A method of processing of shredded rubber-containing waste involves its preliminary preparation, thermal decomposition in a furnace, separation of decomposition products into vapor-gas mixture and solid residue, and separation of a heavy hydrocarbon fraction from the vapor-gas mixture. Preliminary preparation of the waste is carried out by its blowing with water vapor until a waste temperature reaches 100° C., and thermal decomposition is carried out in residual oil in the starting phase, and afterwards in the atomized generated heavy hydrocarbon fraction and superheated water vapor, their weight ratio being (0.1-0.5):1. The heavy hydrocarbon fraction is separated from the vapor-gas mixture with water by atomizing it into the vapor-gas mixture flow at the rate of 5-15% of the mass flow rate of the mixture, while metal is extracted from the solid residue by magnetic separation, after which a product containing zinc oxide is separated by dielectric separation.
C10B 53/07 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of synthetic polymeric materials, e.g. tyres
C10G 1/10 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
C10G 5/06 - Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas by cooling or compressing
The device for producing carbon black from waste rubber has a pyrolysis reactor, a solid product discharge system, a pyrolysis gas emission means, a shell and tube heat exchanger, a solid pyrolysis product receiver, a pyrolysis gas condenser, and a flue gas output means. The shell and tube heat exchanger has a burner linked to the tubes. The space between the tubes of the heat exchanger is filled with a disperse material having a particle size of 3-10 cm. The inlet of the pyrolysis gas emission means is linked to the pyrolysis reactor, and the outlet is linked to the space between the tubes of the heat exchanger. The inlet of the condenser is linked to the casing of the pyrolysis reactor, which is linked to the tubes of the heat exchanger.
C10G 1/10 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
C10B 53/07 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of synthetic polymeric materials, e.g. tyres
C08J 11/12 - Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by dry-heat treatment only
C10B 47/46 - Other processes in ovens with mechanical conveying means with trucks, containers, or trays
C10K 1/04 - Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
Scrap rubber is decomposed in a reactor. The decomposition products are separated into gaseous products and carbon residue. The gaseous products are heated to 1200-1300° C. to decomposition primarily resins and asphaltenes, oil is isolated, atomized to a droplet size of 0.2-2.0 mm, mixed in a ratio of 1:(0.05-3.0) with the carbon residue, which is ground to 0.1-1.0 mm, and thermally decomposed into carbon black with an atomic hydrogen-to-carbon ratio (H:C) in the range of 0.02-0.07 and gases. Ash and volatile compounds are removed from the carbon residue. Carbon black is separated from the ash. The heat given off during combustion of part of the oil is spent on the formation of carbon black, the flash heating of the carbon residue and the removal of volatile substances therefrom, said volatile substances being subjected to intensive heating in the absence of oxygen using heated carbon black particles and oil combustion products.
C08J 11/12 - Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by dry-heat treatment only
C10B 47/44 - Other processes in ovens with mechanical conveying means with conveyor-screws
C10B 53/07 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of synthetic polymeric materials, e.g. tyres
C10G 1/10 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
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