which CO2 has been absorbed, - bringing the liquid medium to cyclic urea formation conditions, and in an urea formation step forming cyclic urea adduct of the ethyleneamine compound, urea formation conditions including a temperature of at least 120°C, wherein the total pressure at the end of the urea formation step is at most 20 bara, wherein the temperature in the absorption step is lower than the temperature in the urea formation step. It has been found that the process according to the invention makes it possible to obtain cyclic urea adducts in an efficient manner in the absence of metal-containing catalysts and to perform the process under relatively mild conditions, in particular relatively low pressure. More specifically, by separating the CO2 absorption step from the urea formation step, the CO2 absorption step can be carried out at relatively low temperatures and pressures. And because the CO2 is already present in the system at the beginning of the urea formation step, the pressure in the urea formation step does not need to be high.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Ten Kate, Antoon Jacob Berend
Veneman, Rens
Raaijmakers, Michiel Jozef Thomas
Jovic, Slavisa
Edvinsson, Rolf Krister
Van Dam, Hendrik
Kantzer, Eike Nicolas
Ehlers, Ina
Skansen, Björn Patrik
Sarning, Michael Bertil Einar
Lake, Karl Fredrik
Wernersson, Stig Mikael
Abrégé
The present invention is directed to a process for converting cyclic alkyleneureas into their corresponding alkyleneamines wherein a feedstock comprising cyclic alkyleneureas is reacted in the liquid phase with water in an amount of 0. -20 mole water per mole urea moiety, at a temperature of at least 230°C, with removal of CO2. It has been found that the process according to the invention allows the efficient conversion of alkyleneureas into the corresponding alkyleneamines. The process has a high yield and low side product production. It is preferred for the cyclic alkyleneurea to comprises one or more of EU (ethyleneurea, the urea derivative of ethylenediamine (EDA)), UDETA (the urea derivative of diethylenetriamine (DETA)), UTETA (the group of urea derivatives of triethylenetetraamine (TETA), DUTETA (the diurea derivative of triethylenetetramine), UTEPAs (the urea derivatives of tetraethylenpentamine (TEPA)), DUTEPAs (the diurea derivatives of TEPA), or urea derivatives of pentaethylenehexamine (PEHA) and higher analogues, UAEEA (the urea derivative of aminoethylethanolannine), HE-UDETA (the urea derivative of hydroxyethyl diethylenetriamine), HE-UTETA (the urea derivative of hydroxyethyl triethylenetetraamine, HE-DUTETA (the diurea derivative of hydroxyethyl triethylenetetraamine), or any mixture of these.
C07C 209/16 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés avec formation de groupes amino liés à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Ten Kate, Antoon Jacob Berend
Lake, Karl Fredrik
Raaijmakers, Michiel Jozef Thomas
Edvinsson, Rolf Krister
Adrian Meredith, Jenny Valborg Therese
Veneman, Rens
Van Dam, Hendrik
Kantzer, Eike Nicolas
Ehlers, Ina
Jovic, Slavisa
Abrégé
A process for producing a cyclic alkylene urea product of Formula I: in which a compound of Formula II and/or Formula III is contacted in a reaction zone with a compound of Formula IV and/or Formula V and in the presence of one or more carbonyl delivering compounds; in which; R1qqR3; R21622; R316213133 alkyl groups; X is on each occurrence independently selected from −O−, −NR2−, groups of Formula VI, and groups of Formula VII and p and q are each independently selected from a whole number in the range of from 0 to 8; wherein the compound of Formula II and/or the compound of Formula III are added to a reaction zone comprising compound of Formula IV and/or compound of Formula (V) continuously or semi-continuously over a period of time, or in two or more batches.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Ehlers, Ina
Kantzer, Eike Nicolas
Edvinsson, Rolf Krister
Van Dam, Hendrik
Lake, Karl Fredrik
Ten Kate, Antoon Jacob Berend
Raaijmakers, Michiel Jozef Thomas
Veneman, Rens
Jovic, Slavisa
Abrégé
2p36366- unit can be linear or branched, by reacting (i) at least one of a hydroxy-functional compound chosen from the alkanolamine-functional compounds, and dihydroxyalkylene compounds, with (ii) an amine-functional compound,in the presence of (iii) a carbon oxide delivering agent, wherein at least one of the alkanolamine-functional compound, the amine-functional compound and/or the carbon oxide delivering agent contains at least one alkylene unit (A) that is a propylene unit
C07D 403/08 - Composés hétérocycliques contenant plusieurs hétérocycles, comportant des atomes d'azote comme uniques hétéro-atomes du cycle, non prévus par le groupe contenant deux hétérocycles liés par une chaîne carbonée contenant des cycles alicycliques
C07C 209/14 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés
C07D 295/04 - Composés hétérocycliques contenant des cycles polyméthylène imine d'au moins cinq chaînons, des cycles aza-3 bicyclo [3.2.2] nonane, piperazine, morpholine ou thiomorpholine, ne comportant que des atomes d'hydrogène liés directement aux atomes de carbone du cycle avec des radicaux hydrocarbonés substitués liés aux atomes d'azote du cycle
C07D 295/10 - Composés hétérocycliques contenant des cycles polyméthylène imine d'au moins cinq chaînons, des cycles aza-3 bicyclo [3.2.2] nonane, piperazine, morpholine ou thiomorpholine, ne comportant que des atomes d'hydrogène liés directement aux atomes de carbone du cycle avec des radicaux hydrocarbonés substitués liés aux atomes d'azote du cycle substitués par des atomes d'oxygène ou de soufre liés par des liaisons doubles
31.
WATER SOLUBLE PYRANINE POLYMERS AND METHOD OF MAKING
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Rodrigues, Klin Aloysius
Bailey, Andrew James
Jones, Jobie Lebron
Winkenwerder, Wyatt August
Band, Elliot Isaac
Abrégé
A method of making a pyranine monomer composition comprises the step of reacting pyranine with a functionalizing agent that functionalizes the pyranine molecule with a polymerizable functional group to provide a composition of functionalized pyranine monomers, said functionalization reaction taking place in an aqueous reaction medium, and in the presence of a molar excess of said functionalizing agent, such that the functionalization reaction product is a monomer composition substantially free of unfunctionalized pyranine compound. The pyranine monomer compositions made by the method can be used to make fluorescent tagged water soluble polymer compositions that advantageously are substantially free of unpolymerized pyranine. The fluorescent tagged water soluble polymer compositions can be used in a method of inhibiting scale in industrial water systems.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Kantzer, Eike Nicolas
Lake, Karl Fredrik
Ten Kate, Antoon Jacob Berend
Raaijmakers, Michiel Jozef Thomas
Veneman, Rens
Edvinsson, Rolf Krister
Ehlers, Ina
Sarning, Michael Bertil Einar
Berg, Robert Kristoffer
Van Dam, Hendrik
Abrégé
The invention pertains to a process to prepare ethylene amines with n ethyleneunits and n+1 amine groups wherein n is at least 4, or urea derivatives of said ethylene amines, by reacting an ethanolamine-functional compound, an amine-functional compound, and a carbon oxide delivering agent, wherein the ethanolamine-functional compound is of the formula HO-(C2H4-NH-)qH, q is at least 1, the amine-functional compound is of the formula H2N-(C2H4-NH-)rH, r is at least 1, the sum q+r is at least 4 and wherein optionally one or more of the ethanol-amine functional compound or amine-functional compound are at least partly used as their cyclic carbamate derivative, or linear or cyclic urea derivative. The process provides TEPA and higher ethylene amines in high yield and high selectivity, without having to use expensive or hazardous startingmaterials. Various urea derivatives of TEPA and PEHA are also claimed.
C07C 209/16 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés avec formation de groupes amino liés à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons
C07C 211/14 - Amines contenant des groupes amino liés à au moins deux groupes aminoalkyle, p. ex. diéthylènetriamines
33.
PROCESS FOR MANUFACTURING A MIXTURE OF STRAIGHT-CHAIN AND NON-STRAIGHT-CHAIN ETHYLENEAMINES
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Van Dam, Hendrik
Lake, Karl Fredrik
Kantzer, Eike Nicolas
Ten Kate, Antoon Jacob Berend
Edvinsson, Rolf Krister
Raaijmakers, Michiel Jozef Thomas
Veneman, Rens
Ehlers, Ina
Adrian Meredith, Jenny Valborg Therese
Jovic, Slavisa
Abrégé
The invention pertains to a process for manufacturing a mixture of straight-chain higher ethyleneamines and non-straight-chain higher ethyleneamines selected from branched higher ethyleneamines and cyclic higher ethyleneamines, or the urea derivatives thereof, comprising the step of reacting amine-functional compound with ethanolamine-functional compound in the presence of a carbon oxide delivering agent, wherein a) amine-functional compound comprising a combination of straight-chain amine- functional compound and non-straight-chain amine-functional compound is reacted with straight-chain ethanolamine-functional compound, or b) straight-chain amine-functional compound is reacted with ethanolamine-functional compound comprising a combination of straight-chain ethanolamine-functional compound and non-straight-chain ethanolamine-functional compound, or c) amine-functional compound comprising a combinationof straight-chain amine-functional compound and non-straight-chain amine-functional compound is reacted with ethanolamine-functional compound comprising a combination of straight-chain ethanolamine-functional compound and non-straight-chain ethanolamine-functional compound. It has been found that the process according to the invention makes it possible to prepare tailor-made mixtures of straight-chain and non-straight-chain higher ethyleneamines, or urea derivatives thereof.
C07D 295/125 - Composés hétérocycliques contenant des cycles polyméthylène imine d'au moins cinq chaînons, des cycles aza-3 bicyclo [3.2.2] nonane, piperazine, morpholine ou thiomorpholine, ne comportant que des atomes d'hydrogène liés directement aux atomes de carbone du cycle avec des radicaux hydrocarbonés substitués liés aux atomes d'azote du cycle substitués par des atomes d'azote liés par des liaisons simples ou doubles avec les atomes d'azote du cycle et les atomes d'azote substituants liés à la même chaîne carbonée, qui n'est pas interrompue par des cycles carbocycliques
C07C 209/16 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés avec formation de groupes amino liés à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons
C07C 201/00 - Préparation d'esters d'acide nitrique ou nitreux ou de composés contenant des groupes nitro ou nitroso liés à un squelette carboné
34.
PROCESS TO PREPARE ETHYLENE AMINES AND ETHYLENE AMINE DERIVATIVES
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Raaijmakers, Michiel Jozef Thomas
Ten Kate, Antoon Jacob Berend
Veneman, Rens
Lake, Karl Fredrik
Jovic, Slavisa
Kantzer, Eike Nicolas
Ehlers, Ina
Edvinsson, Rolf Krister
Skansen, Björn Patrik
Sarning, Michael Bertil Einar
Adrian Meredith, Jenny Valborg Therese
Van Dam, Hendrik
Abrégé
224P242424q224rrH wherein r is at least 1 in the presence of a carbon oxide delivering agent, wherein the molar ratio of ethanolamine-functional compound to amine-functional compound is between 0.05:1 and 0.7:1 and the molar ratio of carbon oxide delivering agent to amine-functional compound is higher than the molar ratio of ethanolamine-functional compound to amine-functional compound, provided that the process is not the process of reacting 3 moles ethylenediamine (EDA) and 1 mole AEEA (aminoethylethanolamine) in the presence of 1.65 moles of urea at 280 deg C for 2 hours.
C07D 233/36 - Un atome d'oxygène avec des radicaux hydrocarbonés, substitués par des atomes d'azote, liés aux atomes d'azote du cycle
C07D 295/13 - Composés hétérocycliques contenant des cycles polyméthylène imine d'au moins cinq chaînons, des cycles aza-3 bicyclo [3.2.2] nonane, piperazine, morpholine ou thiomorpholine, ne comportant que des atomes d'hydrogène liés directement aux atomes de carbone du cycle avec des radicaux hydrocarbonés substitués liés aux atomes d'azote du cycle substitués par des atomes d'azote liés par des liaisons simples ou doubles avec les atomes d'azote du cycle et les atomes d'azote substituants liés à la même chaîne carbonée, qui n'est pas interrompue par des cycles carbocycliques à une chaîne acyclique saturée
C07C 209/16 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés avec formation de groupes amino liés à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons
C07C 211/14 - Amines contenant des groupes amino liés à au moins deux groupes aminoalkyle, p. ex. diéthylènetriamines
35.
PROCESS TO PREPARE HIGHER ETHYLENE AMINES OR UREA DERIVATIVES THEREOF
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Veneman, Rens
Ten Kate, Antoon Jacob Berend
Raaijmakers, Michiel Jozef Thomas
Kantzer, Eike Nicolas
Edvinsson, Rolf Krister
Lake, Karl Fredrik
Ehlers, Ina
Jovic, Slavisa
Van Dam, Hendrik
Hagberg, Lars Torbjörn
Abrégé
224p2424q24q24224rrH wherein r is at least 1 in the presence of a carbon oxide delivering agent and water, with a molar ratio of water : carbon oxide delivering agent of from 0.01:1 to 2:1.
C07D 233/36 - Un atome d'oxygène avec des radicaux hydrocarbonés, substitués par des atomes d'azote, liés aux atomes d'azote du cycle
C07C 209/16 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés avec formation de groupes amino liés à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons
C07C 211/14 - Amines contenant des groupes amino liés à au moins deux groupes aminoalkyle, p. ex. diéthylènetriamines
36.
PROCESS TO TREAT CARBONATITIC NON-SULFIDIC ORES AND COLLECTOR COMPOSITION THEREFOR
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Smolko-Schvarzmayr, Natalija
Gustafsson, Charlotte Ewa Karin
Wetzel, Alexander Michael
Ljungdahl, Göran Thomas
Schwarzmayr, Louis
Janiak, John André
Widell, Mikael Ivar
Abrégé
The present invention relates to a process to treat carbonatitic non-sulfidic ores with a collector composition that comprises a phosphate compound of the formula (I) wherein R is linear or branched, saturated or unsaturated hydrocarbon group containing 1 to 24 carbon atoms that, A is an alkylene oxide unit; Y is H, Na, K or an ammonium or alkylated ammonium, n is 1 - 3, p is 0 - 25, X is chosen from the same groups as R-Ap- or Y, or when n is 2 or 3, the -O-X and an -O-Y may be a single -O- bound to give a cyclic phosphate, to a collector composition containing the phosphate compound of the formula I as a primary collector in combination with a secondary collector and to a pulp composition containing the phosphate compound of the formula (I).
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Smolko-Schvarzmayr, Natalija
Abrégé
The present invention relates to a process to treat siliceous non-sulfidic ores with a collector composition that comprises a phosphate compound of the formula (I) wherein R is linear or branched, saturated or unsaturated hydrocarbon group containing 1 to 24 carbon atoms that, A is an alkylene oxide unit; Y is H, Na, K or an ammonium or alkylated ammonium, n is 1 - 3, p is 0 - 25, X is chosen from the same groups as R-Ap- or Y, to a collector composition containing the phosphate compound of the formula I as a primary collector in combination with a secondary collector and to a pulp composition containing the phosphate compound of the formula (I).
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Van Haeren, Paulus Johannes Cornelis
Doppen, Roy Gérard
Schomaker, Elwin
Vaessen, Raymond Jean Cécile
Ypma, Marco
Oudenhoven, Stijn
Heus, Martin
Abrégé
The present invention relates to a process for the preparation of a solid composition of an amino acid diacetic acid compound wherein the amino acid diacetic acid compound is methyl glycine-N,N-diacetic acid or a salt thereof, or glutamic N,N-diacetic acid or a derivative thereof, containing a step of feeding a saturated or oversaturated aqueous composition of the amino acid diacetic acid compound in an aqueous solvent to a drum dryer,wherein the aqueous composition is fed to the drum surface with a layer thickness of 0.1-10 mm, the drum has a surface temperature of 80-180°C, and the drum operates at a tangential speed of 0.1 -100 m/min and the mass is removed from the drum before a full revolution of the drum, and the product obtainable by the process.
C07C 229/04 - Composés contenant des groupes amino et carboxyle liés au même squelette carboné ayant des groupes amino et carboxyle liés à des atomes de carbone acycliques du même squelette carboné le squelette carboné étant acyclique et saturé
C07C 229/24 - Composés contenant des groupes amino et carboxyle liés au même squelette carboné ayant des groupes amino et carboxyle liés à des atomes de carbone acycliques du même squelette carboné le squelette carboné étant acyclique et saturé ayant plus d'un groupe carboxyle lié au squelette carboné, p. ex. acide aspartique
39.
SODIUM METHYL GLYCINE-N,N-DIACETIC ACID COMPOUND, PROCESS TO PREPARE IT AND USE THEREOF
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Schomaker, Elwin
Van Haeren, Paulus Johannes Cornelis
Heus, Martin
Doppen, Roy Gérard
Abrégé
The present invention relates to a methylglycine-N,N-diacetic acid trisodium salt in the form of a crystal, comprising a crystalline modification referred to as crystal type III characterized by the below reflections when analyzed with X-ray diffraction analysis using Cu Kα radiation. The invention furthermore relates to compositions containing the crystal type III salt, to a process to prepare it, to the use thereof and to the rehydrated crystal type I that can be obtained by contacting crystal type III with water. (Type III)
C07C 229/16 - Composés contenant des groupes amino et carboxyle liés au même squelette carboné ayant des groupes amino et carboxyle liés à des atomes de carbone acycliques du même squelette carboné le squelette carboné étant acyclique et saturé ayant un seul groupe amino et un seul groupe carboxyle liés au squelette carboné l'atome d'azote du groupe amino étant lié de plus à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons à des atomes de carbone de radicaux hydrocarbonés substitués par des groupes amino ou carboxyle, p. ex. acide éthylènediaminetétra-acétique, acides iminodiacétiques
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Górak, Andrej
Skiborowski, Mirko
Kuhlmann, Hanns
Ranft, Daniel
Abrégé
The present invention pertains to a process for recovering acetic acid from an aqueous stream containing acetic acid, comprising the steps of (a) contacting the aqueous stream with tri-n-octylamine and 1-undecanol, with the weight ratio between tri-n-octylamine and 1-undecanol being between 0.8 : 1 and 5 : 1, to produce (I) an organic phase comprising acetic acid, tri-n-octylamine and 1-undecanol, and (II) an aqueous phase; and (b) isolating acetic acid from the organic phase (I).
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Li, Lingling
Gadberry, James Frederic
O'Neal, Tiara Elizabeth
Khandekar, Chandrashekhar Yeshwant
Abrégé
This disclosure relates to winterized pour point depressant compositions for petroleum fluids. Such compositions exhibit stability and are flowable at temperatures down to as low as -47°C, without the need for further dilution.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Lake, Karl Fredrik
Kantzer, Eike Nicolas
Edvinsson, Rolf Krister
Ehlers, Ina
Van Dam, Hendrik
Adrian Meredith, Jenny Valborg Therese
Hagberg, Lars Torbjörn
Ten Kate, Antoon Jacob Berend
Veneman, Rens
Raaijmakers, Michiel Jozef Thomas
Jovic, Slavisa
Abrégé
The invention pertains to a process for manufacturing a cyclic urea adduct of an ethyleneamine compound, the ethyleneamine compound being selected from the group of ethyleneamines and hydroxyethylethyleneamines and comprising at least one –NH-CH2-CH2-NH-moiety and at least two ethylene moieties, wherein the ethyleneamine compound is reacted with CO2 in the presence of an auxiliary compound selected from ethylenediamine (EDA), monoethanolamine (MEA) and mixtures thereof, the molar ratio of auxiliary compound to amine compound being at least 0.02:1. It has been found that the presence of an auxiliary compound selected from ethylenediamine (EDA), monoethanolamine (MEA) and mixtures thereof leads to a substantial increase of the reaction rate as compared to a process wherein the auxiliary compound is not present.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Van Der Schuur, Jan Martijn
Fischer, Bart
Tammer, Martinus Catharinus
Frijns, Maurice Ludovicus Josephina
Abrégé
Process for manufacturing a polyethylene homo-or copolymer by conducting polymerization of ethylene, optionally in combination with one or more co- monomers, at a pressure in the range 500-5000 bar, wherein bis(n-butanoyl) peroxide is used as polymerization initiator.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Bataweel, Mohammed A.
Huang, Jin
Almohsin, Ayman Mohammed
Karadkar, Prasad Baburao
Sundblom, Andreas Ake
Lagnemo, Hans Olof
Restorp, Per Anders
Abrégé
A composition useful for subterranean water or gas shut off applications includes organosilane-modified colloidal silica and an accelerator. The accelerator includes one or more organic or inorganic salts. A method of using a composition, including an organosilane-modified colloidal silica and an accelerator, includes forming a fluid system that is flowed to a formation in a subterranean zone, such as through a wellbore, where the composition forms a gel to plug the formation and shut off water flow into the wellbore.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Brunelle, Patrick
Miles, Jason Victor
Selse, Dennis
Abrégé
The invention relates to oil-in-water (water continuous) emulsions that can be used as fuels, and which have high static and dynamic stability, to a process for their preparation, and to fuel compositions comprising such emulsions.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Craige, Simon
Miles, Jason Victor
Selse, Dennis
Krigsman, Joakim
Abrégé
The invention relates to an oil-in-water emulsion comprising an oil phase and an aqueous phase, and a primary surfactant, wherein the oil phase is dispersed in the aqueous phase, and wherein the oil-in-water emulsion has: an average droplet size distribution (D[4,3]) in the range of from 3 to 15 µmand less than 3wt% of the droplets have a particle size of greater than 125 µm;a viscosity of greater than 100 and up to 700 mPas at 50oC ±10% and 20 s-1±10%;and a static stability of less than 5% residue after centrifugation at 50oC ±10% and 2000g ±10% for 30 minutes±10%. A process for preparing such an oil-in-water emulsion comprises preparing an aqueous phase comprising a primary surfactant, heating a hydrocarbon-containing oil-phase, and blending the hydrocarbon-containing oil and the aqueous phase under conditions sufficient to form an oil-in-water emulsion. The invention also relates to methods for determining the static and dynamic stability of oil-in-water emulsions. Static stability can be determined by a method comprising the steps of: providing an oil-in-water emulsion;centrifuging the oil-in-water emulsion under predetermined conditions for a predetermined period of time; determining the amount of residue deposited from the oil-in-water emulsion after the predetermined period of time; and determining the oil-in-water emulsion's static stability. A method for determining the dynamic stability of an oil-in-water emulsion comprises the steps of: providing an oil-in-water emulsion;analysing the oil-in-water emulsion at a first time; recirculating the oil-in-water emulsion in a recirculation loop; and analysing the oil-in- water emulsion at second time after recirculation has started; in which the oil-in-water emulsion's dynamic stability is determined based on the analysis at the first and second times.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Lewis, Andrew Clist
Siirak, Johan
Cassel, Anders Öijar
Smolko-Schvarzmayr, Natalija
Slikta, Alberto
Abrégé
The present invention relates to a process to treat metal or mineral ores with a collector composition that comprises a nitrile group-containing compound of the formula (I) wherein R is a saturated or unsaturated, linear or branched, hydrocarbon group containing 8 to 26 carbon atoms, R' = O or (II) or (III) or (IV) R'' is a saturated or unsaturated, linear or branched, hydrocarbon group containing 1 to 26 carbon atoms or a hydrogen atom or (-(D)j-CnH2nCN) group or R-((A)m-(B))x group, A is (-0-CH2CH2-); (-O-CH(CH3)CH2-) or (-O-CH(CH2CH3)CH2-) B is (-O-CpH2p-) D is (-CH2CH2-O-); (-CH(CH3)CH2-O-) or (-CH(CH2CH3)CH2-O-) x is 0 or 1 R''' is hydrocarbon group containing 1 to 4 carbon atoms Y is halide or methylsulfate m, j are each independently an integer of 0-5 R'''' is a saturated or unsaturated, linear or branched, hydrocarbon group containing 1 to 26 carbon atoms and n and p are each independently an integer of 1 to 5. The invention also relates to collector composition containing the above nitrile group-containing compound and at least one further collector or frother compound.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Ten Kate, Antoon Jacob Berend
Raaijmakers, Michiel Jozef Thomas
Veneman, Rens
Lake, Karl Fredrik
Berg, Robert Kristoffer
Kantzer, Eike Nicolas
Edvinsson, Rolf Krister
Van Dam, Hendrik
Ehlers, Ina
Abrégé
The invention pertains to a process for preparing hydroxyethylethyleneamines, ethyleneamines, or mixtures thereof, and/or ethylene urea derivatives thereof comprising the step of reacting diethanolamine with an amine-functional compound comprising at least two –NH-units of which at least one is selected from the group of primary amine groups and cyclic secondary amine groups, the amine-functional compound comprising at least one –NH-CH2-CH2-NH-unit wherein one or more -NH- CH2-CH2-NH-units in the amine-functional compound may be present in the form of cyclic ethylene urea moieties, piperazine moieties, or linear ethylene urea moieties, in the presence of a carbon oxide delivering agent, wherein -the molar ratio of amine-functional compound to diethanolamine is at least 0.2:1, and -the molar ratio of carbon oxide delivering agent to –NH-CH2-CH2-NH-units in the amine-functional compound is at least 0.1:1. The invention makes it possible to obtain higher hydroxyethylethyleneamines, ethyleneamines, or mixtures thereof, and/or ethylene urea derivatives thereof from diethanolamine, which is an attractive starting material.
C07C 209/16 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés avec formation de groupes amino liés à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons
C07C 211/14 - Amines contenant des groupes amino liés à au moins deux groupes aminoalkyle, p. ex. diéthylènetriamines
C07D 233/36 - Un atome d'oxygène avec des radicaux hydrocarbonés, substitués par des atomes d'azote, liés aux atomes d'azote du cycle
C07D 295/13 - Composés hétérocycliques contenant des cycles polyméthylène imine d'au moins cinq chaînons, des cycles aza-3 bicyclo [3.2.2] nonane, piperazine, morpholine ou thiomorpholine, ne comportant que des atomes d'hydrogène liés directement aux atomes de carbone du cycle avec des radicaux hydrocarbonés substitués liés aux atomes d'azote du cycle substitués par des atomes d'azote liés par des liaisons simples ou doubles avec les atomes d'azote du cycle et les atomes d'azote substituants liés à la même chaîne carbonée, qui n'est pas interrompue par des cycles carbocycliques à une chaîne acyclique saturée
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Zaitsev, Alexey Borisovich
Abrégé
The present invention pertains to a method for determining the total iron content in a sample comprising Fe3+, comprising the steps of a) combining the sample comprising Fe3+ with an organic reducing agent and a chromogenic compound capable of forming a colored complex with Fe2+ in a liquid phase to form a mixture, resulting in reduction of the Fe3+ to Fe2+, and complexation of the Fe2+ with the chromogenic compound to form a complex of Fe2+ and the chromogenic compound, b) determining the absorption of light of the liquid phase or a fraction thereof at an absorption wavelength of the complex of Fe2+ and the chromogenic compound, and c) calculating the iron content of the sample from the absorption of light, with reference to a standard absorption curve for the complex of Fe2+ and the chromogenic compound, wherein in step a) the mixture further comprises a water-soluble calcium salt. It has been found that the provision of a water-soluble calcium salt leads to an increase in the reduction rate, in particular in a sample wherein the Fe3+ is present in the form of a complex.
G01N 33/84 - Analyse chimique de matériau biologique, p. ex. de sang ou d'urineTest par des méthodes faisant intervenir la formation de liaisons biospécifiques par ligandsTest immunologique faisant intervenir des composés inorganiques ou le pH
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Zhu, Shawn
Thomaides, John Socrates
Cocuzza, Devon
Morales, John M.
Boracci, Andrew Richard
He, Qiwei
Martino, Gary Theodore
Abrégé
A sunscreen formulation comprises an oil carrier, a particulate metal oxide sunscreen active agent and a polymeric rheology modifier that maintains the particulate sunscreen active agent in a stable dispersion in the formulation. In one aspect the polymeric rheology modifier is obtainable by co-polymerizing a monomer mixture comprising at least one alkyl (meth)acrylate and at least one of the following monomers: a bicyclic (meth)acrylate ester different from the alkyl (meth)acrylate, and an aromatic vinyl monomer. In one embodiment the polymeric rheology modifier is crosslinked.
A61Q 17/04 - Préparations topiques pour faire écran au soleil ou aux radiationsPréparations topiques pour bronzer
A61K 8/81 - Cosmétiques ou préparations similaires pour la toilette caractérisés par la composition contenant des composés organiques macromoléculaires obtenus par des réactions faisant intervenir uniquement des liaisons insaturées carbone-carbone
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Zhu, Shawn
Thomaides, John Socrates
Boracci, Andrew Richard
Adamo, Anthony John
Principe-Frank, Diane
He, Qiwei
Morales, John M.
Abrégé
Disclosed are thickened organic liquid compositions comprising an organic liquid and a polymeric rheology modifier wherein the polymeric rheology modifier is obtainable by co- polymerizing at least two of a bicyclic (meth) acrylate ester, an alkyl (meth) acrylate, and an aromatic vinyl monomer. Also disclosed are thickened organic liquid dispersions with suspended solids and methods of stabilizing dispersions using polymeric rheology modifiers.
C08F 220/18 - Esters des alcools ou des phénols monohydriques des phénols ou des alcools contenant plusieurs atomes de carbone avec l'acide acrylique ou l'acide méthacrylique
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Smolko-Schvarzmayr, Natalija
Ljungdahl, Göran Thomas
Ekeroth, Johan
Kleberger Hellström, Åsa Hele'N Jeanette
Svensson, Emelie
Abrégé
The present invention relates to a process for treating non-sulfidic ores with a collector composition containing a primary and a secondary collector,wherein the primary collector is selected from the group of amphoteric and anionic surface active compounds and the secondary collector is an ethoxylated fatty acid wherein the average degree of ethoxylation is higher than 0 and less than 2, to collector compositions suitable for use in the above process,and to pulp comprising such collector compositions.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Kantzer, Eike Nicolas
Lake, Karl Fredrik
Ten Kate, Antoon Jacob Berend
Raaijmakers, Michiel Jozef Thomas
Veneman, Rens
Ehlers, Ina
Sarning, Michael Bertil Einar
Van Dam, Hendrik
Edvinsson, Rolf Krister
Abrégé
The invention pertains to a process for preparing hydroxyethyl ethylene amines and/or ethylene urea derivatives thereof comprising the step of reacting monoethylene glycol with an amine-functional compound comprising at least two -NH- units of which at least one is selected from the group of primary amine groups and cyclic secondary amine groups, the amine-functional compound comprising at least one –NH-CH2-CH2-NH- unit, wherein one or more -NH-CH2-CH2-NH- units in the amine-functional compound may be present in the form of piperazine moieties or ethylene urea moieties, in the presence of a carbon oxide-delivering agent, wherein - the molar ratio of amine-functional compound to monoethylene glycol is in the range of 0.2:1 to 1.5:1 and - the molar ratio of carbon oxide-delivering agent to –NH-CH2-CH2-NH- units in the amine-functional compound is at least 0.5:1. The process according to the invention allows the conversion of monoethylene glycol into ethanol amines in the absence of metals-containing catalysts, and without using ammonia, and preferably with high yield.
C07C 213/02 - Préparation de composés contenant des groupes amino et hydroxy, amino et hydroxy éthérifiés ou amino et hydroxy estérifiés liés au même squelette carboné par des réactions impliquant la formation de groupes amino à partir de composés contenant des groupes hydroxy ou des groupes hydroxy éthérifiés ou estérifiés
C07C 215/12 - Composés contenant des groupes amino et hydroxy liés au même squelette carboné ayant des groupes hydroxy et des groupes amino liés à des atomes de carbone acycliques du même squelette carboné le squelette carboné étant saturé et acyclique l'atome d'azote du groupe amino étant de plus lié à des groupes hydrocarbonés substitués par des groupes hydroxy
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Kantzer, Eike Nicolas
Lake, Karl Fredrik
Ten Kate, Antoon Jacob Berend
Raaijmakers, Michiel Jozef Thomas
Veneman, Rens
Ehlers, Ina
Sarning, Michael Bertil Einar
Van Dam, Hendrik
Edvinsson, Rolf Krister
Adrian Meredith, Jenny Valborg Therese
Abrégé
The invention pertains to a process for preparing polyethyleneamines of the formula NH2-(CH2-CH2-NH-)pH wherein p is at least 3, wherein one or more -NH-CH2-CH2-NH- units may be present as piperazine units and/or ethylene urea derivatives of these compounds, comprising the step of reacting monoethylene glycol with an amine-functional compound comprising at least two -NH- units of which at least one is selected from the group of primary amine groups and cyclic secondary amine groups, in the presence of a carbon oxide-delivering agent, the amine-functional compound comprising at least one –NH-CH2-CH2-NH- unit, wherein one or more -NH-CH2-CH2- NH- units in the amine-functional compound may be present in the form of cyclic ethylene urea moieties, piperazine moieties, or linear ethylene urea moieties, wherein - the molar ratio of amine-functional compound to monoethylene glycol is above 1.2:1 and - the molar ratio of carbon oxide delivering agent to –NH-CH2-CH2-NH- units in the amine-functional compound is at least 0.5:1. It has been found that the process according to the invention makes it possible to obtain ethylene amines and derivatives thereof via a process which makes use of an attractive starting material, with relatively high yield, without having to use ammonia or metal-containing catalysts.
C07C 209/16 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés avec formation de groupes amino liés à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons
C07C 209/62 - Préparation de composés contenant des groupes amino liés à un squelette carboné par clivage de liaisons carbone-azote, soufre-azote ou phosphore-azote, p. ex. hydrolyse d'amides, N-déalkylation d'amines ou de composés d'ammonium quaternaire
C07D 403/06 - Composés hétérocycliques contenant plusieurs hétérocycles, comportant des atomes d'azote comme uniques hétéro-atomes du cycle, non prévus par le groupe contenant deux hétérocycles liés par une chaîne carbonée ne contenant que des atomes de carbone aliphatiques
56.
METHYL HYDROXYETHYL CELLULOSE AS A DRIFT CONTROL AGENT AND RAINFASTNESS AGENT
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Zhang, Lei
Battal, Turgut
Paul, Rupak
Schröder, Ulf
Abrégé
The present invention is directed to a method of spraying an aqueous solution of an agrochemical comprising at least one cellulose ether, wherein the cellulose ether is a methyl hydroxyethyl cellulose (MHEC) polymer. The present invention is also directed to a method for reducing spray drift during the spraying of an aqueous solution. The methods comprise: providing a MHEC polymer; combining the MHEC polymer with at least one agricultural chemical and water to obtain an aqueous solution; and spraying the aqueous solution. Further, the present invention is also directed to a method for providing good resistance to rain wash-off of an agricultural chemical which was deposited onto a surface by spraying. This method comprises: providing a MHEC polymer; combining the MHEC polymer with at least one agricultural chemical and water to obtain an aqueous solution; spraying the aqueous solution onto a surface; and evaporating at least part of the water of the droplets of the aqueous solution which were deposited onto the surface by said spraying.
A01N 25/24 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, caractérisés par leurs formes, ingrédients inactifs ou modes d'applicationSubstances réduisant les effets nocifs des ingrédients actifs vis-à-vis d'organismes autres que les animaux nuisibles contenant des ingrédients augmentant l'adhérence des ingrédients actifs
A01N 25/30 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, caractérisés par leurs formes, ingrédients inactifs ou modes d'applicationSubstances réduisant les effets nocifs des ingrédients actifs vis-à-vis d'organismes autres que les animaux nuisibles caractérisés par les agents tensio-actifs
A01N 31/06 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, contenant des composés organiques de l'oxygène ou du soufre l'atome d'oxygène ou de soufre étant lié directement à un système cyclique cycloaliphatique
A01N 37/40 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, contenant des composés organiques comportant un atome de carbone possédant trois liaisons à des hétéro-atomes, avec au plus deux liaisons à un halogène, p. ex. acides carboxyliques contenant au moins un groupe carboxylique ou un thio-analogue, ou d'un de leurs dérivés, et un atome d'oxygène ou de soufre lié par une liaison simple, liés au même squelette carboné, cet atome d'oxygène ou de soufre ne faisant pas partie d'un groupe carboxylique ou d'un thio-analogue, ou d'une de leurs dérivés, p. ex. acides hydroxycarboxyliques contenant au moins un atome d'oxygène ou de soufre lié à un système cyclique aromatique contenant au moins un groupe carboxylique ou un thio-analogue, ou un de leurs dérivés, et un atome d'oxygène ou de soufre liés au même système cyclique aromatique
A01N 57/20 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, contenant des composés organiques du phosphore comportant des liaisons phosphore-carbone contenant des radicaux acycliques ou cycloaliphatiques
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Nowak, John Douglas
Rahman, Mohammad Abdur
Hou, Xiaowen
Band, Elliot Isaac
Yu, Hua
Abrégé
The present invention relates to a method of stabilizing an aqueous solution of polystyrene sulfonic acid and the compositions therein. This disclosure provides polymer stability in that there is minimal deterioration of the molecular weight of said polymers at or around 25 °C and the stabilizers of the disclosure reduce the need for low temperature refrigeration during transport and storage of polystyrene sulfonic acid.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Kruis, Aleksander Johannes
Levisson, Mark
Mars, Astrid Elisabeth
Kengen, Servatius Wilhelmus Maria
Van Der Oost, John
Sanders, Johan Pieter Marinus
Weusthuis, Ruud Alexander
Abrégé
The present invention relates to a process for the production of ethyl acetate wherein a polypeptide having alcohol acetyl transferase activity converts ethanol and acetyl coenzyme A into ethyl acetate. The polypeptide has an alpha-beta hydrolase fold and an active site comprising a serine, histidine, and optionally aspartic acid in its three-dimensional structure. The polypeptides according to the invention are genes isolated from Kluyveromyces marxianus, Kluyveromyces lactis, Wickerhamomyces ciferrii, Cyberlindnera jadinii, Hanseniaspora uvarum, Eremothecium cymbalarie and Saccharomyces cerevisiae.
C12N 5/00 - Cellules non différenciées humaines, animales ou végétales, p. ex. lignées cellulairesTissusLeur culture ou conservationMilieux de culture à cet effet
C07K 14/00 - Peptides ayant plus de 20 amino-acidesGastrinesSomatostatinesMélanotropinesLeurs dérivés
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Beek, Waldo Joseph Elisabeth
Abrégé
Peroxide masterbatch comprising: - 15-55 wt% of one or more organic peroxides, - 15-45 wt% of one or more copolymers of at least two different monomers, the first monomer being ethylene or propylene, the second monomer being a vinyl monomer comprising at least four carbon atoms and optionally heteroatoms, - 6-70 wt% of at least two filler types –filler type 1 and filler type 2 - each having a different BET surface area: (i) filler type 1 being present in the masterbatch in a concentration of 3-30 wt% and having a BET surface area of more than 100 m2/g; (ii) filler type 2 being present in the masterbatch in a concentration of 3-40 wt% and having a BET surface area of 100 m2/g or less; wherein the masterbatch has the form of extrudates.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Beek, Waldo Joseph Elisabeth
Nijhof, Leonardus Bernardus Gerhardus Maria
Abrégé
Peroxide masterbatch comprising: - 15-55 wt% of one or more organic peroxides, - 15-45 wt% of at least one copolymer of (i) ethylene or propylene and (ii) 1-butene and/or 1-octene, and 13-45 wt% of at least two types of fillers - filler type 1 and filler type 2 - each having a different BET surface area: (i) filler type 1 being present in the masterbatch in a concentration of 3-15 wt% and having a BET surface area of more than 100 m2/g; (ii) filler type 2 being present in the masterbatch in a concentration of 10-30 wt% and having a BET surface area of 100 m2/g or less.
01 - Produits chimiques destinés à l'industrie, aux sciences ainsi qu'à l'agriculture
17 - Produits en caoutchouc ou en matières plastiques; matières à calfeutrer et à isoler
Produits et services
(1) Artificial resins as raw material, plastics as raw material; synthetic resins as raw material; chemical preparations for use in the manufacture of unprocessed artificial resins for curing artificial resins; thermoplastic elastomers as raw material; chemical compounds with a base of synthetic resins as raw material used in the paper and plastics industry; chemical preparations for use in the manufacture of synthetic resins; chemical additives for fuels; chemical additives for coatings and plastics; chemical preparations for use in the manufacture of lacquers and varnish; chemical preparations for use in the manufacture of construction building materials, namely profiles, gratings, floor tiles, roof tiles and façade panels; chemical preparations for use in the manufacture of adhesives
(2) Semi-manufactured plastic products, namely semi-processed plastics; semi-processed synthetic resins; non-metallic flexible tubes of plastic for general industrial or manufacturing use; plastic packing for shipping containers, rubber sheets for packing purposes; semi-processed thermoplastic polymer resins for use in manufacture; synthetic rubber in the form of raw materials and semi-manufactured materials; sheets and panels out of synthetic fibres, namely sheets and panels of synthetic plastic for general industrial use; semi-manufactured microporous plastic tapes, plastic strips, plastics sheets to be used in roof tops
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Van Der Schuur, Jan Martijn
Fischer, Bart
Frijns, Maurice Ludovicus Josephina
Tammer, Martinus Catharinus
Abrégé
Process for manufacturing a polyethylene homo-or copolymer by conducting high-pressure polymerization of ethylene, optionally in combination with one or more co-monomers, in a tubular reactor, wherein tert-amyl peroxyisobutyrate is used as polymerization initiator.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Aberle, Thomas
Abrégé
The invention relates to the use of a building composition marker comprising at least one alpha-amino acid, alpha-amino acid salt or a mixture thereof in a building composition. The invention also relates to a building composition comprising such a building composition marker, and to a process for producing the building composition. The invention further relates to a building composition marker comprising at least one alpha-amino acid, alpha-amino acid salt or mixture thereof, and one or more components selected from: - vinyl ester homopolymers, vinyl ester copolymers comprising one or more vinyl ester units and one or more monomer units from the group selected from olefins, vinylaromatics, vinyl halides, acrylic esters, methacrylic esters, monoesters or diesters of fumaric and/or maleic acid, or silicon-functional monomers; - (meth)acrylic ester homopolymers, (meth)acrylic ester copolymers comprising one or more (meth)acrylic ester units and one or more monomer units from the group of vinylaromatics, vinyl halides, monoesters or diesters of fumaric and/or maleic acid, or silicon-functional monomers; - homopolymers or copolymers of dienes and also of olefins, diene copolymers comprising one or more diene units and one or more monomer units from the group selected from vinyl halides, (meth)acrylic esters, esters of fumaric or maleic acid, and vinylaromatics; - homopolymers of vinylaromatics; - homopolymers of vinyl halides; and - polysaccharides, polysaccharide ethers, and mixtures thereof.
C04B 28/02 - Compositions pour mortiers, béton ou pierre artificielle, contenant des liants inorganiques ou contenant le produit de réaction d'un liant inorganique et d'un liant organique, p. ex. contenant des ciments de polycarboxylates contenant des ciments hydrauliques autres que ceux de sulfate de calcium
C04B 40/00 - Procédés, en général, pour influencer ou modifier les propriétés des compositions pour mortiers, béton ou pierre artificielle, p. ex. leur aptitude à prendre ou à durcir
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Aberle, Thomas
Abrégé
External thermal insulation composite system (ETICS) mortar composition comprising one or more inorganic binders, at least one polymer selected from Vinyl-ester co-polymers containing one or more vinyl ester units and one or more monomer units selected from the group consisting of olefins, vinyl aromatics, vinyl halides, acrylic esters, methacrylic esters, monoesters or diesters of fumaric and/or maleic acid, and silicon-functional monomers,wherein the ETICS mortar composition comprises at least one alpha-amino acid, an alpha-amino acid salt or a mixture thereof.
C04B 28/02 - Compositions pour mortiers, béton ou pierre artificielle, contenant des liants inorganiques ou contenant le produit de réaction d'un liant inorganique et d'un liant organique, p. ex. contenant des ciments de polycarboxylates contenant des ciments hydrauliques autres que ceux de sulfate de calcium
C04B 40/00 - Procédés, en général, pour influencer ou modifier les propriétés des compositions pour mortiers, béton ou pierre artificielle, p. ex. leur aptitude à prendre ou à durcir
66.
THERMALLY EXPANDABLE THERMOPLASTIC MICROSPHERES AND PROCESS FOR THEIR PREPARATION
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Nyholm, Christina
Restorp, Per Anders
Törncrona, Anders
Bergenudd, Helena
Sundblom, Andreas
Andreasson, Bo
Abrégé
The invention relates to a process for the manufacture of thermally expandable thermoplastic microspheres. The process comprises, providing a mixture of monomeric materials suitable for polymerisation to form a thermoplastic polymer and at least one blowing agent, providing to the mixture a colloidal silica that is surface-modified with at least hydrophobic organosilane groups and forming an emulsion. A polymerisation is performed to form the thermally expandable thermoplastic microspheres. The invention further relates to thermally expandable thermoplastic microspheres, expanded microspheres and their use in the manufacture of products.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Widell, Mikael Ivar
Janiak, John André
Gustafsson, Jan Olof
Nordberg, Henrik
Abrégé
The present invention relates to a process to treat magnetite ore containing less than 15 wt% of silica on total ore, the process containing a step of (froth) flotating in the presence of a collector composition that contains 80 to 100 wt% of at least one alkylethermonoamine, less than 20 wt% alkyletherdiamine, all wt% based on total weight of all amine components, and wherein the alkylethermonoamine is an alkylethermonoamine with a degree of branching higher than 1, the alkyl containing 11 to 17 carbon atoms, and further relates to the collector composition that can be used in the process.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Widell, Mikael Ivar
Janiak, John André
Gustafsson, Jan Olof
Nordberg, Henrik
Abrégé
The present invention relates to a collector composition containing 80 to 100 wt% of at least one alkylethermonoamine, less than 20 wt% alkyletherdiamine, all wt% based on total weight of all amine components, and wherein the alkylethermonoamine contains between 60 and 93% isotridecyl(C13)etherpropylamine, 5 and 30% of isododecyl(C12)etherpropylamine, 0 and 10% of isoundecyl(C11)- etherpropylamine, 0 and 10% of isodecyl(C10)etherpropylamine, 2 and 10% tetradecyl(C14) etherpropylamine, all % being based on total weight of alkylethermonoamine and the use thereof in a process to treat iron ore.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Vadillo, Damien Christian
Philbin, Michael Timothy
Thomaides, John Socrates
He, Qiwei
Threlfall-Holmes, Philip Nigel
Abrégé
Disclosed are copolymers of alkyl methacrylate monomers wherein said alkyl methacrylate monomers comprise at least: a. Monomers (A) selected from C6-C10 alkyl methacrylate monomers, and b. Monomers (B) selected from C10-C18 alkyl methacrylate monomers, wherein the mass ratio of Monomers (B) in the copolymer to Monomers (A) in the copolymer is about 99:1 to about 60:40 by weight. In some cases, the copolymers are of lauryl methacrylate and C8alkyI methacrylate. Also disclosed are methods for the preparation of the copolymers.
C08L 33/04 - Homopolymères ou copolymères des esters
C08F 220/18 - Esters des alcools ou des phénols monohydriques des phénols ou des alcools contenant plusieurs atomes de carbone avec l'acide acrylique ou l'acide méthacrylique
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Van Der Kruijs, Peter
Abrégé
Process to prepare alkylaluminoxane by reacting, in the absence of solvent, 1 molar equivalent of alkylaluminium with 0.1 to 0.8 molar equivalent of a substituted allylic alcohol of the formula (I) wherein R1 and R2 are independently selected from aliphatic and aromatic hydrocarbon groups, and each R3, R4, and R5 is independently selected from aliphatic and aromatic hydrocarbon groups and a hydrogen atom.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Zuijderduin, Albert Roland
Ten Broeke, Raymond Albertus Johannes
Talma, Auke Gerardus
Lepelaar, Mark
Böttger, Willem Otto Julius
Groot, Rolf
Abrégé
Radically curable mixture comprising radically curable thermosetting resin, fibres from plants of the Gramineae family, one or more organic peroxides, and optionally fillers, wherein the content of radically curable thermosetting resin in the mixture is inthe range20-50 wt%,the total contentof fillers and fibresin the mixtureis in the range 50-80 wt%, and wherein the content of fibres from plants of the Gramineae family in the mixture is in the range 5-80 wt%and wherein the total moisture content of the fibresfrom plants of the Gramineae familyis 0.5-2 wt%, based on the total weight of said fibres.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Nordberg, Henrik
Smolko-Schvarzmayr, Natalija
Svensson, Magnus
Abrégé
The present invention relates to secondary collector mixtures containing at least one compound (i) selected from the group of branched fatty alcohols with 12-16 carbon atoms having a degree of branching (DB) of 1-3.5 and their alkoxylates with a degree of ethoxylation (DE) of up to 4, and at least one compound (ii) selected from the group of alkoxylates of nonionic hydrocarbon compounds with a degree of ethoxylation of higher than 3 and carbohydrate-based surfactants, wherein if both compounds (i) and (ii) are ethoxylated alcohols, the mixture has a bimodal degree of ethoxylation distribution; to the use of compound (ii) as an emulsifier for compound (i) in a liquid; to collector compositions containing the secondary collector mixtures together with a primary collector that is an amphoteric or anionic surface-active compound; and to the use of the above compositions in a process for froth flotation of non-sulfidic ores.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Gerritsen, René
Hekkert, Richard Hermannes Johannes
Keijzer, Ester Elisabeth Antonia
Abrégé
Aqueous emulsion comprising: -25-70 wt% organic peroxide,based on the weight of the emulsion, -a cyclohexane dicarboxylate ester, and -water. This emulsion is storage stable and can be used for the production of polymers, in particular PVC, that come into contact with food products.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Oskarsson, Hans
Bowen, Lynnette Susan
Janiak, John André
Band, Elliot Isaac
Rus, Kristan Alexander
Abrégé
The application relates to compositions comprising di-fatty-alkyl or -alkenyl polyalkylamines of the general fromula (I) or (II), to a process for their preparation which involves a cyanoethylation step and a hydrogenation step, and their use as demulsifiers for oil-in- water emulsions, corrosion inhibitor, fuel additive, anti-scaling agent, asphalt additive, enhanced oil recovery agent for oil-wells, cutting-oil additive, and anti-static agent. The product show good performance combined with a favourable viscosity profile.
C07C 211/14 - Amines contenant des groupes amino liés à au moins deux groupes aminoalkyle, p. ex. diéthylènetriamines
C10M 141/06 - Compositions lubrifiantes caractérisées en ce que l'additif est un mélange d'au moins deux composés couverts par plus d'un des groupes principaux , chacun de ces composés étant un composé essentiel l'un d'eux, au moins, étant un composé organique contenant de l'azote
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Paul, Rupak
He, Hongbin
Abrégé
Aqueous compositions are provided which consist of i) one or more of glufosinate, glufosinate salts, fertilizer, and mixtures thereof, ii) an alkyl amidoamine, and iii) a quaternary ammonium compound. Furthermore the such compositions in the preparation of agricultural formulations and the use of such formulations to treat a field, plants, or seeds.
A01N 25/30 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, caractérisés par leurs formes, ingrédients inactifs ou modes d'applicationSubstances réduisant les effets nocifs des ingrédients actifs vis-à-vis d'organismes autres que les animaux nuisibles caractérisés par les agents tensio-actifs
A01N 25/02 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, caractérisés par leurs formes, ingrédients inactifs ou modes d'applicationSubstances réduisant les effets nocifs des ingrédients actifs vis-à-vis d'organismes autres que les animaux nuisibles contenant des liquides comme supports, diluants ou solvants
A01N 57/20 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, contenant des composés organiques du phosphore comportant des liaisons phosphore-carbone contenant des radicaux acycliques ou cycloaliphatiques
C05G 3/02 - Mélanges d'un ou plusieurs engrais avec des produits n'ayant pas une activité spécifique d'engrais avec des parasiticides
76.
PROCESS TO CONVERT CYCLIC ALKYLENE UREAS INTO THEIR CORRESPONDING ALKYLENE AMINES
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Edvinsson, Rolf Krister
Kantzer, Eike Nicolas
Larsson, Per Fredrik Olmo
Lake, Karl Fredrik
Ten Kate, Antoon Jacob Berend
Schröder, Ulf
Malmberg, Johan Salman
Abrégé
The present invention relates to a process to convert cyclic alkylene ureas into their corresponding alkylene amines wherein the process is performed by reaction with an amine compound, and wherein the amine compound comprisesa primaryamine,a cyclic secondary amineor a tertiary bicyclic amine.
C07C 209/62 - Préparation de composés contenant des groupes amino liés à un squelette carboné par clivage de liaisons carbone-azote, soufre-azote ou phosphore-azote, p. ex. hydrolyse d'amides, N-déalkylation d'amines ou de composés d'ammonium quaternaire
C07D 233/36 - Un atome d'oxygène avec des radicaux hydrocarbonés, substitués par des atomes d'azote, liés aux atomes d'azote du cycle
77.
PROCESS TO PREPARE HIGHER ETHYLENE AMINES AND ETHYLENE AMINE DERIVATIVES
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Edvinsson, Rolf Krister
Kantzer, Eike Nicolas
Larsson, Per Fredrik Olmo
Lake, Karl Fredrik
Ten Kate, Antoon Jacob Berend
Ehlers, Ina
Abrégé
The present invention relates to a process to prepare ethyleneamines of the formula NH2-(C2H4-NH-)pH wherein p is at least 2 wherein one or more units -NH-C2H4-NH- are present as a piperazine unit or precursors thereof wherein optionally one or more units -NH-C2H4-NH- are present as a cyclic ethylene urea unit or between two units -NH-C2H4- NH- a carbonyl moiety is present, by reacting an ethanolamine-functional compound, an amine-functional compound in the presence of a carbon oxide delivering agent, wherein at least one of the amine-functional compound or the ethanolamine-functional compound contains a piperazine unit, and the reaction is performed in a liquid that comprises water.
C07D 295/13 - Composés hétérocycliques contenant des cycles polyméthylène imine d'au moins cinq chaînons, des cycles aza-3 bicyclo [3.2.2] nonane, piperazine, morpholine ou thiomorpholine, ne comportant que des atomes d'hydrogène liés directement aux atomes de carbone du cycle avec des radicaux hydrocarbonés substitués liés aux atomes d'azote du cycle substitués par des atomes d'azote liés par des liaisons simples ou doubles avec les atomes d'azote du cycle et les atomes d'azote substituants liés à la même chaîne carbonée, qui n'est pas interrompue par des cycles carbocycliques à une chaîne acyclique saturée
C07D 233/36 - Un atome d'oxygène avec des radicaux hydrocarbonés, substitués par des atomes d'azote, liés aux atomes d'azote du cycle
78.
PROCESS TO PREPARE HIGHER ETHYLENE AMINES AND ETHYLENE AMINE DERIVATIVES
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Edvinsson, Rolf Krister
Kantzer, Eike Nicolas
Larsson, Per Fredrik Olmo
Lake, Karl Fredrik
Ten Kate, Antoon Jacob Berend
Abrégé
The present invention relates to a process to prepare ethylene amines of the formula NH2-(C2H4-NH-)pH wherein p is at least 3 or derivatives thereof wherein one or more units -NH-C2H4-NH- may be present as a cyclic ethylene urea unit or between two units -NH-C2H4-NH- a carbonyl moiety is present, by reacting an ethanolamine-functional compound, an amine-functional compound in the presence of a carbon oxide delivering agent, wherein the molar ratio of carbon oxide delivering agent to amine-functional compound is at least 0.6 to 1.
C07C 209/16 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés avec formation de groupes amino liés à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons
79.
PROCESS TO PREPARE HIGHER ETHYLENE AMINES AND ETHYLENE AMINE DERIVATIVES
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Edvinsson, Rolf Krister
Kantzer, Eike Nicolas
Larsson, Per Fredrik Olmo
Lake, Karl Fredrik
Ten Kate, Antoon Jacob Berend
Abrégé
The present invention relates to a process to prepare ethyleneamines of the formula NH2-(C2H4-NH-)pH wherein p is at least 3 or derivatives thereof wherein one or more units -NH-C2H4-NH- may be present as a cyclic ethylene urea unit or between two units -NH-C2H4-NH- a carbonyl moiety is present, by reacting an ethanolamine-functional compound, an amine-functional compound in the presence of a carbon oxide delivering agent, wherein the molar ratio of ethanolamine-functional compound to amine- functional compound is at least 0.7: 1 and the molar ratio of carbon oxide delivering agent to amine-functional compound is at least 0.05: 1.
C07C 209/16 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés avec formation de groupes amino liés à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Paul, Rupak
He, Hongbin
Abrégé
Aqueous solutions are provided which contain i) paraquat, fertilizer, or mixture thereof, ii) an alkyl amidoamine, and iii) a quaternary ammonium compound. Furthermore the use of such compositions in the preparation of agricultural formulations and the use of such formulations to treat a field, plants, or seeds.
A01N 25/02 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, caractérisés par leurs formes, ingrédients inactifs ou modes d'applicationSubstances réduisant les effets nocifs des ingrédients actifs vis-à-vis d'organismes autres que les animaux nuisibles contenant des liquides comme supports, diluants ou solvants
A01N 25/30 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, caractérisés par leurs formes, ingrédients inactifs ou modes d'applicationSubstances réduisant les effets nocifs des ingrédients actifs vis-à-vis d'organismes autres que les animaux nuisibles caractérisés par les agents tensio-actifs
A01N 43/40 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, contenant des composés hétérocycliques comportant des cycles avec un atome d'azote comme unique hétéro-atome du cycle des cycles à six chaînons
C05G 3/02 - Mélanges d'un ou plusieurs engrais avec des produits n'ayant pas une activité spécifique d'engrais avec des parasiticides
C05G 3/06 - Mélanges d'un ou plusieurs engrais avec des produits n'ayant pas une activité spécifique d'engrais avec des agents mouillants
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Thomaides, John Socrates
Morales, John M.
He, Qiwei
Vadillo, Damien Christian
Philbin, Michael Timothy
Abrégé
The invention relates to a specific copolymer obtainable by co-polymerizing at least the following monomers: - more than 80 wt% of at least one bicyclic (meth)acrylate ester, - 0.05to 15 %w/w styrene, and - optionally other ethylenically unsaturated monomers, as well as to the way to synthesize them and the use of such polymers to modify the rheology of a liquid in which they are soluble.
C08F 220/18 - Esters des alcools ou des phénols monohydriques des phénols ou des alcools contenant plusieurs atomes de carbone avec l'acide acrylique ou l'acide méthacrylique
C10L 1/18 - Composés organiques contenant de l'oxygène
82.
METHOD OF MAKING A COMPOSITION OF AN ALKANOLAMINE ALKYLAMIDE AND A POLYOL
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Bevinakatti, Hanamanthsa
White, Karen Lee
Abrégé
The disclosure generally provides methods for preparing compositions comprising alkanolamine alkylamides and polyols. This disclosure further relates to methods for preparing compositions comprising alkanolamine alkylamides and polyols that can be used in formulations that provide moisturization.
C07C 231/02 - Préparation d'amides d'acides carboxyliques à partir d'acides carboxyliques ou à partir de leurs esters, anhydrides ou halogénures par réaction avec de l'ammoniac ou des amines
C07C 233/18 - Amides d'acides carboxyliques ayant des atomes de carbone de groupes carboxamide liés à des atomes d'hydrogène ou à des atomes de carbone acycliques ayant l'atome d'azote d'au moins un des groupes carboxamide lié à un atome de carbone d'un radical hydrocarboné substitué par des atomes d'oxygène liés par des liaisons simples avec le radical hydrocarboné substitué lié à l'atome d'azote du groupe carboxamide par un atome de carbone acyclique ayant l'atome de carbone du groupe carboxamide lié à un atome d'hydrogène ou à un atome de carbone d'un squelette carboné acyclique saturé
C07C 29/00 - Préparation de composés comportant des groupes hydroxyle ou O-métal liés à un atome de carbone ne faisant pas partie d'un cycle aromatique à six chaînons
C07C 31/22 - Alcools trihydroxyliques, p. ex. glycérol
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
He, Qiwei
Bevinakatti, Hanamanthsa
Abrégé
The disclosure provides personal care compositions that comprise a moisturizing agent of formula (I) wherein n is an integer from 2 to 5, R1 is independently H or C1-C3 alkyl and R2 is an unsubstituted linear or branched C1-C6 alkyl, at least one additional moisturizing agent and a cosmetically acceptable vehicle. In particular, the compound of formula (I) is diglycolamine acetamide. The compositions generally improve moisturization of skin and hair.
A61K 8/49 - Cosmétiques ou préparations similaires pour la toilette caractérisés par la composition contenant des composés organiques contenant des composés hétérocycliques
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
He, Qiwei
Bevinakatti, Hanamanthsa
Abrégé
The disclosure provides personal care compositions that comprise a compound of formula (I) wherein n is an integer from 2 to 5, R1 is independently H or C1-C3 alkyl and R2 is an unsubstituted linear or branched C1-C6 alkyl and a cosmetically acceptable vehicle. In particular, the compound of formula (I) is diglycolamine acetamide The composition may be used to moisturise skin or hair.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Frijlink, Wilhelm Klaas
Van Der Schuur, Jan Martijn
Talma, Auke Gerardus
Van Den Berg, Michel
Abrégé
Process for reducing fogging from high melt strength polypropylene (HMS-PP) obtained by heat treating polypropylene at a temperature between 150°C and 300°C in the presence of a dialkyl peroxydicarbonate, said process involving the introductionof an anhydride to said high melt strength polypropylene.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Battal, Turgut
Abrégé
Compositions are provided which i) consists essentially of a siloxane defoamer and an alkoxylated C4-10 alcohol, ii) are aqueous concentrates comprising composition i), an adjuvant, and an electrolyte, and iii) are aqueous formulations obtainable by diluting compositions ii). Furthermore the use of compositions i) and ii) for in the preparation of agricultural formulations iii) and the use of such formulations iii) to treat a field or plants.
A01N 25/30 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, caractérisés par leurs formes, ingrédients inactifs ou modes d'applicationSubstances réduisant les effets nocifs des ingrédients actifs vis-à-vis d'organismes autres que les animaux nuisibles caractérisés par les agents tensio-actifs
A01N 57/20 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, contenant des composés organiques du phosphore comportant des liaisons phosphore-carbone contenant des radicaux acycliques ou cycloaliphatiques
The present invention pertains to an electrochemical cell (1) comprising: - an anolyte space with an anode (11); - a catholyte space with a cathode (12); and - a separator disc (2) separating the anolyte space from the catholyte space; wherein the anolyte space and/or the catholyte space comprise at least one wall (2) which is rotatable about an axis of rotation crossing the separator disc, wherein the electrochemical cell comprises at least one stator (6, 7) in the anolyte space and/or the catholyte space.
C25B 1/10 - Production électrolytique de composés inorganiques ou de non-métaux d'hydrogène ou d'oxygène par électrolyse de l'eau dans des cellules à diaphragme
C25B 9/00 - Cellules ou assemblages de cellulesÉléments de structure des cellulesAssemblages d'éléments de structure, p. ex. assemblages d'électrode-diaphragmeCaractéristiques des cellules relatives aux procédés
C25B 9/12 - Cellules ou assemblages de cellules comprenant au moins une électrode mobile, p.ex. électrodes rotatives; Assemblages de leurs éléments de structure
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Craige, Simon
Miles, Jason Victor
Selse, Dennis
Krigsman, Joakim
Abrégé
The invention relates to an oil-in-water emulsion comprising an oil phase and an aqueous phase, and a primary surfactant, wherein the oil phase is dispersed in the aqueous phase, and wherein the oil-in-water emulsion has: an average droplet size distribution (D[4,3]) in the range of from 3 to 15 µm and less than 3wt% of the droplets have a particle size of greater than 125 µm;a viscosity of greater than 100 and up to 700 mPas at 50°C ±10% and 20 s-1 ±10%; and a static stability of less than 5% residue after centrifugation at 50°C ±10% and 2000g ±10% for 30 minutes ±10%. A process for preparing such an oil-in-water emulsion comprises preparing an aqueous phase comprising a primary surfactant, heating a hydrocarbon-containing oil-phase, and blending the hydrocarbon-containing oil and the aqueous phase under conditions sufficient to form an oil-in-water emulsion. The invention also relates to methods for determining the static and dynamic stability of oil-in-water emulsions. Static stability can be determined by a method comprising the steps of: providing an oil-in-water emulsion; centrifuging the oil-in-water emulsion under predetermined conditions for a predetermined period of time; determining the amount of residue deposited from the oil-in-water emulsion after the predetermined period of time; and determining the oil-in-water emulsion's static stability. A method for determining the dynamic stability of an oil-in-water emulsion comprises the steps of: providing an oil-in-water emulsion; analysing the oil-in-water emulsion at a first time; recirculating the oil-in-water emulsion in a recirculation loop; and analysing the oil-in- water emulsion at second time after recirculation has started; in which the oil-in-water emulsion's dynamic stability is determined based on the analysis at the first and second times.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Vos, Hendrik Jan
Tollin, Lars Magnus
Kooijman, Cornelis
Abrégé
The present invention pertains to a process for the chlorination of acetic acid to form monochloroacetic acid comprising the following steps a. reacting acetic acid with chlorine using acetic anhydride and/or acetyl chloride as catalyst to form a liquid phase, and a gaseous phase, - the liquid phase comprising at least monochloroacetic acid, acid chlorides, acid anhydrides and optionally un reacted acetic acid, and - the gaseous phase comprising HCI, acetic acid, monochloroacetic acid and acid chlorides, b. stripping said liquid phase at a temperature of between 120 and 180°C and a pressure between 1 and 7 bara with gaseous HCI to form a gaseous HCI stream comprising acetic acid, acid chlorides and optionally acid anhydrides and monochloroacetic acid, and a liquid stream comprising monochloroacetic acid and dichloroacetic acid; c. cooling the gaseous HCI stream comprising acetic acid, acid chlorides, acid anhydrides and optionally monochloroacetic acid to a temperature of between 10 and 60°C (preferably around 35°C), and d. feeding the cooled gaseous HCI to an absorber with acetic acid as absorber, absorbing the acetic acid, acid chlorides and optionally monochloroacetic acid forming a stream comprising acetic acid and acid chlorides.
C07C 51/363 - Préparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides par des réactions ne créant pas de groupes carboxyle par introduction d'atomes d'halogènePréparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides par des réactions ne créant pas de groupes carboxyle par substitution d'atomes d'halogène par des atomes d'autres halogènes
C07C 51/43 - SéparationPurificationStabilisationEmploi d'additifs par changement de l'état physique, p. ex. par cristallisation
C07C 51/44 - SéparationPurificationStabilisationEmploi d'additifs par changement de l'état physique, p. ex. par cristallisation par distillation
90.
CELLULOSE ETHERS WITH TEMPORARY CROSS-LINKS, A PROCESS TO MAKE THEM, AND THEIR USE
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Karlsson, Hans Jonas
Abrégé
The invention relates to temporary cross-linked cellulose ethers, a process to make them, as well as their use to influence the rheological profile of an aqueous medium in which they are dissolved. The temporary cross-linked cellulose ethers are characterized in that they are cellulose ethers that are Cross-linked with at least one or more compounds of the formula (C1-4 alkyl)-OC(O)CHOHO-(C1-4 alkyl).
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Rosvall, Magnus
Nordin, Bernth
Abrégé
An electrode (10) is disclosed in which a first layer (30) of TiOx with a porosity in the range 0 -3% is present on at least one surface of an electrode substrate (20), a second layer (40) of TiOx with a porosity of greater than 3 and up to 20% is present on the first layer (30) of TiOx. An electro-catalytic layer (50) is present on the second layer (40) of TiOx. x is in the range 1 -2 for the first (30) and second layer (40) of TiOx. A process for the manufacture of the electrode (10) is disclosed as are uses thereof.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Rosvall, Magnus
Amerio, Ezio
Gustavsson, John
Holmin, Susanne
Bergman, Lars-Erik
Abrégé
An electrode (10) is disclosed. The electrode (10) comprises an electrode substrate (20). A layer of TiOx (30, 40) with a total thickness in the range of between 40 - 200 μm is present on at least one surface of the electrode substrate (20) and a porosity of layer of TiOx (30, 40) is below 15%. An electro-catalytic layer (50) comprising oxides of ruthenium and cerium according comprising at least 50 molar % ruthenium oxides is present on layer of TiOx (30, 40) and wherein x is in the range 1 - 2 for the layer of TiOx. A process for the manufacture of the electrode (10) is disclosed as are uses thereof.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Rosvall, Magnus
Amerio, Ezio
Gustavsson, John
Holmin, Susanne
Bergman, Lars-Erik
Abrégé
An electrode (10) is disclosed. The electrode (10) comprises an electrode substrate (20). A layer of TiOx (30, 40) with a total thickness in the range of between 40 - 200 pm is present on at least one surface of the electrode substrate (20) and a porosity of layer of TiOx (30, 40) is below 15%. An electro-catalytic layer (50) comprising oxides of ruthenium and cerium according comprising at least 50 molar % ruthenium oxides is present on layer of TiOx (30, 40) and wherein x is in the range 1-2 for the layer of TiOx. A process for the manufacture of the electrode (10) is disclosed as are uses thereof.
C25B 11/093 - Électrodes comportant des électro-catalyseurs sur un substrat ou un support caractérisées par le matériau électro-catalytique formé d’au moins un élément catalytique et d’au moins un composé catalytiqueÉlectrodes comportant des électro-catalyseurs sur un substrat ou un support caractérisées par le matériau électro-catalytique formé de plusieurs éléments catalytiques ou composés catalytiques au moins un métal noble ou oxyde de métal noble et au moins un oxyde d’un métal non noble
94.
PROCESS FOR THE PREPARATION OF TRIMETHYL METAL COMPOUNDS
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Caipa Campos, Mabel Andrea
Rosini, Glen
Woudenberg, Richard Herman
Abrégé
Process for the preparation of a trimethyl metal compound with the formula M(CH3)3, said process comprising the step of reacting a trialkyl metal compound of the formula M(R)3 with trimethyl aluminium [AI(CH3)3] to form said trimethyl metal compound with the formula M(CH3)3, wherein M is selected from the group consisting of Ga and In, and R is a linear or branched alkyl group with 2 to 8 carbon atoms.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Opsahl, Ross Christian
Butuc, Steluta Gina
Abrégé
Peroxide of the formula wherein R1 is selected from linear and branched alkyl groups with 1-4 carbon atoms, and R2, R3, and R4 are selected from hydrogen and linear and branched alkyl groups with 1-4 carbon atoms, for use as a medicament, in particular for the treatment of acne.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Caipa Campos, Mabel Andrea
Rosini, Glen
Woudenberg, Richard Herman
Kurniawan, Andy
Te Nijenhuis, Marcellinus Antonius Maria
Abrégé
Process for the production of a trimethyl metal compound with the formula M(CH3)3, said process comprising the steps of (i) reacting a metal trihalide MX3 with a trialkyl aluminium compound AI(R)3 to form a trialkyl metal compound M(R)3 and a dialkyl aluminium halide AI(R)2X, and (ii) reacting said trialkyl metal compound M(R)3 with either trimethyl aluminium [AI(CH3)3] or dimethylaluminium halide [AI(CH3)2X] to form said trimethyl metal compound M(CH3)3, wherein M is selected from the group consisting of Ga and In, X is a halogen, and R is a linear or branched alkyl group with 2 to 8 carbon atoms.
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Altena, Evert
Brand, Johannes
Abrégé
The present invention relates to a process to prepare a free-flowing salt product comprising sodium chloride (NaCl) and/or potassium chloride (KCl), wherein the salt product has a particle size of from 50 μm to 1000 μm,which process comprises the steps of (a) processing a source of pure NaCl, pure KCl, or mixture of salts, to form particles with an average size of less than 100 micrometer; (b) subsequently, compacting the particles from step a) using a pressure of from 40 to 400 MPa; and optionally, crushing the thus obtained particles;and (c) subsequently, absorbing one or more agents into the salt particles, characterized in that no agent is added in or during steps a) and b) or between steps a) and b).
A23L 27/40 - Sels de tableSubstituts diététiques du sel
A23L 27/10 - Épices, agents aromatiques ou condiments naturelsLeurs extraits
A23L 29/294 - Additifs inorganiques, p. ex. silice
A23P 10/25 - Agglomération ou granulation par extrusion ou par compression, p. ex. par des petits trous, des tamis ou entre des surfaces
A23P 10/28 - Mise en comprimésFabrication de produits alimentaires en barres par compression d’un mélange pulvérulent sec
A23L 27/00 - ÉpicesAgents aromatiques ou condimentsÉdulcorants artificielsSels de tableSubstituts diététiques du selLeur préparation ou leur traitement
98.
PROCESS TO PREPARE PHENOLIC ETHYLENEDIAMINE DIACETIC ACID COMPOUNDS
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Reichwein, Adrianus Maria
Jongen, Hubertus Johannes
Groote, Marjolein
Abrégé
The present invention relates to a process to prepare N,N'-di(2-hydroxybenzyl) ethylenediamine-N,N'-diacetic acid and salts thereof comprising a reaction between formaldehyde, ethylenediamine diacetic acid or a salt thereof and phenol at a pH of between 3 and 7 and a temperature below 60°Cwherein the reaction mixture contains 0.2 to 1.1 molar equivalents of alkali metalions on the molar amount of EDDA.
C07C 227/16 - Préparation de composés contenant des groupes amino et carboxyle liés au même squelette carboné à partir de composés contenant déjà des groupes amino et carboxyle ou leurs dérivés par des réactions n'impliquant pas les groupes amino ou carboxyle
99.
PROCESS TO PREPARE PHENOLIC ETHYLENEDIAMINE DIACETIC ACID COMPOUNDS
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Reichwein, Adrianus Maria
Jongen, Hubertus Johannes
Groote, Marjolein
Abrégé
The present invention relates to a process to prepare N,N'-di(2-hydroxybenzyl) ethylenediamine-N,N'-diacetic acid and salts thereof (HBED) comprising a reaction between formaldehyde, ethylenediamine diacetic acid or a salt thereof (EDDA) and phenol, wherein the reaction mixture contains 0.2 to 1.1 molar equivalents of alkali metal ions on the basis of the molar amount of EDDA and the reaction mixture is processed by a step in which at least part of the organic compounds other than the formed HBED are removed from the reaction mixture, and optionally recycled, during which step at least 50% and up to and including 100% of the alkali metal ions in the reaction mixture are potassium ions, to products obtainable by such process and their use.
C07C 227/16 - Préparation de composés contenant des groupes amino et carboxyle liés au même squelette carboné à partir de composés contenant déjà des groupes amino et carboxyle ou leurs dérivés par des réactions n'impliquant pas les groupes amino ou carboxyle
100.
PROCESS FOR THE HYDRODECHLORINATION OF A FEED COMPRISING DICHLOROACETIC ACID
AKZO NOBEL CHEMICALS INTERNATIONAL B.V. (Pays‑Bas)
Inventeur(s)
Tollin, Lars Magnus
Kooijman, Cornelis
Abrégé
The present invention is directed to a process for catalytic hydrodechlorination of dichloroacetic acid, wherein hydrogen gas is contacted with a liquid feed comprising dichloroacetic acid and monochloroacetic acid to form a product stream comprising monochloroacetic acid and an off gas stream comprising hydrogen chloride and hydrogen, and wherein the product stream is contacted with nitrogen gas so as to remove hydrogen gas present in the product stream.
C07C 51/377 - Préparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides par des réactions ne créant pas de groupes carboxyle par élimination d'hydrogène ou de groupes fonctionnelsPréparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides par des réactions ne créant pas de groupes carboxyle par hydrogénolyse de groupes fonctionnels