CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Chen, Pei
Liu, Shunjie
Wang, Xianhong
Abrégé
The present invention belongs to the field of lithium ion batteries, and specifically relates to an in-situ preparation method and a recovery method for a solid polymer electrolyte, as well as a lithium ion battery. The preparation method provided by the present invention comprises the following steps: a) loading an electrolyte precursor onto a surface of a battery separator, and then assembling same with a lithium ion battery positive electrode and a lithium ion battery negative electrode, to obtain a semi-finished lithium ion battery product, components of the electrolyte precursor in step a) comprising a polymer monomer, a lithium salt and an initiator, the lithium salt being lithium perchlorate, lithium hexafluorophosphate, lithium difluorophosphate, or the like; b) under heating conditions, performing in-situ polymerization of the electrolyte precursor on the battery separator in the semi-finished lithium ion battery product, to obtain a solid polymer electrolyte loaded on the battery separator. The preparation method provided by the present invention does not require an additional catalyst, and the prepared solid polymer electrolyte can be depolymerized by means of heating, and has good environmental and economic benefits.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Wang, Xiaohui
Zhou, Xiaoxuan
Wang, Hongshuang
Lin, Cong
Zhai, Haojiang
Abrégé
Disclosed in the present invention are a ketamine small molecule probe, and a preparation method therefor and the use thereof. Two small molecular probes are designed and synthesized, and the blank in the prior art is filled. A target fishing experiment is performed on the total protein in a cell lysis buffer by means of using the two probes, and 61 and 70 target proteins are obtained, respectively. In addition, more than three technical repetitions verify that the two probes can stably bind to the target proteins. A screened SIRT2 protein is used as a target protein of ketamine, and a reference basis is provided for the synthesis and preparation of an anti-inflammatory related drug.
C07C 225/20 - Composés contenant des groupes amino et des atomes d'oxygène, liés par des liaisons doubles, liés au même squelette carboné, au moins un des atomes d'oxygène, liés par des liaisons doubles, ne faisant pas partie d'un groupe —CHO, p. ex. aminocétones ayant des groupes amino liés à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons du squelette carboné
C07C 221/00 - Préparation de composés contenant des groupes amino et des atomes d'oxygène, liés par des liaisons doubles, liés au même squelette carboné
A61P 29/00 - Agents analgésiques, antipyrétiques ou anti-inflammatoires non centraux, p. ex. agents antirhumatismauxMédicaments anti-inflammatoires non stéroïdiens [AINS]
G01N 33/68 - Analyse chimique de matériau biologique, p. ex. de sang ou d'urineTest par des méthodes faisant intervenir la formation de liaisons biospécifiques par ligandsTest immunologique faisant intervenir des protéines, peptides ou amino-acides
3.
BINUCLEAR SCHIFF BASE-COBALT COMPLEX, PREPARATION METHOD AND USE THEREOF
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Pang, Xuan
Zhou, Yanchuan
Duan, Ranlong
Sun, Zhiqiang
Chen, Xuesi
Abrégé
A binuclear Schiff base-cobalt complex, a preparation method and use thereof, wherein the binuclear Schiff base-cobalt complex has a structure represented by Formula (I):
A binuclear Schiff base-cobalt complex, a preparation method and use thereof, wherein the binuclear Schiff base-cobalt complex has a structure represented by Formula (I):
A binuclear Schiff base-cobalt complex, a preparation method and use thereof, wherein the binuclear Schiff base-cobalt complex has a structure represented by Formula (I):
in Formula (I), R1 and R2 are independently selected from a group consisting of hydrogen, nitro, cyano, a halogen, an aliphatic group, a substituted aliphatic group and an aryl group; and X is selected from a group consisting of —F, —Cl, —Br, —I, —NO3, —CH3COO, —CCl3COO, —CF3COO, —ClO4, p-methylbenzoate, p-toluenesulfonate, 2,4-dinitrophenoxy, 3,5-dinitrophenoxy, p-nitrophenoxy and o-nitrophenoxy anions. The present disclosure can provide a binuclear Schiff base-cobalt complex, which can catalyze copolymerization reaction of an epoxide, such as an epoxide with an electron-withdrawing group, with CO2 to prepare a polycarbonate material. Further, multi-component polycarbonate materials having plentiful structures may be synthesized by adding a second component of epoxy monomer in the reaction system, and the molecular weight thereof may reach 44.4 kg/mol.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Zhisen
Yan, Ruiting
Xing, Wei
He, Ting
Shi, Zhaoping
Liu, Changpeng
Abrégé
Provided in the embodiments of the present application is an inorganic material. The inorganic material comprises an iridium oxide nanomaterial, the iridium oxide nanomaterial being of a hexagonal crystal phase structure. The inorganic material has a relatively high intrinsic catalytic activity, and when being used in the field of proton exchange membrane water electrolysis, the inorganic material has a more obvious catalytic effect and is beneficial for reducing catalyst costs. Further provided in the embodiments of the present application are a preparation method for and the related use of the inorganic material.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
SHENZHEN UNIVERSITY (Chine)
Inventeur(s)
Wang, Xiaohui
Jin, Sha
Dou, Xiubo
Abrégé
CBD derivatives effective for treating opioid addiction, neurodegenerative diseases and neuroinflammation. The CBD derivatives have lower toxicity than CBD, are not addictive, and do not inhibit respiration or damage short-time memory.
C07D 207/325 - Composés hétérocycliques contenant des cycles à cinq chaînons, non condensés avec d'autres cycles, ne comportant qu'un atome d'azote comme unique hétéro-atome du cycle avec uniquement des atomes d'hydrogène ou de carbone liés directement à l'atome d'azote du cycle comportant deux liaisons doubles entre chaînons cycliques ou entre chaînons cycliques et chaînons non cycliques avec uniquement des atomes d'hydrogène, des radicaux hydrocarbonés ou des radicaux hydrocarbonés substitués, liés directement aux atomes de carbone du cycle avec des radicaux hydrocarbonés substitués, liés directement à l'atome d'azote du cycle
C07D 233/60 - Composés hétérocycliques contenant des cycles diazole-1, 3 ou diazole-1, 3 hydrogéné, non condensés avec d'autres cycles comportant deux liaisons doubles entre chaînons cycliques ou entre chaînons cycliques et chaînons non cycliques avec uniquement des atomes d'hydrogène ou des radicaux ne contenant que des atomes d'hydrogène et de carbone, liés aux atomes de carbone du cycle avec des radicaux hydrocarbonés, substitués par des atomes d'oxygène ou de soufre, liés aux atomes d'azote du cycle
A61P 25/30 - Médicaments pour le traitement des troubles du système nerveux des états d'abus ou de dépendance
A61P 25/28 - Médicaments pour le traitement des troubles du système nerveux des troubles dégénératifs du système nerveux central, p. ex. agents nootropes, activateurs de la cognition, médicaments pour traiter la maladie d'Alzheimer ou d'autres formes de démence
A61P 25/00 - Médicaments pour le traitement des troubles du système nerveux
A61P 29/00 - Agents analgésiques, antipyrétiques ou anti-inflammatoires non centraux, p. ex. agents antirhumatismauxMédicaments anti-inflammatoires non stéroïdiens [AINS]
6.
CHLOROSULFONATED POLYPROPYLENE CARBONATE, AND PRODUCTION METHOD AND USE THEREOF
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Jiang, Wei
Jin, Jing
Gao, Yunbao
Yan, Nan
Yang, Jun
Abrégé
The present disclosure provides a chlorosulfonated polypropylene carbonate having a structure represented by Formula I, and the production method and use thereof in the fields of binders, stickers, coatings, and others. The present disclosure introduces a highly active chlorosulfonyl group into the molecular chain of polypropylene carbonate, the molecular weight of the final product is decreased at a different degree, and the interface compatibility of the polypropylene carbonate with various substrates can be effectively adjusted and controlled, so that the state and viscosity of the product are modified. At the same time, the chlorosulfonated polypropylene carbonate is also a fully biodegradable material.
The present disclosure provides a chlorosulfonated polypropylene carbonate having a structure represented by Formula I, and the production method and use thereof in the fields of binders, stickers, coatings, and others. The present disclosure introduces a highly active chlorosulfonyl group into the molecular chain of polypropylene carbonate, the molecular weight of the final product is decreased at a different degree, and the interface compatibility of the polypropylene carbonate with various substrates can be effectively adjusted and controlled, so that the state and viscosity of the product are modified. At the same time, the chlorosulfonated polypropylene carbonate is also a fully biodegradable material.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Sun, Liwei
Abrégé
The present disclosure provides a lithium battery positive electrode material and a preparation method therefor. The lithium battery positive electrode material comprises a ternary material and a coating layer. The outer surface of the ternary material is coated with the coating layer for enhancing the surface adhesion of the positive electrode material. Therefore, with respect to the disadvantage that conventional ternary positive electrode materials are easy to be stripped and fall off due to the small surface adhesion thereof after being coated on electrode sheets, the described coating layer covering the outer surface of the ternary material can remarkably enhance the surface adhesion of the ternary material, extremely prevent the ternary material from being stripped and falling off during use, and effectively improve the cycling stability of lithium batteries.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Qiu, Xin
Tian, Zheng
Chao, Runze
Yang, Bing
Abrégé
A rare earth-alkaline earth element compounded magnesium-based alloy and a preparation method therefor. The rare earth-alkaline earth element compounded magnesium-based alloy comprises the following components in percentages by mass: Al: 3.0-9.5%, RE: 1.5-5.0%, AE: 1.5-4.0%, Zn: 0.01-0.8%, and Mn: 0.01-0.40%, with the balance being magnesium and inevitable impurities, wherein the RE comprises La, and the AE comprises Ca. The technical difficulties in the aspects of the flame retardance and room-temperature and high-temperature mechanical properties of a magnesium alloy are solved by compositely applying rare earth-alkaline earth elements, and the mechanical properties and technological adaptability of the material are effectively improved by constructing a component-optimized Mg-Al-RE-AE alloy system, such that the material is suitable for various preparation processes such as die casting, extrusion, and forging and pressing.
C22C 23/02 - Alliages à base de magnésium avec l'aluminium comme second constituant majeur
C22F 1/06 - Modification de la structure physique des métaux ou alliages non ferreux par traitement thermique ou par travail à chaud ou à froid du magnésium ou de ses alliages
C22C 1/03 - Fabrication des alliages non ferreux par fusion utilisant des alliages-mères
9.
PREPARATION OF CULTURE MEDIUM AND USE THEREFOR IN WATER TOXICITY COLORIMETRIC DETECTION
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Yu, Dengbin
Li, Rongbing
Dong, Shaojun
Abrégé
The present invention provides a culture medium and use thereof in water toxicity colorimetric detection. The culture medium comprises glucose, peptone, NaCl, a beef extract, and a ferric salt. The solubility of the ferric salt in water is not high, such that part of the ferric salt remains resuspended in a solution along with cultured bacteria to continuously release Fe3+ after centrifugation and washing, thereby successfully constructing a water toxicity colorimetric detection sensor which is simple, environment-friendly, and visible to naked eyes.
C12Q 1/02 - Procédés de mesure ou de test faisant intervenir des enzymes, des acides nucléiques ou des micro-organismesCompositions à cet effetProcédés pour préparer ces compositions faisant intervenir des micro-organismes viables
G01N 21/33 - CouleurPropriétés spectrales, c.-à-d. comparaison de l'effet du matériau sur la lumière pour plusieurs longueurs d'ondes ou plusieurs bandes de longueurs d'ondes différentes en recherchant l'effet relatif du matériau pour les longueurs d'ondes caractéristiques d'éléments ou de molécules spécifiques, p. ex. spectrométrie d'absorption atomique en utilisant la lumière ultraviolette
G01N 21/29 - CouleurPropriétés spectrales, c.-à-d. comparaison de l'effet du matériau sur la lumière pour plusieurs longueurs d'ondes ou plusieurs bandes de longueurs d'ondes différentes en utilisant la détection visuelle
G01N 21/78 - Systèmes dans lesquels le matériau est soumis à une réaction chimique, le progrès ou le résultat de la réaction étant analysé en observant l'effet sur un réactif chimique produisant un changement de couleur
G01N 1/38 - Dilution, dispersion ou mélange des échantillons
10.
METHOD OF PERFORMING LIVING CATIONIC POLYMERIZATION OF MONOMERS BY SUPERMOLECULAR ANION-BINDING CATALYSIS
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Tao, Youhua
Li, Maosheng
Abrégé
The present application relates to a method of performing living cationic polymerization of monomers by supermolecular anion-binding catalysis. It uses various simple Bronsted acids or adducts thereof with a monomer as the cationic initiator, and various hydrogen bond donors as the catalyst for binding and dissociating counter anions dynamically, to living and controlled polymerize one or more cationically polymerizable monomers to form a homopolymer or a copolymer. In the present application, the hydrogen-bond donor can exert non-covalent anion-binding interactions to dynamically and reversibly activate dormant covalent bond under mild conditions, in turn to precisely control the equilibrium between dormant covalent precursors and active cationic species, thereby achieving the precise control of the polymer's molecular weight, distribution and end group structure, and solving the environment-unfriendly relevant problems in traditional metal-based Lewis acid catalysis, which include extreme low polymerization temperature, restrict anhydrous requirement of the reaction, strict purification requirement of the monomer and catalysis-initiating system, metal residue in polymer or the like.
C08F 116/34 - Homopolymères de composés contenant un ou plusieurs radicaux aliphatiques non saturés, chaque radical ne contenant qu'une seule liaison double carbone-carbone et l'un au moins étant terminé par un radical alcool, éther, aldéhyde, cétone, acétal ou cétal par un radical aldéhyde
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY , CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Yang, Xiaoniu
Li, Zonglin
Zhang, Tong
Abrégé
A microstructure elastic film, comprising a substrate and a microstructure layer attached to the surface of the substrate. The microstructure layer has a granular microstructure connected to the substrate and having a small lower end, an expanded upper end, a rough surface and a fluffy interior, or a mountain-like microstructure connected to the substrate and having a large lower end, a small upper end, a rough surface and a fluffy interior, or a fabric-like microstructure formed by vertically and horizontally staggering fibers. Also provided are a spraying process-based preparation method for the microstructure elastomer film, and a flexible pressure sensor and a preparation method therefor. The current signal and the pressure of the flexible pressure sensor prepared by using the film are in a good linear relationship within the range of 20 MPa, and the flexible pressure sensor can be used for radial pulse monitoring.
G01L 1/18 - Mesure des forces ou des contraintes, en général en utilisant des propriétés des matériaux piézo-résistants, c.-à-d. des matériaux dont la résistance ohmique varie suivant les modifications de la grandeur ou de la direction de la force appliquée au matériau
A61B 5/024 - Mesure du pouls ou des pulsations cardiaques
A61B 5/0245 - Mesure du pouls ou des pulsations cardiaques utilisant des capteurs engendrant des signaux électriques
12.
MAGNESIUM-BASED ALLOY AND PREPARATION METHOD THEREFOR
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Qiu, Xin
Tian, Zheng
Chao, Runze
Yang, Bing
Abrégé
A magnesium-based alloy, comprising (mass%): Al: 3-9%, La: 1.5-7%, RE excluding La: 0.2-0.3%, Zn: 0.01-0.8%, Ca: 1.5-4.0%, CaO: 0.01-0.2%, and the balance being magnesium and inevitable impurities. La, which does not generate a sharp phase, is selected as a main alloying element, and a small amount of other rare earth elements such as Y/Gd are added, such that the precipitation number of an Al-La phase is effectively increased, the size of the precipitated phase is reduced, and the dispersion degree thereof is improved. Accordingly, the strength performance is improved, and the plastic loss is reduced. In addition, a method for preparing the magnesium alloy is further provided.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Tang, Zhaohui
Lv, Jianlin
Yu, Haiyang
Chen, Xuesi
Abrégé
The present invention provides a plinabulin derivative with a structure represented by formula (I). Also provided is use of the plinabulin derivative for resisting tumors, preventing chemotherapy-induced neutropenia, and preventing chemotherapy-induced myelosuppression. In the field of cancer treatment, the two derivatives provided in the present invention can cause fewer toxic and side effects while having similar therapeutic effects as plinabulin and have stronger therapeutic effects and higher therapeutic indexes while causing similar toxic and side effects as plinabulin. In the aspect of preventing chemotherapy-induced neutropenia, the two derivatives have similar ability to prevent neutropenia as plinabulin, with fewer toxic and side effects. In combination with a commercialized leucocyte-promoting drug mecapegfilgrastim, the therapeutic effect of the two derivatives is more excellent than that of the groups of mecapegfilgrastim alone and in combination with plinabulin. In the aspect of preventing chemotherapy-induced myelosuppression, the number of various blood cells can be remarkably increased in the groups of the two derivatives in combination with a chemotherapy drug. The derivative provided in the present invention has wide application prospects in anti-tumor treatment, prevention of neutropenia, and prevention of myelosuppression, and other such aspects.
C07D 403/14 - Composés hétérocycliques contenant plusieurs hétérocycles, comportant des atomes d'azote comme uniques hétéro-atomes du cycle, non prévus par le groupe contenant au moins trois hétérocycles
A61K 31/496 - Pipérazines non condensées contenant d'autres hétérocycles, p. ex. rifampine, thiothixène ou sparfloxacine
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Pang, Xuan
Zhou, Yanchuan
Duan, Ranlong
Sun, Zhiqiang
Chen, Xuesi
Abrégé
123333422 to prepare a polycarbonate material. In addition, a second component epoxy monomer is added to the reaction system, such that a polybasic polycarbonate material with rich structures can be synthesized, the molecular weight thereof reaching 44.4 kg/mol.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY , CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Yang, Xiaoniu
Li, Shuo
Lv, Hongying
Yang, Lei
Tu, Jiangshan
Wu, Haiyang
Abrégé
Provided is a preparation method for a tube. The method comprises the following steps: a) adding a polymer solution into a poor solvent, such that the polymer diffuses on the liquid level of the poor solvent, so as to obtain a polymer film, wherein the solvent in the polymer solution is dissolved in the poor solvent; b) curling the polymer film on the liquid level of the poor solvent by using a mold to obtain a bar; and c) removing the mold to obtain a tube. The present invention further provides the use of the tube as an artificial tubular tissue. According to the method provided by the present invention, the introduction of a binder is avoided, such that the conditions of the resulting tube being uneven in terms of stress, easily breakable, etc., are avoided; moreover, uniform and controllable wall thickness and uniform and stable mechanical properties can be realized. In addition, the method provided by the present invention does not need complex equipment, does not need a heating process and can be completed at room temperature throughout the whole process, and cannot result in heat influence or thermal inactivation on active substances in the tubular material.
A61L 27/50 - Matériaux caractérisés par leur fonction ou leurs propriétés physiques
A61L 27/18 - Matériaux macromoléculaires obtenus par des réactions autres que celles faisant intervenir uniquement des liaisons non saturées carbone-carbone
A61L 27/16 - Matériaux macromoléculaires obtenus par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carbone
A61L 27/40 - Matériaux composites, c.-à-d. en couches ou contenant un matériau dispersé dans une matrice constituée d'un matériau analogue ou différent
A61L 29/06 - Matériaux macromoléculaires obtenus autrement que par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carbone
A61L 29/12 - Matériaux composites, c.-à-d. en couches ou contenant un matériau dispersé dans une matrice constituée d'un matériau analogue ou différent
16.
VACCINE ADJUVANT, AND PREPARATION METHOD THEREFOR AND USE THEREOF
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY , CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Xu, Weiguo
Su, Yuanzhen
Ding, Jianxun
Zhuang, Xiuli
Chen, Xuesi
Abrégé
22 and/or a tertiary amine. Compared with the prior art, the amino-modified polylactic acid is used as a vaccine adjuvant, and a vaccine obtained by means of compounding the vaccine adjuvant with a vaccine antigen complex is more easily phagocytized by dendritic cells and initiates an immune response, and has a good immune effect and a high biocompatibility.
A61K 39/39 - Préparations médicinales contenant des antigènes ou des anticorps caractérisées par les additifs immunostimulants, p. ex. par les adjuvants chimiques
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
He, Chaoliang
Zhang, Zhen
Ren, Hui
Chen, Xuesi
Abrégé
The present invention provides a polyethylene glycol derivative comprising a repeat unit having the structure of Formula (I) and a terminal group having the structure of Formula (II). The polyethylene glycol derivative provided by the present invention has good biocompatibility, due to the repeat unit having the structure of Formula (I); and can react with various groups such as amino, (acyl)hydrazino, and aminooxy with a fast reaction rate under mild reaction conditions, due to the o-phthalaldehyde terminal group having the structure of Formula (II). The polyethylene glycol derivative provided by the present invention is mixed with polyethylene glycol having an amino-containing terminal group in an aqueous medium, to rapidly form a chemically cross-linked hydrogel material. The hydrogel material has mild preparation conditions, fast gel-forming speed, high mechanical strength, and good stability. This polyethylene glycol hydrogel can be applied as drug sustained-release carrier, tissue engineering scaffold, etc. in the field of biomedical materials.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ge, Junjie
Shi, Zhaoping
Xing, Wei
Liu, Changpeng
Hou, Shuai
Jiang, Jiadong
Jin, Zhao
Liang, Liang
Liu, Shiwei
Abrégé
The present disclosure provides a preparation method and device for a metal oxide supported iridium/ruthenium-based catalyst, comprising: S1. dispersing metal oxide in hydrochloric acid, carrying out heating treatment in an inert atmosphere, and washing and drying to obtain a precursor; S2. dispersing the precursor and a dispersing agent in an organic solvent to obtain a suspension; S3. adding an iridium salt/ruthenium salt into the suspension, and carrying out a constant-temperature reflux reaction to obtain the metal oxide supported iridium/ruthenium-based catalyst. The preparation method is simple, economical and environment-friendly, and is suitable for industrial large-scale production. Moreover, the prepared catalyst is a corrosion-resistant non-noble metal oxide supported catalyst, noble metal particles are small in particle size, low in loading capacity and high in dispersity, and the catalytic activity is high.
C25B 1/04 - Hydrogène ou oxygène par électrolyse de l'eau
C25B 11/093 - Électrodes comportant des électro-catalyseurs sur un substrat ou un support caractérisées par le matériau électro-catalytique formé d’au moins un élément catalytique et d’au moins un composé catalytiqueÉlectrodes comportant des électro-catalyseurs sur un substrat ou un support caractérisées par le matériau électro-catalytique formé de plusieurs éléments catalytiques ou composés catalytiques au moins un métal noble ou oxyde de métal noble et au moins un oxyde d’un métal non noble
C25B 11/097 - Plusieurs métaux nobles ou alliages de métaux nobles
B01J 37/02 - Imprégnation, revêtement ou précipitation
B01J 35/10 - Catalyseurs caractérisés par leur forme ou leurs propriétés physiques, en général solides caractérisés par leurs propriétés de surface ou leur porosité
19.
CHLOROSULFONATED POLY(PROPYLENE CARBONATE), AND PREPARATION METHOD THEREFOR AND USE THEREOF
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Jiang, Wei
Jin, Jing
Gao, Yunbao
Yan, Nan
Yang, Jun
Abrégé
Provided are chlorosulfonated poly(propylene carbonate), and a preparation method therefor and a use thereof. The chlorosulfonated poly(propylene carbonate) has a structure represented by formula I. Compared with existing poly(propylene carbonate) and chlorinated poly(propylene carbonate), chlorosulfonated poly(propylene carbonate) having a specific structure is obtained by means of design of the present invention; due to a combined action of a sulfonyl group and a chlorine element, electronegativity is greatly enhanced, and an electron withdrawing capability is rapidly improved so that the chlorosulfonated poly(propylene carbonate) can have better interaction with other materials, and thus can be applied to the fields of adhesives, adhesive stickers, coatings, and the like. According to the present invention, a chlorosulfonyl active group having high activity is introduced into a molecular chain of the poly(propylene carbonate) so that a molecular weight of a final product can be reduced to different extents, interfacial compatibility of the poly(propylene carbonate) with different base materials is effectively regulated and controlled, and thus the form and viscosity of the product are changed. Moreover, the chlorosulfonated poly(propylene carbonate) is also a fully biodegradable material.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Jin, Yongdong
Qi, Guohua
Wang, Bo
Abrégé
The invention discloses an electrochemical device for treating cancer, characterized by using an acupuncture needle as a working electrode to produce hydrogen in a tumor tissue, thereby destroying the tumor tissue through the produced hydrogen gas. The device of the invention has low cost and simple operation, can realize minimally invasive treatment, and is green and environmentally friendly.
A61N 1/36 - Application de courants électriques par électrodes de contact courants alternatifs ou intermittents pour stimuler, p. ex. stimulateurs cardiaques
21.
POLYTHIOPHENE CONJUGATED POLYMER CONTAINING ELECTRON-WITHDRAWING SUBSTITUENT, PREPARATION METHOD THEREFOR AND USE THEREOF
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Liu, Jun
Meng, Bin
Deng, Sihui
Wang, Lixiang
Abrégé
A polythiophene conjugated polymer containing an electron-withdrawing substituent, a preparation method therefor, and the use thereof. The structural formula of the polymer is as represented by formula I. The preparation method comprises: under the protection of an inert atmosphere, dissolving a dibromo monomer, a bis-trialkyltin monomer, a palladium catalyst and a ligand in an organic solvent; and carrying out a Stille polymerization reaction under the conditions of darkness and heating to reflux, so as to obtain a polythiophene conjugated polymer containing an electron-withdrawing substituent. Further provided is the use of the polythiophene conjugated polymer, which contains the electron-withdrawing substituent and is represented by formula I, in an organic field effect transistor as an electron transport material, and the use of the polythiophene conjugated polymer as an n-type high-molecular thermoelectric material.
C08G 61/12 - Composés macromoléculaires contenant d'autres atomes que le carbone dans la chaîne principale de la macromolécule
H01L 51/05 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés au redressement, à l'amplification, à la génération d'oscillations ou à la commutation et ayant au moins une barrière de potentiel ou une barrière de surface; Condensateurs ou résistances à l'état solide, ayant au moins une barrière de potentiel ou une barrière de surface
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ge, Junjie
Li, Yang
Xing, Wei
Wang, Xian
Yang, Xiaolong
Liu, Changpeng
Li, Chenyang
Liang, Liang
Jin, Zhao
Liu, Shiwei
Abrégé
A method for preparing monodisperse noble metal catalyst, comprising: dissolving zinc acetate and ellagic acid in a first solvent, washing, and drying to obtain a carrier precursor (S11); dissolving the carrier precursor in a second solvent to obtain a carrier precursor solution; dissolving a noble metal salt in the second solvent to obtain a noble metal salt solution; adding the noble metal salt solution fractionally into the carrier precursor solution for reacting to obtain a catalyst precursor (S12); grinding and mixing the catalyst precursor and a nitrogen-containing organic substance, and performing a heat treatment in a reducing atmosphere to obtain a monodisperse noble metal catalyst (S13). The preparation method has a simple operation and mild conditions, and can obtain a catalyst that has ultra-low noble metal loading, ultrahigh activity and an ultrahigh noble metal utilization rate. The monodisperse noble metal catalyst obtained by the preparation method can be applied to the electrooxidation of carbon monoxide and the purification of carbon monoxide in hydrogen.
METHOD FOR SEPARATING YTTRIUM OXIDE FROM HIGH-YTTRIUM RARE EARTH ORE BY GROUPING MANNER AND METHOD FOR SEPARATING YTTRIUM OXIDE FROM MEDIUM-YTTRIUM AND EUROPIUM-RICH EARTH ORE BY GROUPING MANNER
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Chen, Ji
Deng, Yuefeng
Li, Deqian
Li, Hailian
Yang, Maohua
Liu, Yu
Zou, Dan
Bai, Yan
Chang, Yongqing
Abrégé
The present disclosure relates to a method for separating yttrium oxide from a high-yttrium rare earth ore by a grouping manner and a method for separating yttrium oxide from a medium-yttrium and europium-rich rare earth ore by a grouping manner, and belongs to the technical field of rare earth extraction and separation. The separating method by a grouping manner according to the present disclosure have advantages such as being advanced and reasonable, short process, low production cost, good adaptability, and easy operation and control. The method has better overall technical and economic indicator performance than the naphthenic acid process and has the value of practical application.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY , CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Wang, Lixiang
Shao, Shiyang
Chen, Fan
Zhao, Lei
Wang, Shumeng
Wang, Xingdong
Lv, Jianhong
Abrégé
STST and a TADF effect; and the boron/sulfur (selenium, tellurium) hybrid fused ring unit has a rigid skeleton structure, and can reduce the degree of relaxation of an excited-state structure, thereby achieving a narrower full width at half maximum. The introduction of a hole transport unit and/or an electron transport unit into a side chain of a polymer can also cause the polymer to have good carrier transport capability, thereby achieving high device efficiency. The polymer is used as a luminescent layer of a solution processing device, so that the narrower electroluminescent full width at half maximum and high external quantum efficiency of the device can be achieved under the condition of not needing an optical filter and a microcavity structure.
C08F 112/14 - Monomères ne contenant qu'un seul radical aliphatique non saturé contenant un cycle substitué par des hétéro-atomes ou des groupes contenant des hétéro-atomes
C08F 212/14 - Monomères contenant un seul radical aliphatique non saturé contenant un cycle substitué par des hétéro-atomes ou des groupes contenant des hétéro-atomes
C09K 11/06 - Substances luminescentes, p. ex. électroluminescentes, chimiluminescentes contenant des substances organiques luminescentes
H01L 51/50 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED)
25.
SCAFFOLD MATERIAL, PREPARATION METHOD THEREFOR, AND USE THEREOF
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Song, Wantong
Si, Xinghui
Ma, Sheng
Zhang, Yu
Tang, Zhaohui
Chen, Xuesi
Abrégé
A scaffold material, which is obtained by means of crosslinking multi-armed amino polyethylene glycol with polyaldehyde dextran. A cross-linked grid is formed by means of the Schiff base effect of aldehyde groups and amino groups; and when a medicine is carried, the medicine can be encapsulated in a scaffold, and furthermore, the medicine can be locally and slowly released at a focal point, and the problems of a quick in vivo metabolism and a low utilization rate of the medicine are effectively solved. The scaffold material has wide development prospects in the application aspects of maintaining the in vivo drug concentration, reducing the administration dosage, improving the drug utilization rate, avoiding drug resistance and the like. In addition, the scaffold material is simple and mild in preparation, free from selectivity for supported drug types, wide in application range, and good in biocompatibility.
A61K 9/19 - Préparations médicinales caractérisées par un aspect particulier à l'état particulaire, p. ex. poudres lyophilisées
A61K 47/36 - PolysaccharidesLeurs dérivés, p. ex. gommes, amidon, alginate, dextrine, acide hyaluronique, chitosane, inuline, agar-agar ou pectine
A61K 31/704 - Composés ayant des radicaux saccharide liés à des composés non-saccharide par des liaisons glycosidiques liés à un composé carbocyclique, p. ex. phloridzine liés à un système carbocyclique condensé, p. ex. sennosides, thiocolchicosides, escine, daunorubicine, digitoxine
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
He, Chaoliang
Zhang, Zhen
Ren, Hui
Chen, Xuesi
Abrégé
A polyethylene glycol derivative, comprising a repeating unit having a structure of formula (I) and a terminal group having a structure of formula (II). The provided polyethylene glycol derivative has good biocompatibility due to the repeating unit having the structure of formula (I). Because the phthalaldehyde terminal group having the structure of formula (II) can react with various groups such as amino, hydrazide group, and aminooxy group, the reaction rate is fast, and the reaction conditions are mild. A chemically crosslinked hydrogel material can be formed quickly by mixing in an aqueous medium the provided polyethylene glycol derivative and polyethylene glycol having terminal groups comprising amino group, the preparation conditions are mild, the gel forming speed is fast, and a high mechanical strength and a good stability are achieved. The polyethylene glycol hydrogel can be used as a sustained-release drug carrier or a tissue engineering stent in the field of biomedical materials.
C07D 405/12 - Composés hétérocycliques contenant à la fois un ou plusieurs hétérocycles comportant des atomes d'oxygène comme uniques hétéro-atomes du cycle et un ou plusieurs hétérocycles comportant des atomes d'azote comme uniques hétéro-atomes du cycle contenant deux hétérocycles liés par une chaîne contenant des hétéro-atomes comme chaînons
A61K 47/10 - AlcoolsPhénolsLeurs sels, p. ex. glycérolPolyéthylène glycols [PEG]PoloxamèresAlkyléthers de PEG/POE
A61K 47/18 - AminesAmidesUréesComposés d’ammonium quaternaireAcides aminésOligopeptides ayant jusqu’à cinq acides aminés
A61L 24/00 - Adhésifs ou ciments chirurgicauxAdhésifs pour dispositifs de colostomie
A61L 24/04 - Adhésifs ou ciments chirurgicauxAdhésifs pour dispositifs de colostomie contenant des matériaux macromoléculaires
A61L 27/18 - Matériaux macromoléculaires obtenus par des réactions autres que celles faisant intervenir uniquement des liaisons non saturées carbone-carbone
C07C 269/04 - Préparation de dérivés d'acide carbamique, c.-à-d. de composés contenant l'un des groupes l'atome d'azote ne faisant pas partie de groupes nitro ou nitroso à partir d'amines avec formation de groupes carbamate
C08G 18/10 - Procédés mettant en œuvre un prépolymère impliquant la réaction d'isocyanates ou d'isothiocyanates avec des composés contenant des hydrogènes actifs, dans une première étape réactionnelle
C08G 18/38 - Composés de bas poids moléculaire contenant des hétéro-atomes autres que l'oxygène
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Zhuang
Liu, Hanmeng
Yao, Zhixia
Liu, Yaosheng
Diao, Yongxing
Hu, Guangxing
Abrégé
A heater for a mask, an electric heating mask and a processing method therefor. The heater comprises: a heating body (301) which is of a sheet structure and has a control circuit electrically connected to an external power supply and used for converting an electrical energy into a thermal energy; and a heat transfer breathable body which is a heat conduction body, has breathable holes, is provided on the surface of the heating body (301), and contacts with the heating body (301) for transferring heat.
A41D 13/11 - Masques de protection du visage, p. ex. pour utilisation chirurgicale ou pour utilisation en atmosphère polluée
A41D 13/005 - Vêtements protecteurs de travail ou de sport, p. ex. blouses de chirurgien ou vêtements protégeant des coups ou des chocs avec des conditions d'environnement interne qui sont commandées avec une température commandée
29.
HEATING FILTER-TYPE FACE MASK AND USAGE METHOD THEREFOR
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Zhuang
Liu, Hanmeng
Yao, Zhixia
Liu, Yaosheng
Diao, Yongxing
Hu, Guangxing
Abrégé
A heating filter-type face mask and a usage method therefor, the mask comprising: a face mask body and a breathing tube. The face mask body has an curvature, and an accommodating cavity is formed in the inner side of the curvature. The breathing tube is provided on the surface of the face mask body. The inside of the breathing tube is used to place a fabric structure and a heating structure at intervals, and both the fabric structure and the heating structure are breathable. The mask may improve the comfort of the face and breathing gas, increase the temperature of air inhaled, and may suppress heat intolerant pathogenic sources outside the mask and kill or shorten the survival time of heat intolerant pathogenic sources inside the mask, thereby achieving effective protection in scenarios that are conducive to low temperature pathogenic sources. The face mask may be worn and used directly or used in conjunction with a mask when the user is wearing said mask. After use, the worn heating filter-type face mask, or the worn heating filter-type face mask and the mask may be subjected to high temperature treatment, which can achieve cyclical usage of the heated filter face mask.
A62B 18/08 - Parties constitutives des casques ou masques à gaz, p. ex. fenêtres, sangles, transmetteurs de voix, dispositifs de signalisation
A61L 2/04 - Procédés ou appareils de désinfection ou de stérilisation de matériaux ou d'objets autres que les denrées alimentaires ou les lentilles de contactAccessoires à cet effet utilisant des phénomènes physiques de la chaleur
30.
METHOD FOR EFFICIENTLY INDUCING PHASE SEPARATION OF WATER-ORGANIC SOLVENT MIXED SOLUTION WITH INORGANIC SALT
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY , CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Lu, Yuyuan
Li, Minglun
An, Lijia
Abrégé
242444; and B) leaving the solution obtained in step A) to stand in a constant temperature environment until the phases are completely separated in order to obtain the product.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Zhuang
Liu, Hanmeng
Yao, Zhixia
Liu, Yaosheng
Diao, Yongxing
Abrégé
A urinal (2) and a toilet bowl. The urinal (2) comprises: a urinal main body, the urinal main body opening upwards, a urinal cavity (201) for storing urine (205) being formed inside the urinal main body, the urinal cavity (201) being internally provided with a sealing storage liquid (204), and the sealing storage liquid (204) being an organic compound which has a specific gravity less than the urine (205) and is insoluble in water, such that the sealing storage liquid (204) covers the urine (205); and a drainage pipe assembly (4), which is used for discharging the urine (205) in the urinal cavity (201) and comprises a drainage pipe (401), the drainage pipe (401) being communicated with the urinal cavity (201).
A47K 11/04 - Cuvettes de cabinets de chambreChaises avec vase de toilette ou spécialement adaptées pour être utilisées avec une cuvette de toilette, p. ex. chaises percées
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Jin, Yongdong
Qi, Guohua
Wang, Bo
Abrégé
An electrochemical device for treating cancer, using an acupuncture needle as a working electrode to produce hydrogen in tumor tissue, thereby destroying the tumor tissue by the produced hydrogen. The device has a low cost and simple operation, can achieve minimally invasive treatment, and is environmentally friendly.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Liao, Wuping
Wu, Guolong
Zhang, Zhifeng
Li, Yanling
Abrégé
11-41-3231-121-121-121-61-121-61233 is greater than 10. The used phosphoryl carboxylic acid extractant is easy to synthesize, and the chemical raw materials used for synthesis are simple and easy to obtain and are low-cost, which may effectively reduce the costs of separating yttrium from other rare earth elements, and which has high industrial application value.
C22B 3/38 - Traitement ou purification de solutions, p. ex. de solutions obtenues par lixiviation par extraction liquide-liquide utilisant des composés organiques contenant du phosphore
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Song, Xinyue
Zhang, Jidong
Li, Caihua
Abrégé
A multi-threading sample testing method for an X-ray diffractometer. The method uses multi-threading technology, and comprises: one core of a CPU in an X-ray diffractometer starting an input thread, wherein the input thread is used for receiving sample information and a test condition input by a user and respectively storing the sample information and the test condition in corresponding arrays; another core of the CPU starting a test thread, and the test thread controlling, according to the sample information and the test condition, a detector to test a sample; and the testing thread saving a test result according to the sample information of the sample and displaying the test result on a display terminal. By means of different threads of a computer respectively controlling a sample testing process and a sample information and test condition inputting process, a background thread performs control by using another CPU core to perform testing while the sample information and the test condition are input, the time occupied by the input process is saved on, and the test efficiency of a high-speed X-ray diffractometer with a plurality of sample stages is improved.
G01N 23/20008 - Détails de construction des appareils d’analyse, p. ex. caractérisés par la source de rayons X, le détecteur ou le système optique à rayons XLeurs accessoiresPréparation d’échantillons à cet effet
G01N 23/20025 - Porte-échantillons ou leurs supports
35.
BRANCHED POLYAMINO ACID BACTERIOSTATIC AGENT AND APPLICATION THEREOF
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (Chine)
Inventeur(s)
Ji, Shengxiang
Liu, Xiao
Han, Miaomiao
Liu, Yadong
Guo, Jianwei
Abrégé
The present invention provides a branched poly(amino acid) antimicrobial agent, comprising a branched poly(amino acid); the branched poly(amino acid) is obtained by the homopolymerization of one amino acid unit, or is obtained by the copolymerization of two or more amino acid units; the amino acid unit has a structure shown by Formula I. The present invention uses the amino acid as raw material, is non-toxic, has no side effects, and is a green and environmentally friendly new antimicrobial agent, and accessible to the users. The branched structure of the poly(amino acid) results in that such material has many active functional groups, may be further modified, has good biocompatibility, and will not develop drug resistance during the long-term use of this antimicrobial agent.
The present invention provides a branched poly(amino acid) antimicrobial agent, comprising a branched poly(amino acid); the branched poly(amino acid) is obtained by the homopolymerization of one amino acid unit, or is obtained by the copolymerization of two or more amino acid units; the amino acid unit has a structure shown by Formula I. The present invention uses the amino acid as raw material, is non-toxic, has no side effects, and is a green and environmentally friendly new antimicrobial agent, and accessible to the users. The branched structure of the poly(amino acid) results in that such material has many active functional groups, may be further modified, has good biocompatibility, and will not develop drug resistance during the long-term use of this antimicrobial agent.
METHOD FOR GROUPING AND SEPARATING YTTRIUM OXIDE FROM HIGH-YTTRIUM RARE EARTH ORE AND METHOD FOR GROUPING AND SEPARATING YTTRIUM OXIDE FROM MIDDLE-YTTRIUM EUROPIUM-RICH RARE EARTH ORE
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Chen, Ji
Deng, Yuefeng
Li, Deqian
Li, Hailian
Yang, Maohua
Liu, Yu
Zou, Dan
Bai, Yan
Chang, Yongqing
Abrégé
A method for grouping and separating yttrium oxide from high-yttrium rare earth ore and a method for grouping and separating yttrium oxide from middle-yttrium europium-rich rare earth ore, relating to the technical field of rare earth extraction and separation, and solving the problems of naphthenic acid needing to be replaced and the difficulty of quickly analysing the concentration changes of two extractants in a HAB system on site during the long-term use of yttrium oxide separation process flows in existing naphthenic acid systems and HAB mixed systems. The grouping and separation methods have the advantages of being advanced and rational and having a short process flow, low production cost, strong adaptability, and easy operation and control, the performance of comprehensive technical and economic indicators being superior to naphthenic acid processes, and having practical application value.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (Chine)
Inventeur(s)
Xu, Weilin
Yang, Fa
Bi, Yipiao
Ruan, Mingbo
Song, Ping
Abrégé
The present disclosure relates to a method for preparing an ordered porous carbon materials with inexpensive carbon black. The method comprises: dispersing carbon black into a concentrated nitric acid to obtain a uniform dispersion; placing the dispersion in a reactor to perform a reaction by a one-step hydrothermal process; and washing and drying the reaction mixture to obtain an ordered porous carbon material in a honeycomb-like arrangement and rich in oxygen defects. The present disclosure also relates to an ordered porous carbon material prepared by the method, a method for electrocatalytically reducing carbon dioxide to formic acid under ambient temperature and atmospheric pressure by using the ordered porous carbon material, and a method for electrocatalytically reducing nitrogen to ammonia under ambient temperature and atmospheric pressure by using the ordered porous carbon material as a supported catalyst.
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Jiang, Wei
Gao, Yunbao
Cui, Xihua
Cui, Jie
Liu, Jingchuan
Abrégé
The present invention provides a chlorinated poly(propylene carbonate)/biomass composite material, comprising 3 wt % to 57 wt % of a chlorinated poly(propylene carbonate); 40 wt % to 94 wt % of a biomaterial; 2 wt % to 20 wt % of a rosin or a rosin derivative; 0 wt % to 1 wt % of an antioxidant; and 0 wt % to 5 wt % of a filler, wherein a sum of amounts of all components is 100 wt %. The chlorinated poly(propylene carbonate) functions as a binder, and plays an important role in the moisture resistance of the composite material. The rosin or the rosin derivative functions as a viscosifier and a lubricant, and can also improve the moisture resistance and mechanical property of the composite material. Under the synergistic effect of the above components, the composite material obtained in the present invention is excellent in both mechanical property and moisture resistance. Further, because the starting materials comprise a larger amount of biomass materials, the cost thereof is low, and because the starting materials contain no formaldehyde, benzene and the like, the material is environment friendly.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Yang, Xiaoniu
Zhang, Bo
Zhao, Xiaoli
Li, Xiaoxiao
Tian, Yumeng
Abrégé
23222, 1 ≤ n ≤ 20, 1 ≤ m ≤ 10, and 1 ≤ p ≤ 10. The method for reversibly protecting a polyamine by means of carbon dioxide, when used for common polyurethane systems, can realize the preparation of a polyurethane by means of a low molecular weight polyamine as a chain extender, and the prepared polyurethane has very good mechanical properties, thereby broadening the application of different forms of aliphatic polyamines as chain-extending cross-linking agents in polyurethane elastomer materials.
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Zhao, Xuesen
Abrégé
The present disclosure provides a blue organic electroluminescent device comprising: a substrate; an anode layer disposed on the substrate; a light emitting layer disposed on the anode layer, the light emitting layer being formed from a blue organic fluorescent material and a hole-type organic host material, wherein the blue organic fluorescent material is 8.0% to 25.0% by mass of the hole-type organic host material; and a cathode layer disposed on the light emitting layer.
H01L 51/56 - Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
H01L 51/50 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED)
H01L 51/00 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
41.
White organic electroluminescent device and preparation method thereof
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Abrégé
The present disclosure provides a white organic electroluminescent device, comprising: a substrate; an anode layer; a first light emitting layer formed from a red organic fluorescent material, a first energy-sensitized organic material and a first hole-type organic host material; a second light emitting layer formed from a green organic fluorescent material, a second energy-sensitized organic material and a second hole-type organic host material; and a cathode layer.
H01L 51/50 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED)
H01L 51/00 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
H01L 51/56 - Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
42.
NOVEL BIO-BASED FURAN POLYETHER ESTER COPOLYMER AND PREPARATION METHOD THEREFOR
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Guangyuan
Wang, Rui
Jiang, Min
Zhang, Qiang
Wang, Guoqiang
Abrégé
The present invention provides a polyether ester copolymer having a structure represented by formula (I) or (I'), wherein n is 10 to 200; m is 0 to 200; p is selected from one or a plurality of 1, 2, 3, 4, and 5. The bio-based furan polyether ester copolymer provided by the present invention has a controlled content of glycol segments in the structure, and such a polyether ester copolymer has better thermodynamic properties and the color tone of the product is improved. Moreover, the present invention can carry out esterification, precondensation, and polycondensation reactions with FDCA and diol monomers under a catalytic action of a metal complex catalyst and/or an esterification catalyst, to efficiently prepare a high-viscosity fully bio-based furan polyether ester copolymer with a novel structure at lower temperatures in a relatively short period of time. The molecules of the bio-based furan polyether ester copolymer contain a controlled content of oligo-glycol segments, and the reaction process is stable, easy to control and involves mild conditions. The invention has an economical and environmentally-friendly preparation method suitable for large-scale industrial production.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Guangyuan
Wang, Rui
Jiang, Min
Zhang, Qiang
Wang, Guoqiang
Abrégé
The present invention relates to a method for preparing 2,5-furandicarboxylic acid, comprising reacting a furoate, a molten salt, and a catalyst under the condition of carbon dioxide gas, to obtain a 2,5-furandicarboxylate; subjecting the 2,5-furandicarboxylate to acidification to obtain 2,5-furandicarboxylic acid, wherein the molten salt has a melting point less than or equal to 400°C; the catalyst comprises a metal salt catalyst and/or an organic base catalyst, and preferably, the furoate is obtained by a neutralization reaction of furoic acid, a basic compound, and water. 2,5-furandicarboxylic acid is prepared starting from a furoate, by using a cheap and readily available conventional metal salt as a catalyst, especially a monomer or a mixture of a low melting organic or inorganic salt as a molten salt. The catalyst and molten salt used are all low-cost chemical products, thus greatly reducing reaction costs, the process is simple, and the reaction temperature is low. The method is an economical and environmentally friendly preparation method suitable for large-scale industrial production and promotes the industrialization process of 2,5-furandicarboxylic acid.
JIANGSU SINC-TECH POLYMERIZATION NEW MATERIALS INDUSTRY TECHNOLOGY RESEARCH INSTITUTE (Chine)
CHANG CHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Guangyuan
Wang, Honghua
Li, Wei
Abrégé
A method of preparation of a cardo polyetherketone structural foam material, including the following steps: 1) performing a mould pressing on a cardo polyetherketone resin by a high-temperature vulcanizing machine to prepare a foaming billet; 2) placing the foaming billet in a foaming cavity of a mould-pressing machine, performing a penetration and a swelling by introducing a supercritical fluid to achieve diffusion equilibrium, forming a polymer-supercritical fluid homogeneous solution, and 3) making the polymer-supercritical fluid homogeneous solution supersaturated through a sudden release of the inner pressure of the system, thereby inducing nucleation and foaming, and finally forming a structural foam having a closed pore structure with a uniform pore size and an adjustable pore density. The production process of the present invention is clean, environmentally friendly, and has relatively high efficiency. The obtained structural foam has good mechanical properties.
C08J 9/12 - Mise en œuvre de substances macromoléculaires pour produire des matériaux ou objets poreux ou alvéolairesLeur post-traitement utilisant des gaz de gonflage produits par un agent de gonflage introduit au préalable par un agent physique de gonflage
B29C 44/02 - Moulage par pression interne engendrée dans la matière, p. ex. par gonflage ou par moussage pour la fabrication d'objets de longueur définie, c.-à-d. d'objets séparés
C08G 65/40 - Composés macromoléculaires obtenus par des réactions créant une liaison éther dans la chaîne principale de la macromolécule à partir de composés hydroxylés ou de leurs dérivés métalliques dérivés des phénols à partir des phénols et d'autres composés
C08J 9/00 - Mise en œuvre de substances macromoléculaires pour produire des matériaux ou objets poreux ou alvéolairesLeur post-traitement
C08L 71/10 - Polyéthers dérivés de composés hydroxylés ou de leurs dérivés métalliques de phénols
B29C 67/20 - Techniques de façonnage non couvertes par les groupes , ou pour la fabrication d'objets poreux ou cellulaires, p. ex. des mousses plastiques, des mousses alvéolaires
B29C 44/00 - Moulage par pression interne engendrée dans la matière, p. ex. par gonflage ou par moussage
B29C 43/00 - Moulage par pressage, c.-à-d. en appliquant une pression externe pour faire couler la matière à moulerAppareils à cet effet
B29K 71/00 - Utilisation de polyéthers comme matière de moulage
45.
Preparation method and use of thickness-controllable bismuth nanosheet and bismuth alloy nanosheet
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Liu, Jianwei
Ma, Xianfeng
Abrégé
A preparation method for a copper material and the copper material prepared therefrom. The method comprises the following steps: ball-milling copper powder to obtain copper nano powder having high activity; cold-pressing the copper nano powder having high activity to form a blank body; and sintering the blank body to obtain the copper material.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ji, Shengxiang
Liu, Xiao
Han, Miaomiao
Liu, Yadong
Guo, Jianwei
Abrégé
Provided in the present invention is a branched polyamino acid bacteriostatic agent, comprising a branched polyamino acid; the branched polyamino acid is obtained by homopolymerisation of one amino acid unit or copolymerisation of two or more amino acid units; the amino acid unit has the structural formula shown in formula I. The raw material used in the present invention is the amino acid, having no toxicity and no side effects, and being a green and environmentally-friendly new bacteriostatic agent that is easily accepted by users. The branched structure of the polyamino acid means that the substance has many reactive functional groups, can be further modified, and has good biocompatibility, and long-term use of the bacteriostatic agent will not cause drug resistance.
C08G 69/10 - Polyamides dérivés, soit des acides amino-carboxyliques, soit de polyamines et d'acides polycarboxyliques dérivés d'acides aminocarboxyliques d'acides alpha-aminocarboxyliques
C08G 69/08 - Polyamides dérivés, soit des acides amino-carboxyliques, soit de polyamines et d'acides polycarboxyliques dérivés d'acides aminocarboxyliques
C08G 69/48 - Polymères modifiés par post-traitement chimique
A01N 43/38 - Biocides, produits repoussant ou attirant les animaux nuisibles, ou régulateurs de croissance des végétaux, contenant des composés hétérocycliques comportant des cycles avec un atome d'azote comme unique hétéro-atome du cycle des cycles à cinq chaînons condensés avec des carbocycles
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Wu, Chunji
Liu, Bo
Cui, Dongmei
Abrégé
A copolymer of ethylene and a conjugated diene is provided, in which ethylene content in the copolymer is greater than 20 mol %, the copolymer has a glass transition temperature between −110° C. and −90° C., and continuous methylene sequence lengths (MSL) in the copolymer are in a range of 12-162 methylene units. A method for producing the copolymer, comprising copolymerizing ethylene and a conjugated diene in the presence of a catalyst system to obtain the copolymer is also provided, in which the catalyst system comprises a heterocyclic-fused cyclopentadienyl rare-earth metal complex, an organoboron salt compound and an organoaluminum compound, wherein the heterocyclic-fused cyclopentadienyl rare-earth metal complex is represented by the structural formula:
B60C 1/00 - Pneumatiques caractérisés par la composition chimique, la disposition ou le mélange physique de la composition
C08F 4/54 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides en mélange avec d'autres de leurs composés
49.
Fiber grating sensor insert, implanting system and method of intelligent plastic pipe
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
JILIN CORE LOGISTICS AND COATING EQUIPMENT CO., LTD. (Chine)
Inventeur(s)
Jia, Yuxi
Gao, Linlin
An, Lijia
Yao, Weiguo
Wan, Guoshun
Ye, Hui
Zhang, Leida
Abrégé
A fiber grating sensor insert, implanting system and method of an intelligent plastic pipe. A fiber grating sensors' strip-shaped insert is accurately implanted in an oblique guiding manner in the pipe's outer surface during the continuous extrusion molding process of the plastic pipe, so that temperature and strain sensors implanted beforehand in strip-shaped insert are buried in the pipe, and the sensors' survival in a bad pipe manufacturing and working environment is ensured, real-time online monitoring on parameters of the pipe such as temperature, strain, pressure and the like is achieved, the conventional continuous extrusion process technology of plastic pipes is combined with optical fiber communication technology, and the manufactured intelligent plastic pipe can achieve real-time online monitoring of temperature, strain, pressure and other parameters, and then can realize the safety early warning, fault diagnosis and automatic control of urban pipe networks, thereby effectively promoting the construction of “smart cities”.
G02B 6/00 - Guides de lumièreDétails de structure de dispositions comprenant des guides de lumière et d'autres éléments optiques, p. ex. des moyens de couplage
G01K 11/32 - Mesure de la température basée sur les variations physiques ou chimiques, n'entrant pas dans les groupes , , ou utilisant des changements dans la transmittance, la diffusion ou la luminescence dans les fibres optiques
G01L 1/24 - Mesure des forces ou des contraintes, en général en mesurant les variations des propriétés optiques du matériau quand il est soumis à une contrainte, p. ex. par l'analyse des contraintes par photo-élasticité
50.
Anthracene-based organic dyes and preparation methods thereof
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Wang, Peng
Ren, Yameng
Zhang, Min
Wang, Junting
Li, Yang
Abrégé
b, thereby the power conversion efficiency of a dye sensitized solar cell is significantly improved when the organic dye prepared according to the present invention is applied in a dye-sensitized solar cell. Furthermore, the preparation method of the organic dye according to the present invention is quite simple together with abundant raw materials and low cost, making it possible to be commercialized.
C07D 285/00 - Composés hétérocycliques contenant des cycles comportant des atomes d'azote et de soufre comme uniques hétéro-atomes du cycle, non prévus par les groupes
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Jiang, Wei
Gao, Yunbao
Cui, Xihua
Cui, Jie
Liu, Jingchuan
Abrégé
The present invention provides a chlorinated poly(propylene carbonate)/biomass composite material, comprising: 3-57 wt% chlorinated poly(propylene carbonate), 40-94 wt% biological material, 2-20 wt% rosin or derivatives thereof, 0-1 wt% antioxidant, and 0-5 wt% filler, and the sum of amounts of all components is 100 wt%. The chlorinated poly(propylene carbonate) is an adhesive, and plays an important role in humidity resistance of the composite material. The rosin or derivatives thereof are a tackifier and a lubricant, and can improve the humidity resistance and mechanical property of the composite material. By means of the synergistic action of the components, the composite material obtained in the present invention has better mechanical property and humidity resistance. In addition, because the biomass material in the raw material has a large proportion, the cost is low; and there is no formaldehyde, benzene and the like in the raw material, the present invention is environment friendly.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
JILIN CORE LOGISTICS AND COATING EQUIPMENT CO., LTD. (Chine)
Inventeur(s)
Jia, Yuxi
Guo, Yunli
An, Lijia
Yao, Weiguo
Gao, Linlin
Wang, Qinglin
Jiang, Mingshun
Wang, Haiqing
Zhi, Jieying
Zhao, Yaru
Sui, Qingmei
Abrégé
A composite material packaged fiber grating sensor and a manufacturing method thereof. The sensor includes a fiber grating sensor component, a composite material coverage layer, a resin package layer and a composite material substrate layer. In the sensor, a temperature fiber grating and a strain fiber grating are packaged in a composite material structure, so that the structure is light and simple, its computability with the composite material is good, the measurement accuracy is high, and the survival rate and the service life of the installed sensor can be greatly improved, the sensor component can be externally pasted on to or inter-implanted in a composite material structural part, and can be applied to the distributed online health monitoring on the structural part. The manufacturing method of the composite material packaged fiber grating sensor is simple, efficient and stable, and is suitable for rapid mass production by enterprises.
B29C 70/34 - Façonnage par empilage, c.-à-d. application de fibres, de bandes ou de feuilles larges sur un moule, un gabarit ou un noyauFaçonnage par pistolage, c.-à-d. pulvérisation de fibres sur un moule, un gabarit ou un noyau et façonnage ou imprégnation par compression
B29C 70/44 - Façonnage ou imprégnation par compression pour la fabrication d'objets de longueur définie, c.-à-d. d'objets distincts utilisant une pression isostatique, p. ex. moulage par différence de pression, avec un sac à vide, dans un autoclave ou avec un caoutchouc expansible
G01K 11/32 - Mesure de la température basée sur les variations physiques ou chimiques, n'entrant pas dans les groupes , , ou utilisant des changements dans la transmittance, la diffusion ou la luminescence dans les fibres optiques
G01D 21/02 - Mesure de plusieurs variables par des moyens non couverts par une seule autre sous-classe
G01L 1/24 - Mesure des forces ou des contraintes, en général en mesurant les variations des propriétés optiques du matériau quand il est soumis à une contrainte, p. ex. par l'analyse des contraintes par photo-élasticité
B29C 70/88 - Façonnage de matières composites, c.-à-d. de matières plastiques comprenant des renforcements, des matières de remplissage ou des parties préformées, p. ex. des inserts caractérisées principalement par des propriétés spécifiques, p. ex. électriquement conductrices ou renforcées localement
G01D 5/353 - Moyens mécaniques pour le transfert de la grandeur de sortie d'un organe sensibleMoyens pour convertir la grandeur de sortie d'un organe sensible en une autre variable, lorsque la forme ou la nature de l'organe sensible n'imposent pas un moyen de conversion déterminéTransducteurs non spécialement adaptés à une variable particulière utilisant des moyens optiques, c.-à-d. utilisant de la lumière infrarouge, visible ou ultraviolette avec atténuation ou obturation complète ou partielle des rayons lumineux les rayons lumineux étant détectés par des cellules photo-électriques en modifiant les caractéristiques de transmission d'une fibre optique
B29C 70/54 - Parties constitutives, détails ou accessoiresOpérations auxiliaires
53.
FIBER GRATING SENSOR INSERT FOR SMART PLASTIC PIPE, AND IMPLANTATION SYSTEM AND METHOD
A fiber grating sensor insert for a smart plastic pipe, comprising: a base resin (7), a fiber grating temperature sensor (1), a fiber grating strain sensor (2) and reinforcing fibers (6); the fiber grating temperature sensor (1) and the fiber grating strain sensor (2) are placed side-by-side in parallel, the two being provided with multiple grating units (4); the positions of the grating units (4) correspond to each other so as to jointly form a grating pair having the function of monitoring both temperature and strain. The fiber grating temperature sensor and the fiber grating strain sensor are embedded within the base resin (7), the base resin also being filled with the reinforcing fibers; the reinforcing fibers are evenly distributed in parallel within a strip-shaped insert of the fiber grating sensor so as to support the entire frame of the strip-shaped insert of the fiber grating sensor. Further disclosed are an implantation system for the strip-shaped insert of the fiber grating sensor and a method for preparing the smart plastic pipe. According to the present invention, by combining the conventional processing technology of continuous extrusion of a plastic pipe material and fiber-optic communication technology, fabricated smart plastic pipes may monitor parameters, such as temperature, strain and pressure, online and in real-time.
G01D 5/00 - Moyens mécaniques pour le transfert de la grandeur de sortie d'un organe sensibleMoyens pour convertir la grandeur de sortie d'un organe sensible en une autre variable, lorsque la forme ou la nature de l'organe sensible n'imposent pas un moyen de conversion déterminéTransducteurs non spécialement adaptés à une variable particulière
G01B 7/16 - Dispositions pour la mesure caractérisées par l'utilisation de techniques électriques ou magnétiques pour mesurer les déformations dans un solide, p. ex. au moyen d'une jauge de contrainte à résistance
G01K 11/32 - Mesure de la température basée sur les variations physiques ou chimiques, n'entrant pas dans les groupes , , ou utilisant des changements dans la transmittance, la diffusion ou la luminescence dans les fibres optiques
54.
Copolymer of ethylene and a conjugated diene, and process for its production
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Wu, Chunji
Liu, Bo
Cui, Dongmei
Abrégé
A copolymer of ethylene and a conjugated diene is provided, in which ethylene content in the copolymer is greater than 20 mol %, the copolymer has a glass transition temperature between −110° C. and −90° C., and continuous methylene sequence lengths (MSL) in the copolymer are in a range of 12-162 methylene units. A method for producing the copolymer, comprising copolymerizing ethylene and a conjugated diene in the presence of a catalyst system to obtain the copolymer is also provided, in which the catalyst system comprises a heterocyclic-fused cyclopentadienyl rare-earth metal complex, an organoboron salt compound and an organoaluminum compound, wherein the heterocyclic-fused cyclopentadienyl rare-earth metal complex is represented by the structural formula:
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Wang, Jin
Zhang, Hongming
Wang, Xianhong
Wang, Fosong
Abrégé
A waterborne polyurethane dispersion and a solvent-free preparation method thereof related to the technical field of preparation of waterborne polyurethane, that resolves existing issues associated with using an organic solvent in a preparation process of waterborne polyurethane. The method comprises reacting at least one polyhydroxy oligomer polyol and at least one polyisocyanate with a small molecule hydrophilic chain extender to form a polyurethane prepolymer having a terminal NCO group; then reacting the polyurethane prepolymer having a terminal NCO group with a small molecule neutralizer, adding water at 60-100°C, reducing the temperature of the reaction system to 20-50°C after dispersal under stirring, adding water again, and obtaining a prepolymer dispersion solution after further dispersal; and finally reacting the prepolymer dispersion solution with a sulfonate polyamine hydrophilic chain extender, then further reacting with a polyamine chain extender to obtain a waterborne polyurethane dispersion. A waterborne polyurethane dispersion obtained by the above preparation method is provided. The method does not comprise adding an organic solvent in the preparation process, and is environmentally friendly.
C08G 18/12 - Procédés mettant en œuvre un prépolymère impliquant la réaction d'isocyanates ou d'isothiocyanates avec des composés contenant des hydrogènes actifs, dans une première étape réactionnelle utilisant plusieurs composés contenant un hydrogène actif dans le premier stade de la polymérisation
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Abrégé
3phen is selected as the organic sensitive material, and a trace amount of the same is doped into the electron-dominated light-emitting layer, which has the function of an energy transporting ladder and a deep binding center for charge carriers, so as to improve the light-emitting effectiveness, spectral stability, and service life of the device, reduce the operating voltage of the device, and delay the attenuation of the effectiveness of the device.
H01L 51/00 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
H01L 51/52 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED) - Détails des dispositifs
H01L 51/56 - Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
C09K 11/06 - Substances luminescentes, p. ex. électroluminescentes, chimiluminescentes contenant des substances organiques luminescentes
H01L 51/50 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED)
57.
WHITE ORGANIC ELECTROLUMINESCENT DEVICE AND PREPARATION METHOD THEREFOR
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Abrégé
A white organic electroluminescent device, comprising: a substrate; an anode layer; a first luminescent layer made of a red organic fluorescent material, a first organic energy sensitized material and a first hole-type organic host material; a second luminescent layer made of a green organic fluorescent material, a second organic energy sensitized material and a second hole-type organic host material; and a cathode layer. Compared with the prior art, a blue organic fluorescent material is used as the luminescent material and the energy sensitized material, so that the photon energy can be transferred to the red organic fluorescent material or the green organic fluorescent material, effectively. Meanwhile, the blue organic fluorescent material also has excellent electron transmission capability, has higher doping concentration in the luminescent layers, facilitates balancing the distribution of the holes and the electrons between the luminescent sections, and also can limit the recombination of the holes and the electrons in the narrow areas of the luminescent layers.
H01L 51/50 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED)
H01L 51/52 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED) - Détails des dispositifs
H01L 51/56 - Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
58.
BLUE ORGANIC ELECTROLUMINESCENT DEVICE AND PREPARATION METHOD THEREFOR
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Zhao, Xuesen
Abrégé
A blue organic electroluminescent device, comprising: a substrate (1); an anode layer (2) provided on the substrate; a luminescent layer (5) provided on the anode layer and formed by a blue organic fluorescent material and a hole-type organic host material, the mass of the blue organic fluorescent material being 8.0% to 25.0% of that of the hole type organic host material; and a cathode layer (8) provided on the luminescent layer. The blue organic electroluminescent device uses the blue organic fluorescent material whose excited state energy is less than that of the hole-type organic host material as a luminescent material, has both relatively high luminous efficiency and color purity, has good thermal stability, and also has an excellent electron transport capability, the dosage concentration is relatively high in the luminescent layer, the device can have functions of both the host material and the blue light material, a balance of distribution of holes and electrons in a luminescent interval is facilitated, recombination of the holes and electrons can also be limited in a narrow region of the luminescent layer, and distribution of carriers in the luminescent layer can be effectively balanced.
H01L 51/50 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED)
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Wang, Lixiang
Ding, Junqiao
Bai, Keyan
Zhao, Lei
Abrégé
The present invention provides a poly-spirofluorene represented by formula (I). In the present invention, a carbazole group is introduced to a side chain of spirofluorene to synthesize a polymer containing carbazole spirofluorene. The polymer containing carbazole spirofluorene prepared in the present invention does not have an intramolecular charge transfer effect from a primary chain to a side chain; and the polymer has a good hole transport capability due to the modification cation of the carbazole, and a good component efficiency can be achieved while the color purity of pure blue light is ensured. By introducing an aromatic group to the poly-spirofluorene in the present invention, transmission of three-primary colors that are blue, green and red can be obtained, thereby achieving the good component efficiency.
A composite material-encapsulated fiber grating sensor, comprising a fiber grating sensor assembly, a composite material cover layer (6), a resin encapsulation layer (7) and a composite material substrate layer (8). The sensor encapsulates a temperature grating (3) and a strain grating (2) in a composite material structure, which achieves a lightweight structure, good compatibility with a composite material, high measurement accuracy, and remarkably improved survival rate and service life of a sensor installation. A sensor assembly may be posted outside of and embedded in a composite material structure, and may be used for distributed on-line health monitoring of the structure. Also disclosed is a method for manufacturing the composite material-encapsulated fiber grating sensor, and the method is simple, efficient and stable, and suitable for high-volume rapid enterprise production.
G01D 21/02 - Mesure de plusieurs variables par des moyens non couverts par une seule autre sous-classe
G01K 11/32 - Mesure de la température basée sur les variations physiques ou chimiques, n'entrant pas dans les groupes , , ou utilisant des changements dans la transmittance, la diffusion ou la luminescence dans les fibres optiques
G01B 11/16 - Dispositions pour la mesure caractérisées par l'utilisation de techniques optiques pour mesurer la déformation dans un solide, p. ex. indicateur optique de déformation
61.
Blue organic electroluminescent device and preparation method thereof
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Jiang, Yunlong
Abrégé
3phen is selected as the organic sensitive material, and a trace amount of the same is doped into the electron-dominated light-emitting layer, which has the function of an energy transporting ladder and a deep binding center for charge carriers, so as to improve the luminescence efficiency, spectral stability, and service life of the device, reduce the operating voltage of the device, and delay the attenuation of the effectiveness of the device.
H01L 51/00 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
C09K 11/06 - Substances luminescentes, p. ex. électroluminescentes, chimiluminescentes contenant des substances organiques luminescentes
H01L 51/56 - Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
H01L 51/52 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED) - Détails des dispositifs
H01L 51/50 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED)
62.
POLYMER CA4 BONDING PHARMACEUTICAL COMPOUND AND PREPARATION METHOD THEREFOR
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Tang, Zhaohui
Song, Wantong
Yu, Haiyang
Niu, Yuewei
Zhang, Dawei
Ma, Sheng
Zhang, Yu
Chen, Xuesi
Abrégé
A polymer CA4 bonding pharmaceutical compound and a preparation method therefor, the compound having the structure as shown in formula (I). CA4 is grafted onto a specific polymer carrier to enable a resulting bonding drug to enrich at a tumor vessel and to slowly release active drugs so as to act to damage the tumor vessels at a tumor site for a long period of time, thereby achieving excellent tumor inhibition results, and effectively solving the problems of short action time and poor efficacy of CA4P. The present invention has a broad development prospect in the oncotherapy field. Moreover, the preparation method is simple, and the raw materials are widely accessible, and thus mass production and industrialization may be achieved.
A61K 31/167 - Amides, p. ex. acides hydroxamiques ayant des cycles aromatiques, p. ex. colchicine, aténolol, progabide ayant l'atome d'azote d'un groupe carboxamide lié directement au cycle aromatique, p. ex. lidocaïne, paracétamol
A61K 35/00 - Préparations médicinales contenant des substances ou leurs produits de réaction de constitution non déterminée
C08G 69/48 - Polymères modifiés par post-traitement chimique
63.
Functionalized highly syndiotactic polystyrene and preparation method thereof
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Cui, Dongmei
Liu, Dongtao
Wang, Zichuan
Abrégé
Compared to the prior art, this invention provides a functionalized highly syndiotactic polystyrene, comprising a repeating unit having a structure represented by formula (I), or comprising a repeating unit having a structure represented by formula (I) and a repeating unit having a structure represented by formula (II). It is indicated by the experimental results that the syndiotacticity selectivity of the highly syndiotactic polymer provided by this invention is no less than 90%, and the proportion of the repeating unit having a structure represented by formula (I) in the polymer may be arbitrarily adjusted and may be up to 100%. Meanwhile, the oxygen- or sulfur-containing groups in the polymer may increase the polarity of the highly syndiotactic polystyrene so as to increase the blendability of the highly syndiotactic polystyrene with other polymers.
C08F 4/52 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides choisis parmi le bore, l'aluminium, le gallium, l'indium, le thallium ou les terres rares
C08F 212/14 - Monomères contenant un seul radical aliphatique non saturé contenant un cycle substitué par des hétéro-atomes ou des groupes contenant des hétéro-atomes
C08F 4/54 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides en mélange avec d'autres de leurs composés
C08F 4/12 - Composés métalliques autres que les hydrures et autres que les composés organiques de métalComplexes d'halogénures de bore ou d'halogénures d'aluminium avec des composés organiques contenant de l'oxygène de bore, d'aluminium, de gallium, d'indium, de thallium ou des terres rares
C08F 112/14 - Monomères ne contenant qu'un seul radical aliphatique non saturé contenant un cycle substitué par des hétéro-atomes ou des groupes contenant des hétéro-atomes
64.
ANTHRACENYL ORGANIC DYE AND PREPARATION METHOD THEREFOR
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Wang, Peng
Ren, Yameng
Zhang, Min
Wang, Junting
Li, Yang
Abrégé
Provided are an anthracenyl organic dye and a preparation method therefor. The organic dye has the structure shown in formula (I) or formula (II), wherein Ra, Rb and R2-1 – R2-4 are defined in the present document. The organic dye is prepared by modifying Ra and Rb on an anthracenyl group, or by modifying Ra and Rb on anthracenyl groups connected by an aryl group or a heteroaryl group. When applied to a dye-sensitised solar cell, the organic dye significantly increases the photoelectric conversion efficiency of the cell. The preparation method for the organic dye is simple, the raw materials are widely available, costs are low, and industrial production may be implemented.
C07D 285/00 - Composés hétérocycliques contenant des cycles comportant des atomes d'azote et de soufre comme uniques hétéro-atomes du cycle, non prévus par les groupes
C09B 3/82 - Préparation à partir de substances contenant déjà le noyau anthracène condensé
C09B 5/00 - Colorants à noyau anthracène condensé avec un ou plusieurs hétérocycles avec ou sans carbocycles
C09B 1/00 - Colorants à noyau anthracène non condensé avec d'autres cycles
Changchun Institute Of Applied Chemistry, Chinese Academy Of Sciences (Chine)
Inventeur(s)
Liao, Wuping
Li, Yanling
Zhang, Zhifeng
Wu, Guolong
Lu, Youcai
Abrégé
The present invention relates to use of an amino-containing neutral phosphine extractant of Formula I in extraction and separation of thorium, and a process of extracting and separating thorium using the amino-containing neutral phosphine extractant of Formula I,
1-16 alkyl and hydrogen, and n is an integer of 1 to 8.
C01F 1/00 - Procédés de préparation des composés des métaux béryllium, magnésium, aluminium, calcium, strontium, baryum, radium, thorium ou des terres rares, en général
C22B 3/06 - Extraction de composés métalliques par voie humide à partir de minerais ou de concentrés par lixiviation dans des solutions inorganiques acides
C22B 60/02 - Obtention du thorium, de l'uranium ou des autres actinides
C22B 3/38 - Traitement ou purification de solutions, p. ex. de solutions obtenues par lixiviation par extraction liquide-liquide utilisant des composés organiques contenant du phosphore
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Qiu, Xuepeng
Dai, Xuemin
Li, Guomin
Dong, Zhixin
Liu, Fangfang
Ji, Xiangling
Gao, Lianxun
Abrégé
A polyimide fiber is prepared from a dianhydride compound and a diamine compound. The diamine compound is selected from one or more compounds in formulae (I), (II), (III), (IV). The polyimide fiber prepared by a polyimide polymer system having a specific hydroxyl heterocyclic diamine copolymerization structure is higher in strength and modulus, and resistant to high temperature. In addition, active groups are provided on the surface of the prepared polyimide fiber, so the polyimide fiber is easily adhered to various resin matrices. A prepared composite material has an excellent mechanical property.
D01F 6/74 - Filaments, ou similaires, faits par l’homme, à un seul composant, formés de polymères synthétiquesLeur fabrication à partir de produits d'homopolycondensation à partir de polycondensats de composés cycliques, p. ex. à partir de polyimides, polybenzimidazoles
D01F 6/78 - Filaments, ou similaires, faits par l’homme, à un seul composant, formés de polymères synthétiquesLeur fabrication à partir de produits de copolycondensation
C08G 73/10 - PolyimidesPolyester-imidesPolyamide-imidesPolyamide-acides ou précurseurs similaires de polyimides
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Qiu, Xuepeng
Dai, Xuemin
Li, Guomin
Dong, Zhixin
Liu, Fangfang
Ji, Xiangling
Gao, Lianxun
Abrégé
A polyimide fiber and a preparation method therefor. The method comprises: enabling a dianhydride compound and a diamine compound to make a polymerization reaction in a solvent to obtain a polyamide acid solution, the diamine compound comprising diamine having a structure as shown in Formula (12) or Formula (13), where A is S or O, the dianhydride compound comprising one or more of dianhydrides having a structure as shown in Formula (14) and Formula (15), where t is 0 or 1; spinning the polyamide acid solution to obtain a polyamide acid fiber; and performing imidization and hot stretching on the polyamide acid fiber in sequence to obtain a polyimide fiber. The polyimide fiber having the structure is higher in rigidity, and hydrogen bonds can be introduced to provide an interaction between molecular chains, thereby influencing the arrangement and crystallinity of the molecular chains in a polymer, and endowing the polyimide fiber with a better mechanical property. The obtained polyimide fiber is higher in glass-transition temperature (Tg) and better in heat resistance.
D01F 6/74 - Filaments, ou similaires, faits par l’homme, à un seul composant, formés de polymères synthétiquesLeur fabrication à partir de produits d'homopolycondensation à partir de polycondensats de composés cycliques, p. ex. à partir de polyimides, polybenzimidazoles
C08G 73/10 - PolyimidesPolyester-imidesPolyamide-imidesPolyamide-acides ou précurseurs similaires de polyimides
D01F 6/78 - Filaments, ou similaires, faits par l’homme, à un seul composant, formés de polymères synthétiquesLeur fabrication à partir de produits de copolycondensation
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Chengyu
Sun, Wenzhi
Pang, Ran
Jiang, Lihong
Zhang, Su
Abrégé
Provided are an orange light LED fluorescent powder, a preparation method therefor and a use thereof, wherein the LED fluorescent powder has a general formula represented by formula I: Sr9-a-b-xMaMg1.5+b(PO4)7 : xEu2+; and in formula I, M is one or two of Ca and Ba, and 0.001 ≤ x ≤ 0.9, 0 ≤ a ≤ 1.0, 0 ≤ b ≤ 2.3. The LED fluorescent powder with a phosphate as a matrix and Eu2+ ions as activation ions has stable chemical properties; the excitation band thereof is broader, the emission spectrum contains abundant red light components, and after the fluorescent powder is encapsulated with a blue light gallium nitride chip to form an LED, the LED can emit warm white light; and the fluorescent powder is non-radioactive, and does not harm the environment. The experimental results show that the fluorescent powder can be effectively excited by light in a wave band of 250-500 nm to emit broad peaks at 470-850 nm, wherein the main emission peak is located near 523 nm and 620 nm. The preparation method is simple, has lower production cost, and is easy for industrial production.
C09K 11/71 - Substances luminescentes, p. ex. électroluminescentes, chimiluminescentes contenant des substances inorganiques luminescentes contenant du phosphore contenant aussi des métaux alcalino-terreux
H01L 33/50 - DISPOSITIFS À SEMI-CONDUCTEURS NON COUVERTS PAR LA CLASSE - Détails caractérisés par les éléments du boîtier des corps semi-conducteurs Éléments de conversion de la longueur d'onde
69.
PREPARATION METHOD FOR POLY(CARBONATE-ETHER)POLYOL
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Liu, Shunjie
Qin, Yusheng
Wang, Xianhong
Qiao, Lijun
Wang, Fosong
Abrégé
Provided is a preparation method for a poly(carbonate-ether)polyol, comprising: reacting a carboxylic acid with an acidity constant of 0.2-4 with an epoxide to obtain an intermediate product, and polymerizing the intermediate product with carbon dioxide under the effect of a rare earth-doped double metal cyanide of Zn3[Co(CN)6]2 to obtain a poly(carbonate-ether)polyol. In the preparation method for a poly(carbonate-ether)polyol provided by the present invention, a carboxylic acid with an appropriate acidity constant is used as an initiator; the carboxylic acid is used to activate the epoxide; and polyethers of different molecular weights generated in situ by activation are used as chain transfer agents for participating in the polymerization of carbon dioxide and the epoxide under the effect of the rare earth-doped double metal cyanide of Zn3[Co(CN)6]2. The preparation method for a poly(carbonate-ether)polyol has a relatively short reaction time and a low content of a propylene carbonate by-product in the product.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (Chine)
Inventeur(s)
Jiang, Wei
Zhao, Guiyan
Dong, Lisong
Jin, Jing
Cui, Jie
Abrégé
This invention provides a chlorinated poly(propylene carbonate) and the preparation method thereof, the chlorinated poly(propylene carbonate) is as represented by formula (I). Compared to the prior poly(propylene carbonate)s, the chlorinated poly(propylene carbonate) has relatively stronger electronegativity due to the presence of chlorine atoms and the interaction of the chlorinated poly(propylene carbonate) with other polar materials can be enhanced, so that it can be widely used as a compatilizer, a binder, a paint, an ink, and the like. After the introduction of chlorine atoms, hydrogen bond interaction is generated within the chlorinated poly(propylene carbonate), so that its processability and mechanical properties are both improved. Furthermore, the chlorine atom may improve the flame retardancy of chlorinated poly(propylene carbonate) materials.
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Cui, Dongmei
Wu, Chunji
Yao, Changguang
Abrégé
This invention provides a metallocene complex and the preparation method thereof and a catalyst composition. This catalyst composition comprises a metallocene complex represented by formula (I) and an organic boron salt. Compared to the prior art, the catalyst used in this invention, which is the metallocene complex represented by formula (I), does not contain a group bonding between the heterocyclic fused cyclopentadienyl ring and the transition metal, and the coordination space of the central metal has a large opening degree. Therefore, the catalytic activity for more sterically hindered monomers is higher, and the comonomer incorporation is also higher. Furthermore, the metallocene complex represented by formula (I) used in this invention is a heterocyclic ring fused cyclopentadienyl ligand. Heterocyclic rings have relatively strong electron-donating capacity. By fusing a cyclopentadienyl group using heterocyclic rings, it is possible to change the electronic effect of the metal center and in turn increase the activity of catalyst. Therefore, by using the metallocene complex represented by formula (I), it is possible to prepare copolymers of ethylene with other olefins at high activity and high comonomer incorporation, and it is also possible to catalyze the polymerization of styrene and substituted styrene at high syndiotacticity and high activity.
C08F 4/52 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides choisis parmi le bore, l'aluminium, le gallium, l'indium, le thallium ou les terres rares
C08F 10/00 - Homopolymères ou copolymères d'hydrocarbures aliphatiques non saturés contenant une seule liaison double carbone-carbone
C08F 36/20 - Homopolymères ou copolymères de composés contenant un ou plusieurs radicaux aliphatiques non saturés, l'un au moins contenant plusieurs liaisons doubles carbone-carbone le radical ne contenant que deux doubles liaisons carbone-carbone non conjuguées
C08F 4/58 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides en mélange avec du silicium, du germanium, de l'étain, du plomb, de l'antimoine, du bismuth ou leurs composés
C07F 19/00 - Composés métalliques couverts par plus d'un des groupes principaux
Changchun Institute of Applied Chemistry Chinese Academy of Sciences (Chine)
Inventeur(s)
Wang, Peng
Yao, Zhaoyang
Abrégé
The present invention provides an organic dye, a process for producing the same and the use thereof. The organic dye has the structure of formula (I) or formula (II). The regulation of the molecular energy levels and three-dimensional structures are achieved by ring-merging phenanthrocarbazole and an electron-rich thiophene unit as well as by selecting appropriate substituents. Thereby, when the organic dye of the present invention is applied to a dye-sensitized solar cell, the power conversion efficiency of the dye-sensitized solar cell is greatly improved. Meanwhile, the raw materials for the process according to the present invention have plenty of sources with low costs, so that a commercial production can be effected.
C09B 57/00 - Autres colorants synthétiques de structure connue
H01L 51/00 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
73.
Metalporphyrin complex, preparation method therefor and method for preparing polycarbonate
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (Chine)
Inventeur(s)
Wu, Wei
Qin, Yusheng
Fu, Shuangbin
Wang, Xianhong
Wang, Fosong
Abrégé
4—, —CN, p-methyl benzoate, o-nitrophenol oxygen anion, 2,4-dinitrophenol oxygen anion, 2,4,6-trinitrophenol oxygen anion, 3,5-dichlorophenol oxygen anion and pentafluorophenol oxygen anion. The metalporphyrin complex provided in the present invention has two quaternary ammonium functional groups or two quaternary phosphonium functional groups, and compared with the prior art, the metalporphyrin complex shows higher catalytic activity in catalyzing polymerization reaction of carbon dioxide and an epoxide.
C07D 487/22 - Composés hétérocycliques contenant des atomes d'azote comme uniques hétéro-atomes dans le système condensé, non prévus par les groupes dans lesquels le système condensé contient au moins quatre hétérocycles
C08G 64/34 - Procédés généraux de préparation utilisant du dioxyde de carbone et de éthers cycliques
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Liao, Wuping
Li, Yanling
Zhang, Zhifeng
Wu, Guolong
Lu, Youcai
Abrégé
A use of an amino group-containing neutral phosphine extraction agent having formula I for the extraction and separation of thorium, and a thorium extraction and separation method for the use. R1 and R2 are each independently selected from C1-C12 alkyl groups, R3 and R4 are each independently selected from C1-16 alkyl groups and hydrogen, and n is an integer from 1 to 8.
C22B 60/02 - Obtention du thorium, de l'uranium ou des autres actinides
C22B 3/38 - Traitement ou purification de solutions, p. ex. de solutions obtenues par lixiviation par extraction liquide-liquide utilisant des composés organiques contenant du phosphore
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Liao, Wuping
Lu, Youcai
Zhang, Zhifeng
Li, Yanling
Wu, Guolong
Abrégé
A use of an amino group-containing neutral phosphine extraction agent having the following formula I for the extraction and separation of tetravalent cerium, and a method using the amino group-containing neutral phosphine extraction agent having formula I to extract and separate tetravalent cerium. R1 and R2 are each independently selected from C1-C12 alkyl groups, R3 and R4 are each independently selected from C1-16 alkyl groups and hydrogen, and n is an integer from 1 to 8.
C22B 3/38 - Traitement ou purification de solutions, p. ex. de solutions obtenues par lixiviation par extraction liquide-liquide utilisant des composés organiques contenant du phosphore
C22B 59/00 - Obtention des métaux des terres rares
76.
RANDOM-SYNDIOTACTIC BLOCK POLYBUTADIENE AND PREPARATION METHOD THEREOF
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY ,CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Xuequan
Zheng, Wenjie
Hu, Yanming
Zhang, Chunyu
Bi, Jifu
Abrégé
The present invention relates to the field of polymer materials. Disclosed are a random-syndiotactic block polybutadiene and preparation method thereof, the provided random-syndiotactic block polybutadiene having a structure of formula (I), and comprising a random polybutadiene structure and a syndiotactic 1, 2-polybutadiene structure, being useful as a compatibilizing agent to improve the compatibility of the syndiotactic 1, 2- polybutadiene/ polybutadiene rubber blend. Experimental results show that, compared to a purely syndiotactic 1, 2-polybutadiene/polybutadiene rubber blend, the addition of the random-syndiotactic block polybutadiene thereto significantly improves the compatibility.
C08F 293/00 - Composés macromoléculaires obtenus par polymérisation sur une macromolécule contenant des groupes capables d'amorcer la formation de nouvelles chaînes polymères rattachées exclusivement à une ou aux deux extrémités de la macromolécule de départ
C08F 8/00 - Modification chimique par post-traitement
77.
BLUE ORGANIC ELECTROLUMINESCENT DEVICE AND PREPARATION METHOD THEREOF
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Jiang, Yunlong
Abrégé
A blue organic electroluminescent device, composed of a substrate (1), an anode layer (2), an anode modification layer (3), a hole transport-electron blocking layer (4), a hole-dominated light-emitting layer (5), an electron-dominated light-emitting layer (6), a hole blocking-electron transport layer (7), a cathode modification layer (8), and a cathode layer (9) arranged in sequence; the electron-dominated layer (6) is composed of organic sensitised material, blue organic light-emitting material, and electron-type organic host material. Selecting rare earth complexes of matching energy levels such as Tm (acac) 3phen or Dy (acac) 3phen as the organic sensitised material, and doping trace amounts of same into the electron-dominated light-emitting layer (6), which has the function of a charge carrier deep binding centre and an energy transport ladder, improves the light-emitting effectiveness, spectral stability, and service life of the device, reduces the operating voltage of the device, and delays the attenuation of effectiveness of the device.
H01L 51/52 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED) - Détails des dispositifs
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Feng, Jing
Abrégé
A red organic electroluminescent device, composed of a substrate (1), an anode layer (2), an anode modification layer (3), a hole transport-electron blocking layer (4), a hole-dominated light-emitting layer (5), an electron-dominated light-emitting layer (6), a hole blocking-electron transport layer (7), a cathode modification layer (8), and a cathode layer (9) arranged in sequence; the electron-dominated layer (6) is composed of organic sensitised material, red organic light-emitting material, and electron-type organic host material. Selecting rare earth complexes of matching energy levels such as EU (DBM) 3phen or EU (TTA) 3phen as the organic sensitised material, and doping trace amounts of same into the electron-dominated light-emitting layer (6), which has the function of a charge carrier deep binding centre and an energy transport ladder, improves the light-emitting effectiveness, spectral stability, and service life of the device, reduces the operating voltage of the device, and delays the attenuation of effectiveness of the device.
H01L 51/50 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED)
H01L 51/56 - Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Cui, Rongzhen
Abrégé
A yellow organic electroluminescent device, composed of a substrate (1), an anode layer (2), an anode modification layer (3), a hole transport-electron blocking layer (4), a hole-dominated light-emitting layer (5), an electron-dominated light-emitting layer (6), a hole blocking-electron transport layer (7), a cathode modification layer (8), and a cathode layer (9) arranged in sequence; the electron-dominated layer (6) is composed of organic sensitised material, yellow organic light-emitting material, and electron-type organic host material. Selecting rare earth complexes of matching energy levels such as Tb (acac) 3 or Tb (acac) 3phen as the organic sensitised material, and doping trace amounts of same into the electron-dominated light-emitting layer (6), which has the function of a charge carrier deep binding centre and an energy transport ladder, improves the light-emitting effectiveness, spectral stability, and service life of the device, reduces the operating voltage of the device, and delays the attenuation of effectiveness of the device.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Li, Yanan
Abrégé
A green organic electroluminescent device, composed of a substrate (1), an anode layer (2), an anode modification layer (3), a hole transport-electron blocking layer (4), a hole-dominated light-emitting layer (5), an electron-dominated light-emitting layer (6), a hole blocking-electron transport layer (7), a cathode modification layer (8), and a cathode layer (9) arranged in sequence; the electron-dominated layer (6) is composed of organic sensitised material, green organic light-emitting material, and electron-type organic host material. Selecting rare earth complexes of matching energy levels such as Tb (acac) 3 or Tb (acac) 3phen as the organic sensitised material, and doping trace amounts of same into the electron-dominated light-emitting layer (6), which has the function of a charge carrier deep binding centre and an energy transport ladder, improves the light-emitting effectiveness, spectral stability, and service life of the device, reduces the operating voltage of the device, and delays the attenuation of effectiveness of the device.
H01L 51/50 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés pour l'émission de lumière, p.ex. diodes émettrices de lumière organiques (OLED) ou dispositifs émetteurs de lumière à base de polymères (PLED)
H01L 51/56 - Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY ,CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Liang
Zhang, Hongjie
Abrégé
A white organic electroluminescent device, composed of a substrate (1), an anode layer (2), an anode modification layer (3), a hole transport-electron blocking layer (4), a hole-dominated light-emitting layer (5), an electron-dominated light-emitting layer (6), a hole blocking-electron transport layer (7), a cathode modification layer (8), and a cathode layer (9) arranged in sequence; the electron-dominated layer (6) is composed of organic sensitised material, blue organic light-emitting material, and electron-type organic host material. Selecting rare earth complexes of matching energy levels such as Tm (acac) 3phen or Dy (acac) 3phen as the organic sensitised material, and doping trace amounts of same into the electron-dominated light-emitting layer (6), which has the function of a charge carrier deep binding centre and an energy transport ladder, improves the light-emitting effectiveness, spectral stability, and service life of the device, reduces the operating voltage of the device, and delays the attenuation of effectiveness of the device.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Qin, Yusheng
Guo, Hongchen
Wang, Xianhong
Wang, Fosong
Abrégé
The present invention provides a preparation method for cyclic carbonate. The method comprises the following steps: cyclizing carbon dioxide and an epoxide in the presence of a main catalyst and cocatalyst, to obtain the cyclic carbonate, wherein the main catalyst is metalloporphyrin complex having the structure represented by formula (I), and the cocatalyst is one or more selected from quaternary ammonium salts, quaternary phosphonium salts and organic bases. Compared with prior arts, the metalloporphyrin complex can be used as catalyst to catalyze the cyclization of carbon dioxide and epoxide, and shows extremely high catalytic activity as the main catalyst. In addition, during the process of cyclization, the metalloporphyrin complex as the main catalyst has a relatively high selectivity for product, inhibits the formation of polycarbonates, and increases the content of cyclic carbonate in the product. The metalloporphyrin complex can be recovered and reused with relatively high catalytic activity.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Wang, Yong
Qin, Yusheng
Guo, Hongchen
Wang, Xianhong
Wang, Fosong
Abrégé
Provided is a titanium catalyst with a structure as shown in formula (I) and the preparation process and use thereof, the catalyst can efficiently catalyse the copolymerization of an epoxide and carbon dioxide for preparing polycarbonate, and the polycarbonate is non-toxic and can be applied to the field of food and medical packaging.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Cui, Dongmei
Liu, Dongtao
Wang, Zichuan
Abrégé
Compared with the prior art, the present invention provides a functional high-syndiotactic polystyrene having repeat units as represented by structures of formula (I) or formula (I) and (II). The experimental results show that the syndiotactic selectivity of the high-syndiotactic polymer provided by present invention is not less than 90%, and the proportion of the repeat units as represented by structure of formula (I) in the polymer can be optionally adjusted and be up to 100%. Meanwhile, the polymer containing oxygen or sulfur group can increase the polarity of the high-syndiotactic polystyrene, thereby increasing the blend properties of the high-syndiotactic polystyrene and other polymers.
C08F 212/14 - Monomères contenant un seul radical aliphatique non saturé contenant un cycle substitué par des hétéro-atomes ou des groupes contenant des hétéro-atomes
C08F 4/52 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides choisis parmi le bore, l'aluminium, le gallium, l'indium, le thallium ou les terres rares
85.
CYCLOOLEFIN COPOLYMER AND PREPARATION METHOD THEREFOR
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Li, Yuesheng
Li, Yanguo
Yang, Jixing
Cui, Lei
Wang, Yongxia
Mu, Hongliang
Abrégé
A cycloolefin copolymer has a structure represented by formula I, II, III or IV, wherein in the formula I, 100≤x≤350, 25≤y≤150; in the formula II, 300≤z≤1000; in the formula III, 180≤m≤430, 40≤n≤220; and in the formula IV, 250≤i≤500, 20≤j≤144. The present invention provides a method for preparing a cycloolefin copolymer. The method comprises: under the effect of a catalyst, a first compound and a second compound are subjected to polymerization reaction in a solvent to obtain a polymerization reaction product; and the polymerization reaction product and a hydrogen source are subjected to hydrogenation reaction to obtain a cycloolefin copolymer, wherein the first compound has a structure represented by formula 1, and the second compound has a structure represented by formula 1, 2, 3 or 4. The cycloolefin copolymer provided by the present invention has good thermal resistance and mechanical performance.
C08F 232/08 - Copolymères de composés cycliques ne contenant pas de radicaux aliphatiques non saturés dans une chaîne latérale et contenant une ou plusieurs liaisons doubles carbone-carbone dans un système carbocyclique contenant des cycles condensés
C08F 4/80 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux non prévus dans le groupe choisis parmi les métaux du groupe du fer ou les métaux du groupe du platine
86.
Chlorinated poly(propylene carbonate) and preparation method thereof
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (Chine)
Inventeur(s)
Jiang, Wei
Zhao, Guiyan
Dong, Lisong
Jin, Jing
Cui, Jie
Abrégé
This invention provides a chlorinated poly(propylene carbonate) and the preparation method thereof, the chlorinated poly(propylene carbonate) is as represented by formula (I). Compared to the prior poly(propylene carbonate)s, the chlorinated poly(propylene carbonate) has relatively stronger electronegativity due to the presence of chlorine atoms and the interaction of the chlorinated poly(propylene carbonate) with other polar materials can be enhanced, so that it can be widely used as a compatilizer, a binder, a paint, an ink, and the like. After the introduction of chlorine atoms, hydrogen bond interaction is generated within the chlorinated poly(propylene carbonate), so that its processability and mechanical properties are both improved. Furthermore, the chlorine atom may improve the flame retardancy of chlorinated poly(propylene carbonate) materials.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Cui, Dongmei
Liu, Bo
Li, Shihui
Liu, Dongtao
Abrégé
The present invention provides a catalyst composition, comprising: an organic boron salt and a bisimine thioester rare earth complex having a structure of formula (I), with the molar ratio of the organic boron salt to the bisimine thioester rare earth complex having a structure of formula (I) being (0.5-2.0) : 1. The present invention also provides a method for preparing the catalyst composition, comprising the following steps: mixing and reacting the organic boron salt, the bisimine thioester rare earth complex having a structure of formula (I) of claim 1, and an organic solvent, so as to obtain the catalyst composition for preparing a crystalline 3,4-polyisoprene. The catalyst composition for preparing a crystalline 3,4-polyisoprene provided by the present invention has a high selectivity, and can result in a high isotactic crystalline 3,4-polyisoprene with a higher content.
C08F 4/52 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides choisis parmi le bore, l'aluminium, le gallium, l'indium, le thallium ou les terres rares
C08F 4/69 - Chrome, molybdène, tungstène ou leurs composés
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Cui, Dongmei
Wu, Chunji
Yao, Changguang
Abrégé
Provided are a metallocene complex, a preparation method therefor, and a catalyst composition. The catalyst composition comprises a metallocene complex as represented by formula (I) and an organic boron salt. In contrast to the prior art, the metallocene complex as represented by the catalyst formula (I) used in the present invention contains no side chain, and has a large open degree of coordination space of the central metal, therefore having a higher catalytic activity and a higher insertion rate for strongly sterically hindered monomers. Moreover, the metallocene complex as represented by formula (I) used in the present invention is a fused heterocyclic cyclopentadienyl ligand, wherein the heterocycle has a strong capacity of supplying electrons, which can be used for fusing the cyclopentadienyl and changing the electronic effect in the metal centre so as to increase the activity of the catalyst. Hence, the metallocene complex as represented by formula (I) can be used for the preparation of a copolymer of ethylene and other alkenes with a high activity and a high insertion rate, and can also be used for catalyzing the polymerization of styrene and substituted styrene with high syndiotacticity and high activity.
C07F 19/00 - Composés métalliques couverts par plus d'un des groupes principaux
C08F 4/52 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides choisis parmi le bore, l'aluminium, le gallium, l'indium, le thallium ou les terres rares
C08F 232/08 - Copolymères de composés cycliques ne contenant pas de radicaux aliphatiques non saturés dans une chaîne latérale et contenant une ou plusieurs liaisons doubles carbone-carbone dans un système carbocyclique contenant des cycles condensés
C08F 210/16 - Copolymères de l'éthylène avec des alpha-alcènes, p. ex. caoutchoucs EP
C08F 232/06 - Copolymères de composés cycliques ne contenant pas de radicaux aliphatiques non saturés dans une chaîne latérale et contenant une ou plusieurs liaisons doubles carbone-carbone dans un système carbocyclique ne contenant pas de cycles condensés contenant plusieurs doubles liaisons carbone-carbone
89.
WET-METHOD IN ATMOSPHERIC OXIDATION METHOD FOR CERIUM IN RARE EARTH HYDROXIDE
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Chen, Ji
Zou, Dan
Li, Deqian
Liu, Yu
Cui, Hongmin
Abrégé
A wet-method in an atmospheric oxidation method for cerium in a rare earth hydroxide comprises: (1) preparing rare earth hydroxide mixed slurry with an REO concentration of 10 to 100g/L; (2) adjusting the alkalinity of the rare earth hydroxide mixed slurry to be 0.1 to 1.5mol/L; and (3) feeding compressed air into the rare earth hydroxide mixed slurry prepared in step (2), an air flow rate being 0.5 to 10L/min and an air feeding time being 0.5 to 10h.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Wu, Wei
Qin, Yusheng
Fu, Shuangbin
Wang, Xianhong
Wang, Fosong
Abrégé
The present invention provides a metalporphyrin complex having structure represented by formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are independently selected from one of hydrogen, halogen, aliphatic group, substituted heteroaliphatic group, aryl and substituted heteroaryl; n is 1-6; L is quaternary ammonium functional group or quaternary phosphonium functional group; M is a metal element; and X is one of halogen, -NO3, BF4-, -CN, p-methyl benzoate, o-nitrophenol oxygen anion, 2,4-dinitrophenol oxygen anion, 2,4,6-trinitrophenol oxygen anion, 3,5-dichlorophenol oxygen anion and pentafluorophenol oxygen anion. The metalporphyrin complex provided in the present invention has two quaternary ammonium functional groups or two quaternary phosphonium functional groups, and compared with the prior art, the metalporphyrin complex shows higher catalytic activity in catalyzing polymerization reaction of carbon dioxide and an epoxide.
C07D 487/22 - Composés hétérocycliques contenant des atomes d'azote comme uniques hétéro-atomes dans le système condensé, non prévus par les groupes dans lesquels le système condensé contient au moins quatre hétérocycles
91.
Metal alkoxide complex, catalyst composition, and production method of polycaprolactone or polylactide
C07C 33/24 - Alcools monohydroxyliques ne contenant que des cycles aromatiques à six chaînons dans la partie cyclique polycycliques sans système cyclique condensé
C08G 63/83 - Métaux alcalins, métaux alcalino-terreux, béryllium, magnésium, cuivre, argent, or, zinc, cadmium, mercure, manganèse ou leurs composés
C08G 63/85 - Germanium, étain, plomb, arsenic, antimoine, bismuth, titane, zirconium, hafnium, vanadium, niobium, tantale ou leurs composés
C07C 31/30 - Alcoolates alcalins ou alcalino-terreux
B01J 31/02 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des composés organiques ou des hydrures métalliques
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Chen, Xuesi
Cui, Liguo
Zhang, Peibiao
Gao, Zhantuan
Wang, Zongliang
Wang, Yu
Abrégé
A method for preparing a tissue engineering scaffold material comprises: a) mixing biocompatible polyester and a non-polar solvent to obtain a first solution; b) adding a phase transformation solvent into the first solution to obtain a second solution; c) placing the second solution in a mold, removing the non-polar solvent and the phase transformation solvent through a liquid-vapor phase transformation process or/and a liquid-solid phase transformation process, and drying a solute to obtain the tissue engineering scaffold material. The tissue engineering scaffold material has good mechanical properties and high porosity.
A61L 27/18 - Matériaux macromoléculaires obtenus par des réactions autres que celles faisant intervenir uniquement des liaisons non saturées carbone-carbone
93.
DOXORUBICIN CONJUGATE MEDICINE AND PREPARATION METHOD THEREOF
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Zhuang, Xiuli
Ding, Jianxun
Zhang, Jiancheng
Chen, Xuesi
Abrégé
Provided in the present invention is a Doxorubicin conjugate medicine comprising a first repeat unit of a structure of formula (I), a second repeat unit of a structure of formula (II), a third repeat unit of a structure of formula (III) and a fourth repeat unit of a structure of formula (IV). Also provides in the present invention is a method for preparing Doxorubicin conjugate medicine. In the present invention, the Doxorubicin conjugate medicine is obtained by the condensation reaction of glucan, carboxylated doxorubicin derivative, lactose acid and folic acid as raw materials. Among them, lactose acid and folic acid have an active targeting function, and the Doxorubicin conjugate medicine provided in the present invention can realize the concentration of drugs at the tumour site through enhanced permeability and retention effects and the active targeting function. In addition, the polymer- Doxorubicin conjugate medicine provided in the present invention has pH sensitivity, wherein the doxorubicin bond on the polymer medicine via an amide bond can be quickly released under the condition of the pH within a tumour tissue or tumour cell, so as to enhance the effect of the medicine.
A61K 47/48 - Préparations médicinales caractérisées par les ingrédients non actifs utilisés, p.ex. supports, additifs inertes l'ingrédient non actif étant chimiquement lié à l'ingrédient actif, p.ex. conjugués polymère-médicament
A61K 31/704 - Composés ayant des radicaux saccharide liés à des composés non-saccharide par des liaisons glycosidiques liés à un composé carbocyclique, p. ex. phloridzine liés à un système carbocyclique condensé, p. ex. sennosides, thiocolchicosides, escine, daunorubicine, digitoxine
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Tang, Zhaohui
Yu, Haiyang
Song, Wantong
Li, Mingqiang
Zhuang, Xiuli
Chen, Xuesi
Abrégé
Provided in the present invention are a cisplatin complex which is formed by cisplatin and a polymer of the structure of formula (I), and the method for preparing the cisplatin complex, which comprises a coordination reaction of cisplatin with the polymer of the structure of formula (I) in an aqueous medium, resulting in the cisplatin complex. The cisplatin complex has good biocompatibility and is degradable; the side chain of the polymer is grafted with polyethylene glycol, thus the prepared cisplatin complex has good solubility; when the cisplatin complex is dissolved in an aqueous medium, the cisplatin is protected by a hydrophilic polyethylene glycol chain segment and a hydrophobic amino acid chain segment, which can effectively avoid a sudden release of the cisplatin due to the influence of the blood circulation system after intravenous injection, thus improving the stability of the cisplatin complex. Additionally, the carboxyl contained in the cisplatin complex provided in the present invention is sensitive to pH values and tends to deprotonate in a low pH environment, which favors the release of the drug and improves the efficiency of the drug.
A61K 47/48 - Préparations médicinales caractérisées par les ingrédients non actifs utilisés, p.ex. supports, additifs inertes l'ingrédient non actif étant chimiquement lié à l'ingrédient actif, p.ex. conjugués polymère-médicament
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Geng, Yanhou
Tian, Hongkun
Dong, Shaoqiang
Abrégé
A soluble phthalocyanine compound has a structure disclosed as Formula (I) or Formula (II), R being an alkyl group, alkoxy group or alkylthio group, and M being a divalent metal or a tervalent+ metal containing a ligand. In the present invention, an identical substituent group is respectively introduced to sites 2, 3, 16 and 17 of the phthalocyanine core, two benzene rings in the phthalocyanine core are kept not substituted, and besides, the central metal atom can regulate the electronic structure of the substituted phthalocyanine and can also generate a synergistic effect with the substituent group to regulate and control the accumulation mode of the substituted phthalocyanine thin film, and thus, the soluble phthalocyanine compound can be used for acquiring an organic thin film transistor with higher mobility. The present invention also provides a preparation method of the soluble phthalocyanine compound and an organic thin film transistor. The carrier mobility is up to 1cm2/V·s.
C07D 487/22 - Composés hétérocycliques contenant des atomes d'azote comme uniques hétéro-atomes dans le système condensé, non prévus par les groupes dans lesquels le système condensé contient au moins quatre hétérocycles
H01L 51/05 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés au redressement, à l'amplification, à la génération d'oscillations ou à la commutation et ayant au moins une barrière de potentiel ou une barrière de surface; Condensateurs ou résistances à l'état solide, ayant au moins une barrière de potentiel ou une barrière de surface
H01L 51/40 - Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Liu, Changyu
Dong, Shaojun
Abrégé
The present invention provides a method for detecting biochemical oxygen demand. Active sludge, surface water, domestic waste water, or industrial waste water comprising microorganism is taken as a water sample with microorganism in the method provided by the present invention. The water sample with microorganism is cultivated to obtain a microorganism film. The blank water sample and the target water sample are made to pass through the microorganism film respectively. The dissolved oxygen reduction current values of the blank water sample and the target water sample are detected. The difference value between the dissolved oxygen reduction current value of the target water sample and that of the blank water sample is obtained. On the basis of the difference value and the predetermined standard curve, the biochemical oxygen demand of the target water sample is acquired. The method provided by the present invention adopts active sludge, surface water, domestic waste water, or industrial waste water comprising microorganism as the water sample with microorganism. The environmental adaptability of the prepared microorganism film is strong, so that one or more of tap water, well water, atmospheric water, or ground water may serve as medium to maintain the physiological activity with no need of providing a buffer solution system.
G01N 27/30 - Électrodes, p. ex. électrodes pour testsDemi-cellules
G01N 35/00 - Analyse automatique non limitée à des procédés ou à des matériaux spécifiés dans un seul des groupes Manipulation de matériaux à cet effet
97.
METHOD FOR EXTRACTING AND SEPARATING RARE-EARTH ELEMENT
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY , CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Chen, Ji
Guo, Lin
Shen, Lu
Deng, Yuefeng
Lan, Jingbo
Abrégé
A method for extracting and separating a rare-earth element. Cations and anions in a quaternary ammonium ionic liquid extractant, that is, 2-ethylhexyl phosphate mono-2-ethylhexyl acrylate trialkyl-ammonium and phosphate di(2-ethylhexyl) phthalate trialkyl-ammonium, are reacted with rare-earth ions to form neutral complex molecules, also, a collaborative effect and a competitive effect are present between the cations and the anions in the quaternary ammonium ionic liquid extractant in a rare-earth element extraction process, the separation factor for the rare-earth element is thus increased. The method for extracting and separating the rare-earth element provides great interfacial phenomena in the extraction process, generates no emulsification, obviates the need for extractant saponification, and provides increased separation factor for rare-earth elements, and particularly increased separation factor for heavy rare-earth elements. In addition, the rare-earth element extraction and separation method is of reduced extraction acidity, of reduced stripping acidity, and of reduced acid consumption.
C22B 59/00 - Obtention des métaux des terres rares
C22B 3/38 - Traitement ou purification de solutions, p. ex. de solutions obtenues par lixiviation par extraction liquide-liquide utilisant des composés organiques contenant du phosphore
98.
2,6-DIHALOBENZONITRILE-4,4'-DIHALOBENZOPHENONE-PHENOLPHTHALEIN TERPOLYMER, PREPARATION METHOD THEREOF AND INSULATING COATING COMPOSITION
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY ,CHINESE ACADEMY OF SCIENCE (Chine)
Inventeur(s)
Zhou, Guangyuan
Wang, Honghua
Su, Xiaolong
Wang, Zhipeng
Abrégé
2,6-dihalobenzonitrile-4,4'-dihalobenzophenone-phenolphthalein terpolymer comprises a first repeat unit shown in formula (I) and a second repeat unit shown in formula (II), the molar ratio of the first repeat unit to the second repeat unit being 0.1:9.9 to 9.9:0.1. A preparation method of the 2,6-dihalobenzonitrile-4,4'-dihalobenzophenone-phenolphthalein terpolymer comprises: reacting 2,6-dihalo benzonitrile and 4,4'-dihalobenzophenone with phenolphthalein in an organic solvent in the presence of an alkali compound and a water-carrying agent to obtain 2,6-dihalobenzonitrile-4,4'-dihalobenzophenone-phenolphthalein terpolymer. The terpolymer has good heat-resisting performance and can be used for preparing high-performance coatings and adhesives. An insulating coating composition comprises the above terpolymer, the intrinsic viscosity thereof being 0.2 dL/g to 1.4 dL/g; a solvent; a flatting agent, and so on.
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Cui, Dongmei
Liu, Xinli
Liu, Bo
Li, Shihui
Liu, Dongtao
Wu, Chunji
Abrégé
Provided is a metallic alkoxy complex as represented by formula (I), wherein X, M, R1, R2, R3, m, n, y and z are as defined in the specification. Also provided is a catalyst composition, comprising the metallic alkoxy complex and a hydroxyl-containing compound; the molar ratio between the metallic alkoxy complex and the hydroxyl-containing compound is 1: 0.1-1000. Also provided is a poly ε-caprolactone or polylactide preparation method. The monomer of ε-caprolactone or lactide reacts in the presence of the metallic alkoxy complex or the catalyst composition to obtain the poly ε-caprolactone or polylactide. Both the metallic alkoxy complex and the catalyst composition thereof can efficiently catalyze the synthesis of the poly ε-caprolactone or polylactide. The molecular weight of the polycaprolactone or polyactide can be controlled by adjusting the molar ratio between the metallic alkoxy complex and the hydroxyl-containing compound within the range of 1-600,000, and the molecular weight distribution range is between 1.03-1.50.
C08G 63/82 - Procédés de préparation caractérisés par le catalyseur utilisé
B01J 21/00 - Catalyseurs contenant les éléments, les oxydes ou les hydroxydes du magnésium, du bore, de l'aluminium, du carbone, du silicium, du titane, du zirconium ou du hafnium
B01J 23/00 - Catalyseurs contenant des métaux, oxydes ou hydroxydes métalliques non prévus dans le groupe
CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Hongjie
Zhang, Ming
Li, Chengyu
Zhao, Kun
Li, Dongming
Zhang, Li
Abrégé
An AC LED white light luminous device belongs to LED manufacturing field. The problem to be solved by the present invention is low-costly solving a problem of LED stroboflash by AC driver and solving a series of problems of heat emission difficulty caused by multi-LED integrated packaging. An LED white light luminous unit includes an LED chip and a light emitting material that can irradiate when it is excited by the LED chip. The emitting lifetime of the light emitting material is 1-100ms. The LED chip only comprises one PN junction. The light emitted by the LED chip is mixed with the light emitted by the light emitting material, and the color of the mixed light is white. The LED white light luminous unit can be driven by AC of which frequency is not more than 100 Hz. In the LED luminous device of prevent invention, it is used that single PN junction chip rather than prior integrated packaged AC multi-LED chip.