A method for treating an environmental medium having organic contaminants is disclosed. A mixture is added to the environmental medium. The environmental medium is heated to activate the mixture and to evaporate the organic contaminants within the environmental medium to generate contaminated vapors. The mixture acts as an additional heat source. The mixture includes a metal powder. The contaminated vapors are extracted via a perforated pipe, thereby removing the organic contaminants in a gaseous form from the environmental medium. The organic contaminants have an initial boiling point in range of 50° C. to 400° C., when immersed in water or in contact with moist soil, measured at a standard atmospheric pressure of 1 atm.
A method for treating an environmental medium is disclosed. A heat source with a heat exchanger is provided aboveground in proximity to the environmental medium to be treated. A mixture is heated to a temperature below a boiling point of the mixture. The mixture consists of a vegetable oil, an emulsifier, and water. The heated mixture and an alkaline compound catalyst are introduced into the contaminated environmental medium. The alkaline compound is potassium hydroxide or sodium hydroxide. The alkaline compound is dissolved in an alcohol in an amount ranging from 0.1 to 5% of the alkaline compound to form an alkyl oxide solution.
C09K 17/50 - Composés organiques mélangés avec des ingrédients actifs inorganiques, p. ex. catalyseurs de polymérisation le composé organique étant d'origine naturelle, p. ex. dérivés de la cellulose
B09C 1/08 - Régénération de sols pollués par des procédés chimiques
3.
Zero-valent metal suspension in non-aqueous phase for water remediation
The present subject matter illustrates a zero-valent metal suspension in non-aqueous phase. The suspension comprises 41 wt. % of a plurality of zero-valent iron particles; 0.1 wt % of a surfactant; 36 wt. % of an oil; and 23 wt. % of a thickening agent.
B09C 1/02 - Extraction au moyen de liquides, p. ex. lavage, lixiviation
B01J 20/02 - Compositions absorbantes ou adsorbantes solides ou compositions facilitant la filtrationAbsorbants ou adsorbants pour la chromatographieProcédés pour leur préparation, régénération ou réactivation contenant une substance inorganique
A method and a system for in-situ remediation of recalcitrant organic and inorganic contaminants in an environmental medium are disclosed. Dissolved gases from water and an oil are removed to form degassed water and a degassed oil. The degassed water and the degassed oil are mixed to form a surfactant-free oil-in water emulsion. The surfactant-free oil-in-water emulsion is injected into the environmental medium, thereby producing anaerobic conditions to cause indigenous anerobic bacteria to biodegrade residual concentrations of the contaminants in the environmental medium.
C09K 17/50 - Composés organiques mélangés avec des ingrédients actifs inorganiques, p. ex. catalyseurs de polymérisation le composé organique étant d'origine naturelle, p. ex. dérivés de la cellulose
C09K 8/86 - Compositions à base d'eau ou de solvants polaires contenant des composés organiques
B01D 69/02 - Membranes semi-perméables destinées aux procédés ou aux appareils de séparation, caractérisées par leur forme, leur structure ou leurs propriétésProcédés spécialement adaptés à leur fabrication caractérisées par leurs propriétés
The present subject matter relates to a composition for in-situ remediation of soil and aquifer comprising of a water miscible oil; a solvent (for dissolving the vegetable oil to form a solution); and a catalyst (selected from enzymes biocatalysts, particularly lipases, alkaline compounds, heat or combinations thereof). The present subject matter provides a process for the preparation of the composition and application of the same for surface remediation. Further, the present subject matter provides an in-situ alcoholysis remediation method to reduce contaminant concentrations in aquifer and soil by enabling the generation of both soluble and slowly fermenting electron donors required for the anaerobic remediation of organohalide compounds contaminating soils and groundwater. The method of remediation includes mixing an engineered water-soluble oil or water miscible oil with a solvent and adding a catalyst to groundwater to promote the formation of fatty acid alkyl esters, carboxylic acid salts and glycerol.
The present subject matter illustrates a method for accelerated in-situ chemical reduction of subsoil matter. The method comprises supplying a mixture comprising ferrous sulfide into soil pathways to biologically react with dissolved contaminates in the groundwater. Further, an organic hydrogen donor is supplied into the soil-pathways to produce anerobic-conditions to cause indigenous anaerobic bacteria to biodegrade residual concentrations of the contaminates.
B09C 1/06 - Régénération de sols pollués par des procédés thermiques
C02F 1/70 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par réduction
B09C 1/08 - Régénération de sols pollués par des procédés chimiques
B01J 20/02 - Compositions absorbantes ou adsorbantes solides ou compositions facilitant la filtrationAbsorbants ou adsorbants pour la chromatographieProcédés pour leur préparation, régénération ou réactivation contenant une substance inorganique
B01F 17/00 - Utilisation de substances comme agents émulsifiants, humidifiants, dispersants ou générateurs de mousse
C02F 103/06 - Eau souterraine contaminée ou eau de lessivage
7.
Zero-valent metal suspension in non-aqueous phase for water remediation
The present subject matter illustrates a zero-valent metal suspension in non-aqueous phase. The suspension comprises 41 wt. % of a plurality of zero-valent iron particles; 0.1 wt % of a surfactant; 36 wt. % of an oil; and 23 wt. % of a thickening agent.
B09C 1/02 - Extraction au moyen de liquides, p. ex. lavage, lixiviation
C02F 1/44 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par dialyse, osmose ou osmose inverse
C02F 1/70 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par réduction
B01J 20/02 - Compositions absorbantes ou adsorbantes solides ou compositions facilitant la filtrationAbsorbants ou adsorbants pour la chromatographieProcédés pour leur préparation, régénération ou réactivation contenant une substance inorganique
A formulation for the bioremediation of soil or groundwater includes from about 80 to 95% of an emulsifiable C4-C22 vegetable oil selected from the group consisting of soybean oil, coconut oil, rapeseed (canola) oil, peanut oil, crambe oil, sunflower oil and combinations thereof; and from about 5 to 20% of an emulsifier selected from the group consisting of a vegetable oil derived from a C16-C20 fatty acid ester or a mixture of such esters. The efficacy of the formulation is improved by adding hydrogen-enriched water to the emulsifiable oil as a dilution fluid.
C02F 5/10 - Traitement de l'eau avec des produits chimiques complexants ou des agents solubilisants pour l'adoucissement, la prévention ou l'élimination de l'entartrage, p. ex. par addition d'agents séquestrants en utilisant des substances organiques
