A polyethylene film with enhanced physical and mechanical properties, along with a method for its production, is presented. Notably, the film exhibits a 2% secant modulus exceeding 20,000 psi, dart impact resistance greater than 500 g/mil, and machine direction (MD) tear strength above 500 g/mil. The production method involves reacting ethylene with a comonomer in the presence of a Ziegler-Natta (titanium) base prepolymer at temperatures ranging from 75°C to 95°C. The process operates under an ethylene partial pressure between 90 psia and 125 psia, with a comonomer-to-ethylene ratio of 0.08 to 0.15, enabling the formation of an ethylene-based polymer without the need for additional cocatalysts or antistatic agents in the gas phase polymerization process.
17 - Produits en caoutchouc ou en matières plastiques; matières à calfeutrer et à isoler
Produits et services
Semi-processed resins
3.
OLEFIN POLYMERIZATION CATALYST COMPONENTS CONTAINING DIGLYCIDYLESTER COMPONENTS AND ITS USE FOR THE PRODUCTION OF POLYPROPYLENE HAVING HIGH ISOTACTICITY AT HIGH MELT FLOW RATE
The present invention relates to a phthalate free Ziegler-Natta catalyst component for olefin polymerization, prepared in the presence of a diglycidylester compound in combination with one or more internal electron donors. The catalyst components, according to present invention, produce polypropylene polymers having higher stereo-regularity with high melt flow rate than polymers produced with catalyst components not including a diglycidylester compound.
C08F 4/652 - Prétraitement avec des métaux ou des composés métalliques
C08F 4/651 - Prétraitement avec des non-métaux ou des composés exempts d'atomes métalliques
4.
OLEFIN POLYMERIZATION CATALYST COMPONENTS CONTAINING SILANE AND PROCESS FOR THE PRODUCTION OF POLYPROPYLENE HAVING HIGH ISOTACTICITY AT HIGH MELT FLOW RATE
The present invention relates to a solid Ziegler-Natta catalyst component for use in olefin polymerization. The catalyst component comprises magnesium, titanium, halide, one or more dicylopentyldialkoxysilane compounds, one or more dialkylaminotrialkoxysilane compounds, and one or more internal electron donors comprising urea, phthalate and 1,3-diether. The catalyst components, according to present invention, are able to produce polypropylene polymers having high isotacticity with high melt flow rate.
The present invention provides a process for producing a solid catalyst component without using internal electron donors, prepared by reacting an alkoxymagnesium compound with an acyl halide and/or sulfinyl halide and/or sulfonyl halide compound, and an alkanol and/or an alkanediol to form reaction product (A), optionally reacting the reaction product (A) with an organohalide and oranophosphorus compound to form reaction product (B), reacting the reaction product (B) with a halogen-containing titanium or vanadium compound to obtain the solid catalyst component (C). The solid catalyst component can be used in a olefin polymerization catalyst system to produce polypropylene polymers with high activity, high stereo-regularity, and good morphology.
The present invention provides a process for producing a solid catalyst component without using internal electron donors, prepared by reacting an alkoxymagnesium compound with an acyl halide and/or sulfinyl halide and/or sulfonyl halide compound, and an alkanol and/or an alkanediol to form reaction product (A), optionally reacting the reaction product (A) with an organohalide and oranophosphorus compound to form reaction product (B), reacting the reaction product (B) with a halogen-containing titanium or vanadium compound to obtain the solid catalyst component (C). The solid catalyst component can be used in a olefin polymerization catalyst system to produce polypropylene polymers with high activity, high stereo-regularity, and good morphology.
C08F 4/76 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux non prévus dans le groupe choisis parmi les métaux réfractaires choisis parmi le titane, le zirconium, le hafnium, le vanadium, le niobium ou le tantale
OLEFIN POLYMERIZATION CATALYST COMPONENTS CONTAINING SILANE AND PROCESS FOR THE PRODUCTION OF POLYPROPYLENE HAVING HIGH ISOTACTICITY AT HIGH MELT FLOW RATE
The present invention relates to a solid Ziegler-Natta catalyst component for use in olefin polymerization. The catalyst component comprises magnesium, titanium, halide, one or more dicylopentyldialkoxysilane compounds, one or more dialkylaminotrialkoxysilane compounds, and one or more internal electron donors comprising urea, phthalate and 1,3-diether. The catalyst components, according to present invention, are able to produce polypropylene polymers having high isotacticity with high melt flow rate.
A multilayer blown film, designed for use in heavy duty sacks manufactured by a high-speed Form-Fill-Seal packaging process, having unique heat sealing characteristics and desirable mechanical properties is disclosed. Additionally, a multilayer blown film consists of skin layers prepared from a Ziegler-Natta catalyzed ethylene and alpha-olefin copolymer with novel composition distribution, and at least one core layer that includes both HPDE and LLDPE. The multilayer blown film, with no external sealing additives present in skin layers, exhibits outstanding processability, superior tear resistance, as well as balanced stiffness and toughness.
B32B 27/32 - Produits stratifiés composés essentiellement de résine synthétique comprenant des polyoléfines
B32B 27/08 - Produits stratifiés composés essentiellement de résine synthétique comme seul composant ou composant principal d'une couche adjacente à une autre couche d'une substance spécifique d'une résine synthétique d'une sorte différente
9.
METHOD FOR PREPARING A ZIEGLER-NATTA CATALYST SYSTEM WITH IMPROVED PERFORMANCE IN PROPYLENE POLYMERIZATION
A method for preparing a Ziegler-Natta catalyst system, especially a phthalate-free catalyst system, with improved performance in propylene polymerization is provided. It is found that catalyst performance, especially catalyst activity and hydrogen response, is significantly improved when a propylene-based pre-polymer is prepared in the presence of a vinyldisilane compound and then used in propylene polymerization.
This present invention relates to a method for using halogenation agents to react with magnesium precursor or with magnesium complexes to form catalyst components without using internal electron donors. The catalyst components are used to produce polypropylene with good productivity and high stereospecificity. This method offers a wide range of catalyst component preparations and selections to enhance the catalyst component applications regarding activity, stereospecificity, hydrogen response, molecular weight, and distributions.
This present invention relates to a method for using halogenation agents to react with magnesium precursor or with magnesium complexes to form catalyst components without using internal electron donors. The catalyst components are used to produce polypropylene with good productivity and high stereospecificity. This method offers a wide range of catalyst component preparations and selections to enhance the catalyst component applications regarding activity, stereospecificity, hydrogen response, molecular weight, and distributions.
The present invention relates to a phthalate free propylene-ethylene copolymer having high ethylene content characterized by low hexane extractable and xylene soluble properties, while showing excellent mechanical properties. The preparation of the copolymer is carried out in the presence of a phthalate free catalyst system comprising (a) phthalate free catalyst component obtained by contacting a magnesium halide, a titanium compound having at least a Ti-halogen bond and one or more electron donor compounds comprising urea, a carbonate ether, and a 1,3-diether; (b) an alkyl aluminum compound; and (c) an external electron donor compound.
A preparation method to produce a Ziegler-Natta catalyst for olefin polymerization through treatment of MgCl2.xROH adduct with a transition metal halide in the presence of one or more urea compounds in combination with one or more internal electron donors is provided. The catalyst systems, according to present invention, are able to produce polypropylene polymers with higher stereo-regularity. The catalyst systems, according to present invention, are able to produce polypropylene polymers using a phthalate-free catalyst system, with an isotacticity that is equal to or higher than catalyst systems containing phthalate derivatives.
C08F 4/76 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux non prévus dans le groupe choisis parmi les métaux réfractaires choisis parmi le titane, le zirconium, le hafnium, le vanadium, le niobium ou le tantale
14.
CATALYSTS COMPONENT AND PROCESS FOR THE PRODUCTION OF POLYPROPYLENE HAVING HIGH MELT FLOW RATE WITH HIGH ISOTACTICITY
The present invention relates to a Ziegler-Natta catalyst composition for olefin polymerization, which comprises alkyltrialkoxysilane, urea, phthalate and 1,3-diether element as internal electron donors. The catalyst components, according to the present invention, are able to produce polypropylene polymers having high melt flow rate with high isotacticity.
C08F 4/76 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux non prévus dans le groupe choisis parmi les métaux réfractaires choisis parmi le titane, le zirconium, le hafnium, le vanadium, le niobium ou le tantale
22•xROH adduct with a transition metal halide in the presence of one or more urea compounds in combination with one or more internal electron donors is provided. The catalyst systems, according to present invention, are able to produce polypropylene polymers with higher stereo-regularity. The catalyst systems, according to present invention, are able to produce polypropylene polymers using a phthalate-free catalyst system, with an isotacticity that is equal to or higher than catalyst systems containing phthalate derivatives.
The present invention relates to a Ziegler-Natta catalyst composition for olefin polymerization, which comprises alkyltrialkoxysilane, urea, phthalate and 1,3-diether element as internal electron donors. The catalyst components, according to the present invention, are able to produce polypropylene polymers having high melt flow rate with high isotacticity.
The present invention relates to a solid Ziegler-Natta catalyst component for olefin polymerization containing an organosilicon element in combination with one or more internal electron donors. The catalyst components, according to the present invention, are able to produce polypropylene polymers with higher stereo-regularity. The present invention also provides a phthalate-free catalyst system capable of producing polypropylene with an isotacticity that is equal to or higher than catalyst systems containing phthalate derivatives.
The present invention provides phthalate free impact resistant polypropylene copolymer and methods of preparation, which are produced directly from the polymerization reactor system without further compounding of components which significantly alters the physical properties of the resulting polymer. The copolymer according to the present invention possesses both low temperature ductility and high flexural modulus, wherein said polymer is produced in the presence of a phthalate free ZN catalyst comprising urea component.
C08L 23/16 - Copolymères de l’éthylène et du propylène ou de l’éthylène, du propylène et de diène
B01J 31/02 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des composés organiques ou des hydrures métalliques
C08F 2/24 - Polymérisation en émulsion utilisant des agents émulsifiants
19.
HIGH DUCTILITY, HIGH MODULUS AND PHTHALATE FREE IMPACT RESISTANT PROPYLENE COPOLYMER
The present invention provides phthalate free impact resistant polypropylene copolymer and methods of preparation, which are produced directly from the polymerization reactor system without further compounding of components which significantly alters the physical properties of the resulting polymer. The copolymer according to the present invention possesses both low temperature ductility and high flexural modulus, wherein said polymer is produced in the presence of a phthalate free ZN catalyst comprising urea component.
Disclosed are support-activators and catalyst compositions comprising the support-activators for polymerizing olefins in which the support-activator includes clay heteroadduct, prepare from a colloidal phyllosilicate such as a colloidal smectite clay, which is chemically-modified with a heterocoagulation agent. By limiting the amount of heterocoagulation reagent relative to the colloidal smectite clay as described herein, the smectite heteroadduct support-activator is a porous and amorphous solid which can be readily isolated from the resulting slurry by a conventional filtration process, and which can activate metallocenes and related catalysts toward olefin polymerization. Related compositions and processes are disclosed.
C08F 4/659 - Composant couvert par le groupe contenant une liaison métal de transition-carbone
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
Disclosed is a Ziegler-Natta catalyst composition comprising one or more Ziegler-Natta procatalyst compositions which comprise magnesium, titanium, a halogen, one or more internal electron donors; one or more aluminum containing cocatalysts; optionally one or more stereo- selectivity control agents (SC A); and one or more activity limiting agents (ALA) comprising one or more alkyl-, cycloalkyl- or aryl carbonates and derivatives. Such a Ziegler-Natta catalyst composition exhibits self-limiting catalyst activity in olefin polymerization, particularly propylene polymerization.
C08F 110/04 - Monomères contenant trois ou quatre atomes de carbone
B01J 31/02 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des composés organiques ou des hydrures métalliques
B01J 31/16 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des complexes de coordination
C08F 210/00 - Copolymères d'hydrocarbures aliphatiques non saturés contenant une seule liaison double carbone-carbone
B01J 31/00 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques
22.
Carbonate Compounds as Activity Limiting Agents in Ziegler-Natta Catalyst Compositions for Olefin Polymerization
Disclosed is a Ziegler-Natta catalyst composition comprising one or more Ziegler-Natta procatalyst compositions which comprise magnesium, titanium, a halogen, one or more internal electron donors; one or more aluminum containing cocatalysts; optionally one or more stereo-selectivity control agents (SCA); and one or more activity limiting agents (ALA) comprising one or more alkyl-, cycloalkyl- or aryl carbonates and derivatives. Such a Ziegler-Natta catalyst composition exhibits self-limiting catalyst activity in olefin polymerization, particularly propylene polymerization.
Disclosed are support-activators and catalyst compositions comprising the support-activators for polymerizing olefins in which the support-activator includes a clay heteroadduct, also termed a composite, prepared from a colloidal phyllosilicate such as a colloidal smectite clay, which is chemically-modified with a surfactant. In an aspect, the clay composite can comprise the contact product of a colloidal smectite clay and a surfactant in a liquid carrier, but in the absence of any other reactant such as a cationic polymetallate, and their use as support-activators for metallocene precatalysts is also described. The use of surfactants with cationic polymetallates in forming clay-composites is also described.
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
ABSTRACT Disclosed are support-activators and catalyst compositions comprising the support-activators for polymerizing olefins in which the support-activator includes a clay heteroadduct, also termed a composite, prepared from a colloidal phyllosilicate such as a colloidal smectite clay, which is chemically-modified with a surfactant. In an aspect, the clay composite can comprise the contact product of a colloidal smectite clay and a surfactant in a liquid carrier, but in the absence of any other reactant such as a cationic polymetallate, and their use as support-activators for metallocene precatalysts is also described. The use of surfactants with cationic polymetallates in forming clay-composites is also described.
Disclosed are support-activators and catalyst compositions comprising the support-activators for polymerizing olefins in which the support-activator includes clay heteroadduct, prepare from a colloidal phyllosilicate such as a colloidal smectite clay, which is chemically-modified with a heterocoagulation agent. By limiting the amount of heterocoagulation reagent relative to the colloidal smectite clay as described herein, the smectite heteroadduct support-activator is a porous and amorphous solid which can be readily isolated from the resulting slurry by a conventional filtration process, and which can activate metallocenes and related catalysts toward olefin polymerization. Related compositions and processes are disclosed.
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
C08F 210/16 - Copolymères de l'éthylène avec des alpha-alcènes, p. ex. caoutchoucs EP
C08F 4/659 - Composant couvert par le groupe contenant une liaison métal de transition-carbone
C08F 2/01 - Procédés de polymérisation caractérisés par des éléments particuliers des appareils de polymérisation utilisés
The present invention relates to a solid catalyst component comprising magnesium, titanium, halide, and internal electron donor compounds comprising dilakylurea, malonate, succinate, and 1,3-diether, wherein the succinate amount is less than about 30% by mol with respect to the total amount of electron donor, the molar ratio between succinate and 1,3-diether is in the range of about 0.1 - 0.5, and the molar ratio between malonate and 1,3-diether is in the range of about 0.5 - 2.5. The catalyst component according to present invention provides highly isotactic polypropylene polymer with broad molecular weight distribution.
C08F 4/42 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
27.
Catalyst components for the preparation of highly isotactactic polypropylene polymer with broad molecular weight distribution
The present invention relates to a solid catalyst component comprising magnesium, titanium, halide, and internal electron donor compounds comprising dilakylurea, malonate, succinate, and 1,3-diether, wherein the succinate amount is less than about 30% by mol with respect to the total amount of electron donor, the molar ratio between succinate and 1,3-diether is in the range of about 0.1-0.5, and the molar ratio between malonate and 1,3-diether is in the range of about 0.5-2.5. The catalyst component according to present invention provides highly isotactic polypropylene polymer with broad molecular weight distribution.
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
Cyclic organosilicon compounds having a structure represented by the general formula
Cyclic organosilicon compounds having a structure represented by the general formula
Cyclic organosilicon compounds having a structure represented by the general formula
and a method for using thereof as a component of catalysts for producing propylene polymer having a very high melt-flowability are disclosed. The cyclic organosilicon compounds are employed as external electron donors in Ziegler-Natta catalyst systems to dramatically improve the hydrogen response, and therefore the catalyst systems can be used to prepare polymer having high melt-flowability and high isotacticity at high yield.
C08F 10/00 - Homopolymères ou copolymères d'hydrocarbures aliphatiques non saturés contenant une seule liaison double carbone-carbone
B01J 31/02 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des composés organiques ou des hydrures métalliques
29.
Olefin polymerization Ziegler-Natta catalyst components and process for the production of olefin polymers therewith
The present invention relates to a solid Ziegler-Natta catalyst component for olefin polymerization containing an organosilicon element in combination with one or more internal electron donors. The catalyst components, according to the present invention, are able to produce polypropylene polymers with higher stereo-regularity. The present invention also provides a phthalate-free catalyst system capable of producing polypropylene with an isotacticity that is equal to or higher than catalyst systems containing phthalate derivatives.
Disclosed are support-activators and catalyst compositions comprising the support-activators for polymerizing olefins in which the support-activator includes clay heteroadduct, prepare from a colloidal phyllosilicate such as a colloidal smectite clay, which is chemically-modified with a heterocoagulation agent. By limiting the amount of heterocoagulation reagent relative to the colloidal smectite clay as described herein, the smectite heteroadduct support-activator is a porous and amorphous solid which can be readily isolated from the resulting slurry by a conventional filtration process, and which can activate metallocenes and related catalysts toward olefin polymerization. Related compositions and processes are disclosed.
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
What is disclosed is a Ziegler-Natta catalyzed ethylene and alpha-olefin LLDPE copolymer having a unique composition distribution and long chain-branching. The polymers of the present invention inherently exhibit outstanding melt strength with great bubble stability, sufficient flexibility, excellent gel performance, as well as desirable mechanical properties such as balanced toughness and stiffness, which are desirable properties for thick gauge film applications. Specifically, the polymers of the present invention.
C08J 9/00 - Mise en œuvre de substances macromoléculaires pour produire des matériaux ou objets poreux ou alvéolairesLeur post-traitement
C08J 9/14 - Mise en œuvre de substances macromoléculaires pour produire des matériaux ou objets poreux ou alvéolairesLeur post-traitement utilisant des gaz de gonflage produits par un agent de gonflage introduit au préalable par un agent physique de gonflage organique
Disclosed are support-activators and catalyst compositions comprising the support-activators for polymerizing olefins in which the support-activator includes clay heteroadduct, prepare from a colloidal phyllosilicate such as a colloidal smectite clay, which is chemically-modified with a heterocoagulation agent. By limiting the amount of heterocoagulation reagent relative to the colloidal smectite clay as described herein, the smectite heteroadduct support-activator is a porous and amorphous solid which can be readily isolated from the resulting slurry by a conventional filtration process, and which can activate metallocenes and related catalysts toward olefin polymerization. Related compositions and processes are disclosed.
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
B01J 29/04 - Catalyseurs contenant des tamis moléculaires ayant des propriétés d'échangeurs de base, p. ex. zéolites cristallines, argiles pontées
33.
Process for preparing catalysts and catalyst compositions
Disclosed are support-activators and catalyst compositions comprising the support-activators for polymerizing olefins in which the support-activator includes clay heteroadduct, prepare from a colloidal phyllosilicate such as a colloidal smectite clay, which is chemically-modified with a heterocoagulation agent. By limiting the amount of heterocoagulation reagent relative to the colloidal smectite clay as described herein, the smectite heteroadduct support-activator is a porous and amorphous solid which can be readily isolated from the resulting slurry by a conventional filtration process, and which can activate metallocenes and related catalysts toward olefin polymerization. Related compositions and processes are disclosed.
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
A multilayer blown film, designed for use in heavy duty sacks manufactured by a high-speed Form-Fill-Seal packaging process, having unique heat sealing characteristics and desirable mechanical properties is disclosed. Additionally, a multilayer blown film consists of skin layers prepared from a Ziegler-Natta catalyzed ethylene and alpha-olefin copolymer with novel composition distribution, and at least one core layer that includes both HPDE and LLDPE. The multilayer blown film, with no external sealing additives present in skin layers, exhibits outstanding processability, superior tear resistance, as well as balanced stiffness and toughness.
B32B 27/08 - Produits stratifiés composés essentiellement de résine synthétique comme seul composant ou composant principal d'une couche adjacente à une autre couche d'une substance spécifique d'une résine synthétique d'une sorte différente
B32B 27/32 - Produits stratifiés composés essentiellement de résine synthétique comprenant des polyoléfines
B65B 9/00 - Enserrage d'objets les uns à la suite des autres ou de quantités de matériaux, p. ex. liquides ou semi-liquides, dans des bandes plates, pliées ou tubulaires faites de feuilles en matière soupleDivision des tubes flexibles remplis pour former des paquets
35.
Cyclic organosilicon compounds as electron donors in Zeigler-Natta catalyst systems for producing propylene polymer having high melt-flowability
Cyclic organosilicon compounds having a structure represented by the general formula
and a method for using thereof as a component of catalysts for producing propylene polymer having a very high melt-flowability are disclosed. The cyclic organosilicon compounds are employed as external electron donors in Ziegler-Natta catalyst systems to dramatically improve the hydrogen response, and therefore the catalyst systems can be used to prepare polymer having high melt-flowability and high isotacticity at high yield.
B01J 31/00 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques
B01J 31/02 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des composés organiques ou des hydrures métalliques
C08F 10/00 - Homopolymères ou copolymères d'hydrocarbures aliphatiques non saturés contenant une seule liaison double carbone-carbone
C08F 4/58 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides en mélange avec du silicium, du germanium, de l'étain, du plomb, de l'antimoine, du bismuth ou leurs composés
36.
Process for preparing high melt strength polypropylene
The present invention relates to a polypropylene composition comprising a long chain branched polymer having high melt strength. The process for preparing the corresponding polypropylene having composition is provided comprising blending a propylene base polymer with a unsaturated polyfunctional poly(alkylsiloxane), a polyfunctional acrylate coagent, an initiator, additives such as stabilizer, acid neutralizer and antioxidants, and reactive extruding the blend to form a branched polymer composition bridged by siloxane units.
C08F 255/02 - Composés macromoléculaires obtenus par polymérisation de monomères sur des polymères d'hydrocarbures tels que définis dans le groupe sur des polymères d'oléfines contenant deux ou trois atomes de carbone
The present invention relates to a process for the (co)polymerization of olefins to make polyethylene (co)polymers having sporadic long chain branches in high molecular weight fractions and a high molecular weight tail along with reversed comonomer composition distribution for improving processability, melt strength and optical properties. Such polyethylene (co)polymers have been prepared with a process comprising the reaction of at least the following components: (a) an advanced Ziegler-Natta catalyst precursor comprising titanium; (b) an activator comprising organohalogenous aluminum compounds; (c) ethylene; and (d) one or more alpha-olefins.
Disclosed are a catalyst component for olefin polymerization comprising titanium, magnesium, a halogen, internal donors, in combination with a silane and oxalic acid diamides of the following formula:
An olefin polymerization catalyst system consisting of the solid catalyst component, an organoaluminum compound, and an optional external electron donor compound is also disclosed. Employment of both oxalic acid diamides and silane component in the presence of internal electron donors as an elements of solid Ziegler-Natta type catalyst composition enhances stereo-specificity while maintaining excellent catalyst activity and hydrogen response, in which the modified catalyst composition produces polypropylene with good productivity and higher stereo-specificity than catalyst composition without such modification.
C08F 4/44 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides
C08F 4/42 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs
C08F 4/654 - Prétraitement avec des métaux ou des composés métalliques avec le magnésium ou ses composés
C08F 4/655 - Prétraitement avec des métaux ou des composés métalliques avec l'aluminium ou ses composés
The present invention relates to a Ziegler-Natta catalyst component for olefin polymerization containing an amide element in combination with one or more internal electron donors. The catalyst components, according to the present invention, are able to produce polypropylene polymers with higher stereo-regularity. The present invention also provides a phthalate-free catalyst system capable of producing polypropylene with an isotacticity that is equal to or higher than catalyst systems containing phthalate derivatives.
Heterocyclic organic compounds are used as electron donors in conjunction with solid Ziegler-Natta type catalyst in processes in which polyolefins such as polypropylene are produced. The electron donors may be used in the preparation of solid catalyst system, thus serving as “internal electron donors,” or they may be employed during or prior to polymerization with the co-catalyst as “external electron donors.”
C08F 4/52 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides choisis parmi le bore, l'aluminium, le gallium, l'indium, le thallium ou les terres rares
C08F 4/10 - Composés métalliques autres que les hydrures et autres que les composés organiques de métalComplexes d'halogénures de bore ou d'halogénures d'aluminium avec des composés organiques contenant de l'oxygène de métaux alcalino-terreux, de zinc, de cadmium, de mercure, de cuivre ou d'argent
C08F 4/16 - Composés métalliques autres que les hydrures et autres que les composés organiques de métalComplexes d'halogénures de bore ou d'halogénures d'aluminium avec des composés organiques contenant de l'oxygène de silicium, de germanium, d'étain, de plomb, de titane, de zirconium ou de hafnium
C08F 4/654 - Prétraitement avec des métaux ou des composés métalliques avec le magnésium ou ses composés
41.
Catalyst component for high activity and high stereoselectivity in olefin polymerization
What is disclosed is a method for preparing a catalyst system and a catalyst system for polymerizing or copolymerizing an α-olefin. Catalyst component (A) is obtained by a process of reacting a magnesium complex (A-1) containing acid salts of group IB-VIIIB elements formed by contacting a magnesium halide with an acid salt solution of group IB-VIIIB metals or spherical particles adducts, an internal electron donor (A-2) of diester or diether or composite compounds, and a titanium compound (A-3). The catalyst compound (A) is contacted with a silicon compound (B) and an organoaluminium compound (C) to complete the catalyst system providing a good balance of catalyst performance in terms of activity and stereo-specificity.
Organosilicon compounds having a structure represented by the general formula
and a method for using same are provided as electron donors in the Ziegler-Natta type catalyst system for the homo-polymerization or co-polymerization of alpha olefins. The organosilicon compounds may be used in the preparation of the solid catalyst component, thus serving as “internal electron donors”, or employed during or prior to polymerization as “external electron donors,” and therefore they can be used to prepare phthalate-free polyolefins.
The present invention relates to a Ziegler-Natta catalyst component for olefin polymerization containing a urea element in combination with one or more internal electron donors. The catalyst components are able to produce polypropylene polymers with higher stereo-regularity. The present invention also provides phthalate-free catalyst system capable of producing polypropylene with an isotacticity that is equal to or higher than catalyst systems containing phthalate derivatives.
A phthalate-free catalyst component for olefin polymerization comprising titanium, magnesium, a halogen, diether, and oxalic acid diamides represented by the following formula (I):
and an olefin polymerization catalyst system consisting of the solid catalyst component, an organoaluminum compound, and an optional external electron donor compound. The present catalyst compositions improve diether-based catalyst selectivity while maintaining excellent catalyst activity and hydrogen response. An olefin polymer that has a moderate molecular weight distribution while maintaining higher stereoregularity (isotacticity) over diether-based catalyst, and better than or equal to phthalate-based catalyst can be produced by utilizing the inventive catalyst component.
C08F 4/52 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides choisis parmi le bore, l'aluminium, le gallium, l'indium, le thallium ou les terres rares
C08F 4/64 - Titane, zirconium, hafnium ou leurs composés
B01J 31/02 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des composés organiques ou des hydrures métalliques
C08F 4/609 - Catalyseurs comprenant un non-métal spécifique ou un composé spécifique exempt d'atomes métalliques organique
B01J 31/38 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant en outre des composés métalliques inorganiques non prévus dans les groupes du titane, du zirconium ou du hafnium
45.
OXALIC ACID DIAMIDES AS MODIFIERS FOR POLYOLEFIN CATALYSTS
The present invention relates to the use of oxalic acid diamides as modifiers in conjunction with solid Ziegler-Natta type catalyst in processes in which polyolefins such as polypropylene are produced. The modified catalyst compositions produce polypropylene with good productivity and higher sterospecificity than systems without such modification.
The present invention relates to the use of oxalic acid diamides as modifiers in conjunction with solid Ziegler-Natta type catalyst in processes in which polyolefins such as polypropylene are produced. The modified catalyst compositions produce polypropylene with good productivity and higher sterospecificity than systems without such modification.
A cast film, for use in monolayer and multilayer applications, having an outstanding inherent cling property is disclosed. Additionally, a multilayer cast film utilizing a cast film component layer prepared from a Ziegler-Natta catalyzed ethylene and alpha-olefin copolymer is disclosed, wherein the cast film component layer has a cling force of at least 200 grams-force per inch width at 200% pre-stretch, a slow puncture resistance of greater than 50 J/mm, and a TD tear strength of greater than 450g/mil, with no cling additives present in the cast film component layer.
B32B 9/04 - Produits stratifiés composés essentiellement d'une substance particulière non couverte par les groupes comprenant une telle substance comme seul composant ou composant principal d'une couche adjacente à une autre couche d'une substance spécifique
48.
Cast film component layer exhibiting an outstanding cling property
A cast film, for use in monolayer and multilayer applications, having an outstanding inherent cling property is disclosed. Additionally, a multilayer cast film utilizing a cast film component layer prepared from a Ziegler-Natta catalyzed ethylene and alpha-olefin copolymer is disclosed, wherein the cast film component layer has a cling force of at least 200 grams-force per inch width at 200% pre-stretch, a slow puncture resistance of greater than 50 J/mm, and a TD tear strength of greater than 450 g/mil, with no cling additives present in the cast film component layer.
B32B 27/32 - Produits stratifiés composés essentiellement de résine synthétique comprenant des polyoléfines
B32B 27/08 - Produits stratifiés composés essentiellement de résine synthétique comme seul composant ou composant principal d'une couche adjacente à une autre couche d'une substance spécifique d'une résine synthétique d'une sorte différente
B32B 27/18 - Produits stratifiés composés essentiellement de résine synthétique caractérisée par l'emploi d'additifs particuliers
49.
Ethylene copolymers with a novel composition distribution and processes for making the same
A Ziegler-Natta catalyzed ethylene copolymer having a novel composition distribution in which comonomers are incorporated into the high molecular weight polymer molecules and distributed evenly among the entire polyethylene chains, and a method for making the same are provided. The resins having a novel composition distribution have controlled molecular weight distribution which is narrower than conventional ZN-ethylene copolymers but broader than single-site catalyzed ethylene copolymers. The resins having a novel composition distribution exhibit a superior tear strength and impact strength.
Non-phthalate compounds having a structure represented by the general formula (I) and a method for using same are provided as electron donors in the Ziegler-Natta type catalyst system for the homopolymerization or copolymerization of alpha olefins. The non-phthalate compounds may be used in the preparation of the solid catalyst component, thus serving as "internal electron donors", or employed during or prior to polymerization as "external electron donors", and therefore they can be used to prepare phthalate-free polyolefins.
Non-phthalate compounds having a structure represented by the general formula
and a method for using same are provided as electron donors in the Ziegler-Natta type catalyst system for the homopolymerization or copolymerization of alpha olefins. The non-phthalate compounds may be used in the preparation of the solid catalyst component, thus serving as “internal electron donors”, or employed during or prior to polymerization as “external electron donors,” and therefore they can be used to prepare phthalate-free polyolefins.
C08F 4/52 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides choisis parmi le bore, l'aluminium, le gallium, l'indium, le thallium ou les terres rares
C08F 4/654 - Prétraitement avec des métaux ou des composés métalliques avec le magnésium ou ses composés
52.
Heterocyclic organic compounds as electron donors for polyolefin catalysts
Heterocyclic organic compounds are used as electron donors in conjunction with solid Ziegler-Natta type catalyst in processes in which polyolefins such as polypropylene are produced. The electron donors may be used in the preparation of solid catalyst system, thus serving as “internal electron donors”, or they may be employed during or prior to polymerization with the co-catalyst as “external electron donors”.
C08F 4/52 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides choisis parmi le bore, l'aluminium, le gallium, l'indium, le thallium ou les terres rares
C08F 4/10 - Composés métalliques autres que les hydrures et autres que les composés organiques de métalComplexes d'halogénures de bore ou d'halogénures d'aluminium avec des composés organiques contenant de l'oxygène de métaux alcalino-terreux, de zinc, de cadmium, de mercure, de cuivre ou d'argent
C08F 4/16 - Composés métalliques autres que les hydrures et autres que les composés organiques de métalComplexes d'halogénures de bore ou d'halogénures d'aluminium avec des composés organiques contenant de l'oxygène de silicium, de germanium, d'étain, de plomb, de titane, de zirconium ou de hafnium
53.
HETEROCYCLIC ORGANIC COMPOUNDS AS ELECTRON DONORS FOR POLYOLEFIN CATALYSTS
Heterocyclic organic compounds are used as electron donors in conjunction with solid Ziegler- Natta type catalyst in processes in which polyolefins such as polypropylene are produced. The electron donors may be used in the preparation of solid catalyst system, thus serving as "internal electron donors", or they may be employed during or prior to polymerization with the co-catalyst as "external electron donors".
Heterocyclic organic compounds are used as electron donors in conjunction with solid Ziegler-Natta type catalyst in processes in which polyolefins such as polypropylene are produced. The electron donors may be used in the preparation of solid catalyst system, thus serving as “internal electron donors”, or they may be employed during or prior to polymerization with the co-catalyst as “external electron donors”.
C08F 4/44 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides
55.
Ethylene copolymers with a novel composition distribution and processes for making the same
A Ziegler-Natta catalyzed ethylene copolymer having a novel composition distribution in which comonomers are incorporated into the high molecular weight polymer molecules and distributed evenly among the entire polyethylene chains, and a method for making the same are provided. The resins having a novel composition distribution have controlled molecular weight distribution which is narrower than conventional ZN-ethylene copolymers but broader than single-site catalyzed ethylene copolymers. The resins having a novel composition distribution exhibit a superior tear strength and impact strength.
A Ziegler-Natta catalyzed ethylene copolymer having a novel composition distribution in which comonomers are incorporated into the high molecular weight polymer molecules and distributed evenly among the entire polyethylene chains, and a method for making the same are provided. The resins having a novel composition distribution have controlled molecular weight distribution which is narrower than conventional ZN-ethylene copolymers but broader than single-site catalyzed ethylene copolymers. The resins having a novel composition distribution exhibit a superior tear strength and impact strength.
What is disclosed is a method for preparing a catalyst system and a catalyst system for polymerizing or copolymerizing an α-olefin. Catalyst component (A) is obtained by a process of reacting a magnesium complex (A-1) containing acid salts of group IB-VIIIB elements formed by contacting a magnesium halide with an acid salt solution of group IB-VIIIB metals or spherical particles adducts, an internal electron donor (A-2) of diester or diether or composite compounds, and a titanium compound (A-3). The catalyst compound (A) is contacted with a silicon compound (B) and an organoaluminium compound (C) to complete the catalyst system providing a good balance of catalyst performance in terms of activity and stereo-specificity.
Cyclic organosilicon compounds having a structure represented by the general formula
and a method for using thereof as a component of catalysts for producing propylene polymer having a very high melt-flowability are disclosed. The cyclic organosilicon compounds are employed as external electron donors in Ziegler-Natta catalyst systems to dramatically improve the hydrogen response, and therefore the catalyst systems can be used to prepare polymer having high melt-flowability and high isotacticity at high yield.
C08F 4/44 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides
C08F 10/00 - Homopolymères ou copolymères d'hydrocarbures aliphatiques non saturés contenant une seule liaison double carbone-carbone
C08F 4/58 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides en mélange avec du silicium, du germanium, de l'étain, du plomb, de l'antimoine, du bismuth ou leurs composés
59.
CYCLIC ORGANOSILICON COMPOUNDS AS ELECTRON DONORS IN ZEIGLER-NATTA CATALYST SYSTEMS FOR PRODUCING PROPYLENE POLYMER HAVING HIGH MELT-FLOWABILITY
Cyclic organosilicon compounds having a structure represented by the general formula and a method for using thereof as a component of catalysts for producing propylene polymer having a very high melt-fiowability are disclosed. The cyclic organosilicon compounds are employed as external electron donors in Ziegler-Natta catalyst systems to dramatically improve the hydrogen response, and therefore the catalyst systems can be used to prepare polymer having high melt-flowability and high isotacticity at high yield.
Cyclic organosilicon compounds that may be employed as an electron donor for polymerization catalyst systems, polymerization catalyst systems employing the cyclic organosilicon compounds as an electron donor, methods of making the polymerization catalyst systems, and polymerization processes to produce polyolefin are disclosed. The organosilicon compounds, which are useful as electron donors in polymerization catalyst systems for the production of polyolefins, are represented by the following formula I (I) wherein Q1 and Q2 may be identical or different and are each hetero-atoms selected from the group consisting of N, O, S, Si, B, and P, with the proviso that Q1 and Q2 cannot both be N or both be O. R1 and R2 may be identical or different and are each hydrocarbon-based substituents to Q1 and Q2, respectively. The subscripts m and n are independently O to 3. R3 is an aliphatic, alicyclic or aromatic group. R4 is a hydrocarbon group with 1 to 6 carbon atoms. R5 is a bridging group with a backbone chain length between the two hetero-atoms Q1 and Q2 being 1-8 atoms. The bridging group is selected from the group consisting of aliphatic, alicyetic, and aromatic bivalent radicals.
B01J 31/14 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des composés organiques ou des hydrures métalliques contenant des composés organométalliques ou des hydrures métalliques d'aluminium ou de bore
C07F 7/10 - Composés comportant une ou plusieurs liaisons C—Si azotés
Cyclic organo silicon compounds that may be employed as an electron donor for polymerization catalyst systems, polymerization catalyst systems employing the cyclic organosilicon compounds as an electron donor, methods of making the polymerization catalyst systems, and polymerization processes to produce polyolefin are disclosed. The organosilicon compounds, which are useful as electron donors in polymerization catalyst systems for the production of polyolefins, are represented by the formula (I): where Q1, Q2, Q3, and Q4 may be identical or different and are each hetero-atoms selected from the group consisting of N, O, S, Si, B, and P. R1, R2, R3, and R4 may be identical or different and are each hydrocarbon-based substituents to Q1, Q2, Q3, and Q4, respectively. The subscripts i, j, m, and n are independently 0 to 3. R5 and R6 may be identical or different and are each a bridging group with a backbone chain length between the two hetero-atoms Q1 and Q3, and Q2 and Q4, respectively, being 1-8 atoms. The bridging group is selected from the group consisting of aliphatic, alicyclic, and aromatic bivalent radicals.
Cyclic organosilicon compounds that may be employed as an electron donor for polymerization catalyst systems, polymerization catalyst systems employing the cyclic organosilicon compounds as an electron donor, methods of making the polymerization catalyst systems, and polymerization processes to produce polyolefin are disclosed. The organosilicon compounds, which are useful as electron donors in polymerization catalyst systems for the production of polyolefins, are represented by the formula:
4, respectively, 1-8 atoms. The bridging group is selected from the group consisting of aliphatic, alicyclic, and aromatic bivalent radicals.
C08F 4/44 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides
Cyclic organosilicon compounds that may be employed as an electron donor for polymerization catalyst systems, polymerization catalyst systems employing the cyclic organosilicon compounds as an electron donor, methods of making the polymerization catalyst systems, and polymerization processes to produce polyolefin are disclosed. The organosilicon compounds, which are useful as electron donors in polymerization catalyst systems for the production of polyolefins, are represented by the following formula:
2 being 1-8 atoms. The bridging group is selected from the group consisting of aliphatic, alicyclic, and aromatic bivalent radicals.
C08F 4/44 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides
B01J 31/00 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques
Methods and apparatus to form a catalyst precursor, comprising combining in a reactor magnesium, an alkoxysilane compound, a halogenized silicon compound, a halogenized transition metal compound, a substituted aromatic furan compound having a structural formula,
and an alkyl halide or aromatic halide compound to obtain a solid catalyst precursor, wherein the alkoxysilane compound and halogenized silicon compound are combined prior to either being exposed to the halogenized transition metal compound, and wherein the alkyl halide or aromatic halide compound is introduced to the reactor as the final step.
A process for synthesizing a catalyst component for manufacturing ethylene polymer and co-polymer. The present invention provides a process for synthesizing catalyst component (A), comprising forming a complex by contacting the solid intermediate (B) with an aluminum compound represented by formula X3-nAl(OY)n, and alkyl metal (C), wherein X is halide, Y is a hydrocarbon group or chelating carbonyl group, and wherein 1 is less than or equal to n which is less than or equal to 3, and then contacting the complex with titanium halide having formula ९X4 wherein X is halide. Solid intermediate (B) is formed by reacting magnesium metal with alkyl halide in the presence of alkoxy aluminum represented by formula Al(ORa)3, silicon halide represented by formula SiX4 and alkoxy silane represented by formula Si(ORb)4, wherein Ra and Rb are an aromatic or aliphatic alkyl group and wherein X is halide. Alkyl metal (C) is synthesized by reacting alkyl aluminum compounds represented by formula A1RC3 with a secondary amine having formula HNRd2 and then by reacting with alkyl magnesium compounds represented by formula R6MgR^ wherein Rc, Rd, Re and Rf are an aromatic or aliphatic alkyl group. The catalyst component is suitable for producing ethylene polymer and co-polymer with narrow molecular weight distribution as well as improved branching compositional distribution.
f are an aromatic or aliphatic alkyl group. The catalyst component is suitable for producing ethylene polymer and co-polymer with narrow molecular weight distribution as well as improved branching compositional distribution.
B01J 21/00 - Catalyseurs contenant les éléments, les oxydes ou les hydroxydes du magnésium, du bore, de l'aluminium, du carbone, du silicium, du titane, du zirconium ou du hafnium
B01J 37/00 - Procédés de préparation des catalyseurs, en généralProcédés d'activation des catalyseurs, en général
67.
Highly active alpha-olefin copolymerization catalyst system
A high activity magnesium-based supported catalyst component useful in a catalyst system for the compolymerization of ethylene and alpha-olefin and a process for preparing the catalyst component is described. In the process, alkoxysilane ester is contacted with a halogen-substituted silane to form an organic silicon complex. Optionally, the organic silicon complex is contacted with an aminosilane compound to form an organic silicon complex containing nitrogen. The organic silicon complex containing nitrogen or the organic silicon complex is contacted with a transition metal compound to form an organic silicon complex containing transition metal. The organic silicon complex containing transition metal is then contacted with a substituted aromatic ring nitrogen compound to form a fourth reaction complex, which is then contacted with a magnesium-based composite support that has been prepared in situ by reacting metallic magnesium with an alkyl or aromatic halide to form the catalyst component.
A high activity magnesium-based supported catalyst component useful in a catalyst system for the compolymerization of ethylene and alpha-olefin and a process for preparing the catalyst component is described. In the process, alkoxysilane ester is contacted with a halogen-substituted silane to form an organic silicon complex. Optionally, the organic silicon complex is contacted with an aminosilane compound to form an organic silicon complex containing nitrogen. The organic silicon complex containing nitrogen or the organic silicon complex is contacted with a transition metal compound to form an organic silicon complex containing transition metal. The organic silicon complex containing transition metal is then contacted with a substituted aromatic ring nitrogen compound to form a fourth reaction complex, which is then contacted with a magnesium-based composite support that has been prepared in situ by reacting metallic magnesium with an alkyl or aromatic halide to form the catalyst component.
INSTITUTE OF CHEMISTRY, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Lu, Honglan
Liu, Zhongyang
Chen, Chih-Jian
Hu, Youliang
Lu, Yingying
Ke, Yucai
Guo, Cunyue
Abrégé
Processes are disclosed relating to modifying clays with an olefinic functionalized surfactant containing a chain end polymerizable double bond, and to treating the thus modified organoclay with an olefin polymerization catalyst precursor, and polymerizing an olefin in the presence of the thus treated organoclay and an organoaluminum cocatalyst.
B01J 31/38 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant en outre des composés métalliques inorganiques non prévus dans les groupes du titane, du zirconium ou du hafnium
