Disclosed is a method for the integrated production of two different urea products. One is an aqueous urea solution suitable for use in NOx abatement (generally indicated as Diesel Exhaust Fluid DEF). The other is a solution used as a fertilizer, viz. Urea Ammonium Nitrate (UAN). The production of DEF and UAN are integrated as follows: ammonia recovered from the production of urea is used as a feed to the production of ammonium nitrate. At least part of an aqueous urea stream from urea production, is mixed with ammonium nitrate so as to obtain UAN.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 3/00 - Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
C07C 273/02 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
C07C 273/10 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of ammonia
The disclosure pertains to a degassing apparatus with a confinement comprising a bottom part, a degassing zone is provided by the bottom part. Liquid is redistributed horizontally away from a liquid outlet in embodiments to provide residence time in the degassing zone. The degassing apparatus can be a part of a decomposer of a urea plant.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
The disclosure pertains to a chemical reactor comprising a first and a second chamber, a membrane comprising an oxygen transporting mixed ionic-electronic conducting material and separating the first and second chamber, an inlet of the first chamber, an inlet of the second chamber, and an outlet of the second chamber.
B01J 19/08 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor
B01J 19/24 - Stationary reactors without moving elements inside
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or propertiesManufacturing processes specially adapted therefor characterised by their properties
B01D 71/00 - Semi-permeable membranes for separation processes or apparatus characterised by the materialManufacturing processes specially adapted therefor
Disclosed is a system for the production of urea ammonium nitrate (UAN), which is particularly suitable for processing relatively small ammonium nitrate waste streams into UAN. The system comprises a concentration for ammonium nitrate, a treatment section which allows recovering and recirculating nitrogen compounds entrained in vapor from the concentration section, and a pH control section allowing to adjust the pH of the processed ammonium nitrate waste stream to the extent necessary.
C05C 9/00 - Fertilisers containing urea or urea compounds
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
The disclosure pertains to an ammonium nitrate reactor with a first type static mixer in the mixing zone upstream of the tube bundle and/or a second type static mixer downstream of the tube bundle.
B01J 19/24 - Stationary reactors without moving elements inside
B01J 4/00 - Feed devicesFeed or outlet control devices
B01J 10/00 - Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particlesApparatus specially adapted therefor
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
The disclosure pertains to a urea production process wherein vapor from an evaporation unit for concentrating urea solution is condensed and the resulting process condensate, which contains urea originating from urea entrained in the vapor, is combined with a second urea solution to obtain a dilute urea solution that is suitable e.g. for DEF.
Disclosed is a method for the integrated production of two different urea products. One is an aqueous urea solution suitable for use in NOx abatement (generally indicated as Diesel Exhaust Fluid DEF). The other is a solution used as a fertilizer, viz. Urea Ammonium Nitrate (UAN). The production of DEF and UAN are integrated as follows: ammonia recovered from the production of urea is used as a feed to the production of ammonium nitrate. At least part of an aqueous urea stream from urea production, is mixed with ammonium nitrate so as to obtain UAN.
C07C 273/18 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
Jorissen, Paul Maria Gerardus Clemens Petrus Hubertus
Scheerder, Alexander Aleida Antonius
Ofei, Kirk Anguah
Brun, Alessandro
Simml, Michael
Abstract
The disclosure pertains in certain embodiments to a plant and to urea production in a plant comprising a valve body comprising an inner body part and an outer body part.
B01J 3/03 - Pressure vessels, or vacuum vessels, having closure members or seals specially adapted therefor
C05C 9/00 - Fertilisers containing urea or urea compounds
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
The disclosure pertains to a fluidized bed granulation process, for instance for urea melt. An embodiment of the process comprises providing a fluidized bed of the particles in a granulation compartment of the fluidized bed granulator; forming a film of the granulation liquid in the form of a hollow conical frustum projecting into the granulation compartment by supplying the granulation liquid through a first channel of a granulation nozzle; supplying secondary gas stream through a secondary gas channel of the granulation nozzle into the granulation compartment, wherein the secondary gas channel is provided as an annulus around the first channel, wherein the exit of the secondary gas channel is directly exposed to the fluidized bed in the granulation compartment, wherein particles from the fluidized bed are entrained in said secondary gas stream.
B01J 19/26 - Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
B01J 2/16 - Processes or devices for granulating materials, in generalRendering particulate materials free flowing in general, e.g. making them hydrophobic by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain
The disclosure pertains to a urea production plant and process using a thermal stripper, wherein the reaction mixture is separated in two parts, wherein the first part is supplied at least in part to the thermal stripper and the second part at least in part bypasses the thermal stripper and is supplied to a medium pressure recovery section.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
The disclosure pertains to a urea production process wherein vapor from an evaporation unit for concentrating urea solution is condensed and the resulting process condensate, which contains urea originating from urea entrained in the vapor, is combined with a second urea solution to obtain a dilute urea solution that is suitable e.g. for DEF.
Disclosed is a process for the production of an aqueous urea solution suitable for use as a Diesel Exhaust Fluid (DEF), wherein a condensate of off-gas obtained from further purifying an aqueous urea stream in a treatment section adapted to produce DEF, is sent to an LP dissociation section, thereby the removal of ammonia therefrom. This enables water obtained from such condensate to be recirculated to the DEF purification section, and prevents an unwanted build-up of water in recirculation to urea synthesis.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
B01J 3/00 - Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matterApparatus therefor
13.
AMMONIUM NITRATE PRODUCTION WITH MULTIPLE CONDENSERS
The disclosure pertains to the production of ammonium nitrate using a neutralizer that is provided with multiple condensers for the vapor from the neutralizer.
C05C 9/00 - Fertilisers containing urea or urea compounds
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
The disclosure pertains to an ammonium nitrate reactor with a first type static mixer in the mixing zone upstream of the tube bundle and/or a second type static mixer downstream of the tube bundle.
Disclosed is a system for the production of urea ammonium nitrate (UAN), which is particularly suitable for processing relatively small ammonium nitrate waste streams into UAN. The system comprises a concentration for ammonium nitrate, a treatment section which allows recovering and recirculating nitrogen compounds entrained in vapor from the concentration section, and a pH control section allowing to adjust the pH of the processed ammonium nitrate waste stream to the extent necessary.
The disclosure pertains to a plant for the production of ammonia. The ammonia is produced from hydrogen obtained by electrolysis of water. The electrolysis is powered by a renewable source of energy, complemented with power obtained from the plant during periods of low or no availability of the renewable energy. To this end, the plant is configured such that it can be operated in a charge configuration (obtaining and storing power) and a discharge configuration (employing said power).
The disclosure pertains to a urea production process wherein carbamate in a medium pressure (MP) urea solution is decomposed in a tube bundle of a high pressure (HP) carbamate condenser and resulting gas is condensed in indirect heat exchange with urea solution to be heated and wherein a high pressure (HP) stripper is preferably operated with relatively low stripping efficiency.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C01B 3/02 - Production of hydrogen or of gaseous mixtures containing hydrogen
C01B 3/50 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
C01B 3/52 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquidsRegeneration of used liquids
The disclosure pertains to a plant and process for the coupled production of urea and melamine. In an embodiment, a lean carbamate solution is supplied from the melamine production section to a recovery section of the urea production section. In an embodiment, enriched carbamate solution from the urea production section is supplied to an off-gas condenser of the melamine production section.
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
The disclosure pertains to a urea production plant and process using a thermal stripper, wherein the reaction mixture is separated in two parts, wherein the first part is supplied at least in part to the thermal stripper and the second part at least in part bypasses the thermal stripper and is supplied to a medium pressure recovery section.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
The disclosure pertains to a urea production plant and process using a thermal stripper, wherein the reaction mixture is separated in two parts, wherein the first part is supplied at least in part to the thermal stripper and the second part at least in part bypasses the thermal stripper and is supplied to a medium pressure recovery section.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
The disclosure pertains to a process for the production of urea and melamine, wherein off-has from a high pressure melamine plant is combined with a urea liquid obtained from flashing of a urea synthesis solution. Also disclosed is a system for the combined production, and the modification of an existing plant or system.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
B01J 3/00 - Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matterApparatus therefor
The disclosure pertains to a high pressure carbamate condensation apparatus for a urea plant, a urea plant, and a urea production method. The apparatus comprises a first U-shaped tube bundle arranged around a second U-shaped tube bundle.
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
B01J 4/00 - Feed devicesFeed or outlet control devices
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
2 feed under urea formation conditions in said reactor to form a urea synthesis solution comprising urea, water, carbamate and ammonia, wherein the process further comprises contacting a carbamate-containing liquid stream with an equipment part of said high pressure synthesis section that is made of a ferritic steel alloy.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 3/34 - Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
B01J 19/02 - Apparatus characterised by being constructed of material selected for its chemically-resistant properties
B22F 7/06 - Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting of composite workpieces or articles from parts, e.g. to form tipped tools
Embodiments pertain to a urea plant and to the operation of a urea plant in a reduced load mode. In embodiments, two evaporators in parallel are used, connected to a finishing section respectively to a melamine plant.
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
The disclosure pertains to urea production with, in series, an MP carbamate condenser for condensing at least urea synthesis section off-gas, gas/liquid separation giving a gas stream and a liquid stream, and a second carbamate condenser receiving off-gas from melamine production and said liquid stream.
C07D 251/60 - Preparation of melamine from urea or from carbon dioxide and ammonia
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
The disclosure pertains to a plant and process for the coupled production of urea and melamine. In an embodiment, a lean carbamate solution is supplied from the melamine production section to a recovery section of the urea production section. In an embodiment, enriched carbamate solution from the urea production section is supplied to an off-gas condenser of the melamine production section.
C07D 251/60 - Preparation of melamine from urea or from carbon dioxide and ammonia
C07C 273/02 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
C07D 251/60 - Preparation of melamine from urea or from carbon dioxide and ammonia
Embodiments pertain to a urea plant and to the operation of a urea plant in a reduced load mode. In embodiments, two evaporators in parallel are used, connected to a finishing section respectively to a melamine plant.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
The disclosure pertains to melamine production coupled to urea production, using a melamine off-gas condenser operating at a pressure of at least 25 bar. In embodiment, carbamate solution from a recovery section of the urea production is supplied to the melamine off-gas condenser. In an embodiment, carbamate solution from melamine mother liquor treatment is supplied to the LP carbamate condenser of the recovery section.
C07D 251/60 - Preparation of melamine from urea or from carbon dioxide and ammonia
C07C 273/02 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
C07D 251/60 - Preparation of melamine from urea or from carbon dioxide and ammonia
The disclosure pertains to urea production with, in series, an MP carbamate condenser for condensing at least urea synthesis section off-gas, gas/liquid separation giving a gas stream and a liquid stream, and a second carbamate condenser receiving off-gas from melamine production and said liquid stream.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
The disclosure pertains to a urea plant and process of the thermal stripping type as well as to a method of modifying a urea plant of the thermal stripping type. Provided is a urea plant with a thermal stripper and a high pressure carbamate condenser with a shell space wherein gas from the stripper is condensed in the shell space.
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
38.
METHOD AND PLANT FOR THE PRODUCTION OF AMMONIA WITH RENEWABLE ENERGY
C25B 1/04 - Hydrogen or oxygen by electrolysis of water
F01D 15/10 - Adaptations for driving, or combinations with, electric generators
F25J 3/04 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
39.
METHOD AND PLANT FOR THE PRODUCTION OF AMMONIA WITH RENEWABLE ENERGY
The disclosure pertains to a plant for the production of ammonia. The ammonia is produced from hydrogen obtained by electrolysis of water. The electrolysis is powered by a renewable source of energy, complemented with power obtained from the plant during periods of low or no availability of the renewable energy. To this end, the plant is configured such that it can be operated in a charge configuration (obtaining and storing power) and a discharge configuration (employing said power).
C25B 1/04 - Hydrogen or oxygen by electrolysis of water
F01D 15/10 - Adaptations for driving, or combinations with, electric generators
F25J 3/04 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
Embodiments of the disclosure pertain to a chemical reactor comprising a mixing zone comprising first static mixer and a second static mixer both arranged in shell of the reactor, wherein the second static mixer is positioned further from said first inlet than said first static mixer, wherein the second static mixer is adapted for more intimate mixing of fluids in the reaction mixture than the first static mixer.
B01J 19/24 - Stationary reactors without moving elements inside
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01J 2/16 - Processes or devices for granulating materials, in generalRendering particulate materials free flowing in general, e.g. making them hydrophobic by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain
The disclosure pertains to a fluidized bed granulation process, for instance for urea melt. An embodiment of the process comprises providing a fluidized bed of the particles in a granulation compartment of the fluidized bed granulator; forming a film of the granulation liquid in the form of a hollow conical frustum projecting into the granulation compartment by supplying the granulation liquid through a first channel of a granulation nozzle; supplying secondary gas stream through a secondary gas channel of the granulation nozzle into the granulation compartment, wherein the secondary gas channel is provided as an annulus around the first channel, wherein the exit of the secondary gas channel is directly exposed to the fluidized bed in the granulation compartment, wherein particles from the fluidized bed are entrained in said secondary gas stream.
B01J 2/16 - Processes or devices for granulating materials, in generalRendering particulate materials free flowing in general, e.g. making them hydrophobic by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain
A urea plant and urea production process of the stripping type are provided that are adapted for making Diesel Exhaust Fluid (DEF) or precursor thereof in a DEF production unit downstream of a treatment section. The treatment section receives a part of the urea synthesis stream from a reaction zone, in particular bypassing the HP stripper.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
The present disclosure relates to a corrosion resistant duplex stainless steel (ferritic austenitic alloy) which is suitable for use in a plant for the production of urea; and uses thereof. The disclosure also relates to objects made of said duplex stainless steel. Furthermore, the present disclosure also relates to a method for the production of urea and to a plant for the production of urea comprising one or more parts made from said duplex stainless steel, and to a method of modifying an existing plant for the production of urea.
C22C 38/02 - Ferrous alloys, e.g. steel alloys containing silicon
C22C 38/04 - Ferrous alloys, e.g. steel alloys containing manganese
C22C 38/44 - Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
F28F 21/08 - Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
C21D 9/08 - Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articlesFurnaces therefor for tubular bodies or pipes
C21D 8/00 - Modifying the physical properties by deformation combined with, or followed by, heat treatment
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
The disclosure pertains to a process for the production of urea and melamine, wherein off-has from a high pressure melamine plant is combined with a urea liquid obtained from flashing of a urea synthesis solution. Also disclosed is a system for the combined production, and the modification of an existing plant or system.
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
B01J 19/24 - Stationary reactors without moving elements inside
C07C 273/12 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of melamine
The disclosure pertains to a urea production plant and process using a thermal stripper, wherein the reaction mixture is separated in two parts, wherein the first part is supplied at least in part to the thermal stripper and the second part at least in part bypasses the thermal stripper and is supplied to a medium pressure recovery section.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
The disclosure pertains to a high pressure carbamate condensation apparatus for a urea plant, a urea plant, and a urea production method. The apparatus comprises a first U-shaped tube bundle arranged around a second U-shaped tube bundle.
B01J 4/00 - Feed devicesFeed or outlet control devices
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
F28F 21/08 - Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
The disclosure pertains to a high pressure carbamate condensation apparatus for a urea plant, a urea plant, and a urea production method. The apparatus comprises a first U-shaped tube bundle arranged around a second U-shaped tube bundle.
B01J 4/00 - Feed devicesFeed or outlet control devices
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
F28F 21/08 - Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
50.
UREA PLANT WITH VALVE; UREA PRODUCTION PROCESS; USE AND METHOD
Jorissen, Paul Maria Gerardus Clemens Petrus Hubertus
Scheerder, Alexander Aleida Antonius
Ofei, Kirk Anguah
Brun, Alessandro
Simml, Michael
Abstract
The disclosure pertains in certain embodiments to a plant and to urea production in a plant comprising a valve body comprising an inner body part and an outer body part.
The disclosure pertains to a urea production process wherein carbamate in a medium pressure (MP) urea solution is decomposed in a tube bundle of a high pressure (HP) carbamate condenser and resulting gas is condensed in indirect heat exchange with urea solution to be heated and wherein a high pressure (HP) stripper is preferably operated with relatively low stripping efficiency.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
A urea plant and urea production process of the stripping type are provided that are adapted for making Diesel Exhaust Fluid (DEF) or precursor thereof in a DEF production unit downstream of a treatment section. The treatment section receives a part of the urea synthesis stream from a reaction zone, in particular bypassing the HP stripper.
B01J 10/00 - Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particlesApparatus specially adapted therefor
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
The disclosure pertains to a urea production process wherein carbamate in a medium pressure (MP) urea solution is decomposed in a tube bundle of a high pressure (HP) carbamate condenser and resulting gas is condensed in indirect heat exchange with urea solution to be heated and wherein a high pressure (HP) stripper is preferably operated with relatively low stripping efficiency.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
57.
Nitric acid production process and plant with oxygen supply unit
The disclosure pertains to a nitric acid production process and plant. The process involves supplying an oxygen gas stream and ammonia feedstock to the burner section. In embodiments, a part of the tail gas stream (4) is heated in a tail gas heating section (7) and supplied to the burner section (1).
B01J 8/02 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds
B01J 19/24 - Stationary reactors without moving elements inside
2 stripper, downstream medium-pressure treatment unit and a medium-pressure dissociator receiving urea synthesis solution from the reactor, wherein gas from the treatment unit and dissociator are condensed in a first condenser and off-gas from the synthesis section is condensed separately in a second condenser. A revamping method is also described.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
B01D 3/00 - Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
The disclosure pertains to a urea plant and process of the thermal stripping type as well as to a method of modifying a urea plant of the thermal stripping type. Provided is a urea plant with a thermal stripper and a high pressure carbamate condenser with a shell space wherein gas from the stripper is condensed in the shell space.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 3/00 - Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
The disclosure pertains to a urea plant and process of the thermal stripping type as well as to a method of modifying a urea plant of the thermal stripping type. Provided is a urea plant with a thermal stripper and a high pressure carbamate condenser with a shell space wherein gas from the stripper is condensed in the shell space.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
2 feed under urea formation conditions in said reactor to form a urea synthesis solution comprising urea, water, carbamate and ammonia, wherein the process further comprises contacting a carbamate-containing liquid stream with an equipment part of said high pressure synthesis section that is made of a ferritic steel alloy.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 3/34 - Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
B01J 19/02 - Apparatus characterised by being constructed of material selected for its chemically-resistant properties
B22F 7/06 - Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting of composite workpieces or articles from parts, e.g. to form tipped tools
Method of producing prills includes providing a hollow body rotatable about a first axis, the body having a wall rotationally symmetrical around the first axis forming an interior space, the wall including nozzles; providing a second body disposed in the hollow body such that a gap exists between the hollow body and the second body; supplying liquid to the gap; generating jets of liquid from the nozzles radially outward by driving the rotational motion of the hollow body and/or second body around the first axis of rotation using a rotary drive unit; applying a reciprocal pressure excitation on the jets of liquid by moving the hollow body and/or second body along the first axis; and decoupling the rotations of the one of the hollow body and second body and a reciprocating drive-unit.
B01J 2/04 - Processes or devices for granulating materials, in generalRendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a gaseous medium
B05B 3/10 - Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements discharging over substantially the whole periphery of the rotating member
B05B 3/14 - Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with oscillating elementsSpraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with intermittent operation
An apparatus for producing prills includes a hollow body rotatable about a first axis, the body having a wall rotationally symmetrical around the first axis forming an interior space, the wall including nozzles for generating jets of liquid in a radially outward direction with respect to the first axis when rotating the hollow body; a second body disposed in the hollow body forming a gap between the hollow body and the second body; a liquid inlet for supplying a flow of liquid to the gap; a rotary drive unit for driving the hollow body around the first axis; a reciprocating drive-unit for reciprocally moving the hollow body and/or second body with respect to the other body along the first axis of rotation for applying reciprocal pressure on the jets; and a coupling for enabling relative rotations between the one of the hollow body and second body and the reciprocating drive-unit.
B01J 2/04 - Processes or devices for granulating materials, in generalRendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a gaseous medium
B01J 2/18 - Processes or devices for granulating materials, in generalRendering particulate materials free flowing in general, e.g. making them hydrophobic using a vibrating apparatus
B05B 1/08 - Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to produce a jet, spray, or other discharge of particular shape or nature, e.g. in single drops of pulsating nature, e.g. delivering liquid in successive separate quantities
B05B 3/10 - Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements discharging over substantially the whole periphery of the rotating member
B05B 3/14 - Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with oscillating elementsSpraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with intermittent operation
64.
NITRIC ACID PRODUCTION PROCESS AND PLANT WITH OXYGEN SUPPLY UNIT
The disclosure pertains to a nitric acid production process and plant. The process involves supplying an oxygen gas stream and ammonia feedstock to the burner section. In embodiments, a part of the tail gas stream (4) is heated in a tail gas heating section (7) and supplied to the burner section (1).
The disclosure pertains to a nitric acid production process and plant. The process involves supplying an oxygen gas stream and ammonia feedstock to the burner section. In embodiments, a part of the tail gas stream (4) is heated in a tail gas heating section (7) and supplied to the burner section (1).
The disclosure pertains to a urea production plant and process using a high-pressure CO2 stripper, downstream medium-pressure treatment unit and a medium-pressure dissociator receiving urea synthesis solution from the reactor, wherein gas from the treatment unit and dissociator are condensed in a first condenser and off-gas from the synthesis section is condensed separately in a second condenser. A revamping method is also described.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
22 stripper, downstream medium-pressure treatment unit and a medium-pressure dissociator receiving urea synthesis solution from the reactor, wherein gas from the treatment unit and dissociator are condensed in a first condenser and off-gas from the synthesis section is condensed separately in a second condenser. A revamping method is also described.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
Embodiments of the disclosure pertain to a chemical reactor comprising a mixing zone comprising first static mixer and a second static mixer both arranged in shell of the reactor, wherein the second static mixer is positioned further from said first inlet than said first static mixer, wherein the second static mixer is adapted for more intimate mixing of fluids in the reaction mixture than the first static mixer.
B01F 25/431 - Straight mixing tubes with baffles or obstructions that do not cause substantial pressure dropBaffles therefor
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
B01J 19/24 - Stationary reactors without moving elements inside
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
Embodiments of the disclosure pertain to a chemical reactor comprising a mixing zone comprising first static mixer and a second static mixer both arranged in shell of the reactor, wherein the second static mixer is positioned further from said first inlet than said first static mixer, wherein the second static mixer is adapted for more intimate mixing of fluids in the reaction mixture than the first static mixer.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
B01J 19/24 - Stationary reactors without moving elements inside
B01F 25/431 - Straight mixing tubes with baffles or obstructions that do not cause substantial pressure dropBaffles therefor
A method for the removal of ammonia from the off-gas of a finishing section of a urea production plant, a corresponding urea plant, and a method of accordingly modifying a pre-existing urea plant. In a scrubbing section, off-gas is brought into contact with acidic scrubbing liquid to provide a scrubbed off-gas and a utilized scrubbing liquid comprising ammonium salt. The method specifies an evaporation section, which is part of the urea plant that produces urea melt, that is divided into first and second stages. The first stage is part of the urea melt production plant. The second stage is decoupled, as regards recirculation of liquids other than the urea product stream, from the urea melt production plant. This is accomplished by sending utilized scrubbing liquid containing ammonium salts to the second stage evaporation section, and condensed vapours from said second stage evaporation section to said scrubbing section.
C07C 273/14 - SeparationPurificationStabilisationUse of additives
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
The disclosure pertains to an urea production plant and process using a thermal stripper, wherein the reaction mixture is separated in two parts, wherein the first part is supplied at least in part to the thermal stripper and the second part at least in part bypasses the thermal stripper and is supplied to a medium pressure recovery section.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
Some embodiments of the disclosure pertain to a plant and a process for producing a urea-containing product. The plant comprises a medium pressure dissociation unit and a high pressure CO2 stripper each receiving a part of the urea synthesis solution. Stripped urea solution is further treated in a medium pressure treatment unit.
B01J 10/00 - Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particlesApparatus specially adapted therefor
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
73.
UREA PRODUCTION PROCESS AND PLANT WITH PARALLEL MP UNITS
B01J 10/00 - Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particlesApparatus specially adapted therefor
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
2 feed under urea formation conditions in said reactor to form a urea synthesis solution comprising urea, water, carbamate and ammonia, wherein the process further comprises contacting a carbamate-containing liquid stream with an equipment part of said high pressure synthesis section that is made of a ferritic steel alloy.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 3/34 - Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
B01J 19/02 - Apparatus characterised by being constructed of material selected for its chemically-resistant properties
C22C 38/02 - Ferrous alloys, e.g. steel alloys containing silicon
C22C 38/04 - Ferrous alloys, e.g. steel alloys containing manganese
C22C 38/42 - Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
C22C 38/44 - Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
C22C 38/48 - Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
C22C 38/26 - Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
B22F 7/06 - Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting of composite workpieces or articles from parts, e.g. to form tipped tools
Described are a high pressure carbamate condenser, urea plant, and urea production process. The high pressure carbamate condenser as described is of the shell-and-tube heat exchanger type with a tube bundle and has a redistribution chamber connected to tubes of the tube bundle and to a duct. The duct extends between the redistribution chamber and the shell.
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
B01J 10/00 - Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particlesApparatus specially adapted therefor
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C07C 273/14 - SeparationPurificationStabilisationUse of additives
F28D 7/06 - Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits having a single U-bend
Disclosed is a method for the removal of soluble particulate matter from a gas stream, such as urea dust from the off-gas of a finishing section of a urea production plant. The method comprises subjecting the off-gas to at least two quenching stages an aqueous quenching liquid. The quenching liquid used in a first, upstream quench stage, is allowed to have a higher concentration of dissolved particulate matter than the quenching liquid in the second, downstream quench stage. The quenched gas is led through a particle capture zone, typically comprising one or more of a wet scrubber, a Venturi scrubber, and a wet electrostatic precipitator.
Disclosed is a method for the removal of ammonia from the off-gas of a finishing section of a urea production plant. Also disclosed is a corresponding urea plant, and a method of accordingly modifying a pre-existing urea plant. In a scrubbing section, the off-gas is brought into contact with an acidic scrubbing liquid so as to provide a scrubbed off-gas and a utilized scrubbing liquid comprising ammonium salt. The method specifies an evaporation section, which is part of the urea plant that produces urea melt, that is divided into first and second stages. The first stage is part of the urea melt production plant. The second stage decoupled, as regards recirculation of liquids other than the urea product stream, from the urea melt production plant. This is accomplished by sending utilized scrubbing liquid that contains ammonium salts to the second stage evaporation section, and by sending condensed vapours from said second stage evaporation section to said scrubbing section.
C07C 273/14 - SeparationPurificationStabilisationUse of additives
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
A urea production process which includes and a synthesis section, a recovery section and evaporation section and a finishing section wherein the evaporation section includes a first evaporator and downstream thereof a second evaporator for urea solution. The second evaporator operates a lower pressure than the first evaporator to provide a urea melt and second vapor, solidifying the urea melt in a finishing section to provide a solid urea produce and off gas, scrubbing the off gas followed by condensing to produce a first condensate and second condensate; supplying the first condensate to a wastewater treatment section and supply the second condensate to the scrubber wherein the second condensate is used as a scrub liquid in the scrubber.
C02F 103/36 - Nature of the water, waste water, sewage or sludge to be treated from the chemical industry not provided for in groups from the manufacture of organic compounds
A urea production process comprising concentrating a first urea solution in a first vacuum evaporator in an evaporation section to give a urea melt and a first vapor, and condensing the first vapor in a first condensation section, wherein the first condensation section is a chilled condensation section, and a urea production system comprising the chilled condensation section.
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
A method is disclosed for stripping in a stripper a urea synthesis solution received from a urea forming process wherein ammonia and CO2 are reacted under urea forming conditions. The shell space of the stripper comprises a continuous vertical zone.
C07C 273/18 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
The disclosure pertains to an urea production plant and process using a thermal stripper, wherein the reaction mixture is separated in two parts, wherein the first part is supplied at least in part to the thermal stripper and the second part at least in part bypasses the thermal stripper and is supplied to a medium pressure recovery section.
B01J 3/00 - Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matterApparatus therefor
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
The disclosure pertains to an urea production plant and process using a thermal stripper, wherein the reaction mixture is separated in two parts, wherein the first part is supplied at least in part to the thermal stripper and the second part at least in part bypasses the thermal stripper and is supplied to a medium pressure recovery section.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01J 3/00 - Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matterApparatus therefor
83.
Integrated production of urea for Diesel Exhaust Fluid and urea ammonium nitrate
Disclosed is a method for the integrated production of two different urea products. One is an aqueous urea solution suitable for use in NOx abatement (generally indicated as Diesel Exhaust Fluid DEF). The other is a solution used as a fertilizer, viz. Urea Ammonium Nitrate (UAN). The production of DEF and UAN are integrated as follows: ammonia recovered from the production of urea is used as a feed to the production of ammonium nitrate. At least part of an aqueous urea stream from urea production, is mixed with ammonium nitrate so as to obtain UAN.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
B01D 3/00 - Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
C07C 273/02 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
C07C 273/10 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of ammonia
C07C 273/14 - SeparationPurificationStabilisationUse of additives
Disclosed is a urea finishing method including an off-gas treatment, the method comprising urea finishing and supplying the off-gas to a quenching zone and to a scrub column comprising a sump and a venturi stage, wherein the sump has a split sump configuration with two compartments.
B01D 53/78 - Liquid phase processes with gas-liquid contact
B01J 2/16 - Processes or devices for granulating materials, in generalRendering particulate materials free flowing in general, e.g. making them hydrophobic by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain
Disclosed is a method for the removal of ammonia from the off-gas of a finishing section of a urea production plant. Also disclosed is a corresponding urea plant, and a method of accordingly modifying a pre-existing urea plant. In a scrubbing section, the off-gas is brought into contact with an acidic scrubbing liquid so as to provide a scrubbed off-gas and a utilized scrubbing liquid comprising ammonium salt. The method specifies an evaporation section, which is part of the urea plant that produces urea melt, that is divided into first and second stages. The first stage is part of the urea melt production plant. The second stage decoupled, as regards recirculation of liquids other than the urea product stream, from the urea melt production plant. This is accomplished by sending utilized scrubbing liquid that contains ammonium salts to the second stage evaporation section, and by sending condensed vapours from said second stage evaporation section to said scrubbing section.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
Disclosed is a method for the removal of ammonia from the off-gas of a finishing section of a urea production plant. Also disclosed is a corresponding urea plant, and a method of accordingly modifying a pre-existing urea plant. In a scrubbing section, the off-gas is brought into contact with an acidic scrubbing liquid so as to provide a scrubbed off-gas and a utilized scrubbing liquid comprising ammonium salt. The method specifies an evaporation section, which is part of the urea plant that produces urea melt, that is divided into first and second stages. The first stage is part of the urea melt production plant. The second stage decoupled, as regards recirculation of liquids other than the urea product stream, from the urea melt production plant. This is accomplished by sending utilized scrubbing liquid that contains ammonium salts to the second stage evaporation section, and by sending condensed vapours from said second stage evaporation section to said scrubbing section.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C07C 273/14 - SeparationPurificationStabilisationUse of additives
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
The disclosure pertains to a urea production process using a first and a downstream second evaporator in an evaporation section, a finishing section and a scrubber for treating off-gas of the finishing section. Condensate from the condenser of the second evaporator is supplied to the scrubber.
B01D 53/73 - After-treatment of removed components
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C07C 273/14 - SeparationPurificationStabilisationUse of additives
The disclosure pertains to a urea production process and a production plant comprising evaporation, finishing, and wastewater treatment sections, and a scrubber. The evaporation section comprises a first evaporator and downstream second evaporator, and first and second condensers. The process includes concentrating urea solution in the first evaporator, giving concentrated urea solution and a first vapor, concentrating the concentrated urea solution in the second evaporator, giving a urea melt and second vapor, solidifying the urea melt in the finishing section giving solid urea product and off-gas, scrubbing said off-gas in the scrubber, condensing said first and second vapors in the first and second condensers, respectively, giving first and second condensates, separately supplying said first condensate to a wastewater treatment section, and said second condensate to said scrubber. The second condensate is used as scrub liquid in said scrubber, which additionally uses an acid scrub liquid.
B01D 53/73 - After-treatment of removed components
C07C 273/02 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
The disclosure pertains to a urea production process comprising concentrating a first urea solution in a first vacuum evaporator in an evaporation section to give a urea melt and first vapor, and condensing said first vapor in a first condensation section, wherein the first condensation section is a chilled condensation section.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
The disclosure pertains to a urea production process comprising concentrating a first urea solution in a first vacuum evaporator in an evaporation section to give a urea melt and first vapor, and condensing said first vapor in a first condensation section, wherein the first condensation section is a chilled condensation section.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
Disclosed is a shell-and-tube heat exchanger type with a tube bundle and has a redistribution chamber connected to tubes of the tube bundle and to a duct. The duct extends between the redistribution chamber and the shell.
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
B01J 10/00 - Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particlesApparatus specially adapted therefor
F28D 9/02 - Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the heat-exchange media travelling at an angle to one another
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C07C 273/14 - SeparationPurificationStabilisationUse of additives
F28D 7/06 - Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits having a single U-bend
Disclosed is a method for the removal of urea dust from the off-gas of a finishing section of a urea production plant. the method comprises subjecting the off-gas to quenching with water so as to produce quenched off-gas. The quenched off-gas is subjected to humidification by mixing said quenched gas stream with a humidification fluid selected from (a) saturated steam and (b) superheated steam mixed with a second aqueous stream, so as to produce a humidified gas stream, subjecting said humidified gas stream to particle separation (i.e., dust removal) by means of a scrubbing liquid in which at least part of the particles in the gas stream are soluble.
C05C 9/00 - Fertilisers containing urea or urea compounds
C07C 273/02 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
322 feed under urea formation conditions in said reactor to form a urea synthesis solution comprising urea, water, carbamate and ammonia, wherein the process further comprises contacting a carbamate- containing liquid stream with an equipment part of said high pressure synthesis section that is made of a ferritic steel alloy.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C22C 38/02 - Ferrous alloys, e.g. steel alloys containing silicon
C22C 38/04 - Ferrous alloys, e.g. steel alloys containing manganese
C22C 38/20 - Ferrous alloys, e.g. steel alloys containing chromium with copper
C22C 38/22 - Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
C22C 38/26 - Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
C22C 38/40 - Ferrous alloys, e.g. steel alloys containing chromium with nickel
B01J 19/02 - Apparatus characterised by being constructed of material selected for its chemically-resistant properties
The application provides in an aspect a process for producing urea in a urea plant comprising a high pressure synthesis section comprising a reactor, wherein the process comprises reacting NH3 feed and CO2 feed under urea formation conditions in said reactor to form a urea synthesis solution comprising urea, water, carbamate and ammonia, wherein the process further comprises contacting a carbamate- containing liquid stream with an equipment part of said high pressure synthesis section that is made of a ferritic steel alloy.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
C22C 38/18 - Ferrous alloys, e.g. steel alloys containing chromium
C22C 38/22 - Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
C22C 38/26 - Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
F28F 21/08 - Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
95.
Urea production process and plant with heat integration in low pressure recovery section
The invention pertains to a urea production process using a high pressure stripper and a low pressure decomposer connected to a low pressure carbamate condenser which is in heat exchanging contact through a wall with a sub-atmospheric decomposer wherein urea solution obtained from the low pressure decomposer is processed.
C07C 273/14 - SeparationPurificationStabilisationUse of additives
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
A method is disclosed for stripping in a stripper a urea synthesis solution received from a urea forming process wherein ammonia and CO2 are reacted under urea forming conditions. The shell space of the stripper comprises a continuous vertical zone.
A method is disclosed for stripping in a stripper a urea synthesis solution received from a urea forming process wherein ammonia and CO2 are reacted under urea forming conditions. The shell space of the stripper comprises a continuous vertical zone.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
A method is disclosed for stripping in a stripper a urea synthesis solution received from a urea forming process wherein ammonia and CO2 are reacted under urea forming conditions. The shell space of the stripper comprises a continuous vertical zone.
C07C 273/04 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
A fluidized bed granulator for granulation with urea or urea-containing liquids is described, wherein the granulation liquid is supplied via a supply manifold comprising a header and risers. The risers are at least in part provided inside channels for secondary gas.
B01J 2/16 - Processes or devices for granulating materials, in generalRendering particulate materials free flowing in general, e.g. making them hydrophobic by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain
C05C 9/00 - Fertilisers containing urea or urea compounds
C07C 273/02 - Preparation of urea or its derivatives, i.e. compounds containing any of the groups the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
B05B 7/04 - Spray pistolsApparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
B01J 19/26 - Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
B05B 7/10 - Spray pistolsApparatus for discharge producing a swirling discharge
Disclosed is a urea finishing method including an off-gas treatment, the method comprising urea finishing and supplying the off-gas to a quenching zone and to a scrub column comprising a sump and a venturi stage, wherein the sump has a split sump configuration with two compartments.
B01D 47/12 - Washers with plural different washing sections
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
