Emerald Kalama Chemical, LLC

United States of America

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Date
2020 7
Before 2020 20
IPC Class
C08K 5/101 - EstersEther-esters of monocarboxylic acids 9
C09J 11/06 - Non-macromolecular additives organic 9
C08J 3/18 - Plasticising macromolecular compounds 8
C08K 5/00 - Use of organic ingredients 7
C08K 5/103 - EstersEther-esters of monocarboxylic acids with polyalcohols 7
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Status
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Registered / In Force 26
Found results for  patents

1.

LOW VOC MULTIFUNCTIONAL ADDITIVES TO IMPROVE WATERBORNE POLYMER FILM PROPERTIES

      
Document Number 03135399
Status Pending
Filing Date 2020-04-03
Open to Public Date 2020-10-08
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Foster, Stephen Finley
  • Farrell, Bradley Les
  • Mcbride, Emily
  • Posselt, Kyle Jeffrey
  • Vaughn-Biege, Julie O.
  • Strother, Sarah L.

Abstract

Low VOC multifunctional additive blends provide, in addition to coalescence, increased hardness, hardness development, scrub resistance, block resistance, dirt pickup resistance, wet adhesion, and corrosion (flash rust) resistance, among other properties, to waterborne coatings or other waterborne polymer film-forming compositions, and are comprised of known low volatile coalescents in combination with certain high volatile components some of which were not known nor heretofore utilized as coalescents. The inventive blends have been found to act synergistically to provide coalescence and unexpected improvement in properties of waterborne polymer formulations, while still providing a low VOC content to the formulations. The invention is also directed to methods for improving the properties of waterborne polymer systems and for incorporating organic acids into waterborne coatings to enhance flash rust resistance, among other properties, through use of the low VOC multifunctional additive blends of the invention.

IPC Classes  ?

  • A61K 8/87 - Polyurethanes
  • A61K 8/891 - Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
  • A61Q 1/06 - Lipsticks

2.

LOW VOC MULTIFUNCTIONAL ADDITIVES TO IMPROVE WATERBORNE POLYMER FILM PROPERTIES

      
Application Number US2020026635
Publication Number 2020/206296
Status In Force
Filing Date 2020-04-03
Publication Date 2020-10-08
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Foster, Stephen Finley
  • Farrell, Bradley Les
  • Mcbride, Emily
  • Posselt, Kyle Jeffrey
  • Vaughn-Biege, Julie O.
  • Strother, Sarah L.

Abstract

Low VOC multifunctional additive blends provide, in addition to coalescence, increased hardness, hardness development, scrub resistance, block resistance, dirt pickup resistance, wet adhesion, and corrosion (flash rust) resistance, among other properties, to waterborne coatings or other waterborne polymer film-forming compositions, and are comprised of known low volatile coalescents in combination with certain high volatile components some of which were not known nor heretofore utilized as coalescents. The inventive blends have been found to act synergistically to provide coalescence and unexpected improvement in properties of waterborne polymer formulations, while still providing a low VOC content to the formulations. The invention is also directed to methods for improving the properties of waterborne polymer systems and for incorporating organic acids into waterborne coatings to enhance flash rust resistance, among other properties, through use of the low VOC multifunctional additive blends of the invention.

IPC Classes  ?

  • A61K 8/87 - Polyurethanes
  • A61K 8/891 - Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
  • A61Q 1/06 - Lipsticks

3.

MULTIFUNCTIONAL AROMATIC ALCOHOLS FOR PERSONAL CARE, HOME CARE AND INDUSTRIAL AND INSTITUTIONAL COMPOSITIONS

      
Application Number US2019062422
Publication Number 2020/106847
Status In Force
Filing Date 2019-11-20
Publication Date 2020-05-28
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Farrell, Bradley Les
  • Pippine, Kelly Reed
  • Foster, Stephen Finley
  • Stokes, Rosanna Williamson
  • Yarnell, Amber
  • Keehan, Natalie Irene
  • Strother, Sarah L.

Abstract

Multifunctional additives for use in a wide variety of products comprise aromatic alcohols including without limitation 3-phenylpropanol, 2-phenylethanol, 2-methyl-3-phenylpropanol, methyl benzene ethanol, methyl benzene propanol, or 4-phenyl-1- butanol, or mixtures thereof. The multifunctional aromatic alcohols provide unexpected improvements in processing and in end use product properties of a wide variety of products and are useful at a wide range of pH.

IPC Classes  ?

4.

Monobenzoate analogs useful as plasticizers in plastisol compositions

      
Application Number 16725574
Grant Number 10995198
Status In Force
Filing Date 2019-12-23
First Publication Date 2020-04-30
Grant Date 2021-05-04
Owner Emerald Kalama Chemical, LLC (USA)
Inventor
  • Mcbride, Emily
  • Roth, Steven D.
  • Andrews, Jerry
  • Arendt, William D.

Abstract

Unique 3-PPB monobenzoate analogs useful as plasticizers in polymeric dispersions, such as plastisols, melt compounds, and adhesives among other applications. The analogs are structurally similar to and/or derived from 3-phenylpropyl benzoate and heretofore were not known for use in industrial applications, particularly not as a plasticizer in polymeric applications including without limitation plastisols and adhesives. Depending on the application, the advantages rendered by the use of the inventive monobenzoate analogs include, among other things, excellent solvating properties and rheology, low viscosity and significantly improved viscosity over time, comparable or improved Tg suppression, set and open times, as well as health, safety and environmental advantages, over traditional plasticizers.

IPC Classes  ?

  • C08K 5/101 - EstersEther-esters of monocarboxylic acids
  • C08K 5/12 - EstersEther-esters of cyclic polycarboxylic acids
  • C08L 27/06 - Homopolymers or copolymers of vinyl chloride
  • C08L 33/08 - Homopolymers or copolymers of acrylic acid esters
  • C08L 33/10 - Homopolymers or copolymers of methacrylic acid esters

5.

MODIFIERS FOR LUXURY VINYL TILE TO INCREASE HARDNESS AND RIGIDITY

      
Application Number US2019039884
Publication Number 2020/006450
Status In Force
Filing Date 2019-06-28
Publication Date 2020-01-02
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Mcbride, Emily
  • Linkenhoger, Karena Kaye
  • Farrell, Bradley Les
  • Posselt, Kyle Jeffrey
  • Arendt, William D

Abstract

Modifiers for use in vinyl flooring applications reduce or eliminate the need for traditional, general-purpose plasticizers in applications that require increased hardness or rigidity. High solvating, fast fusing modifiers, such as dibenzoates, added to LVT formulations provide unexpectedly increased flexural strength, hardness, indentation resistance and deflection not heretofore known or recognized in luxury vinyl tile formulations.

IPC Classes  ?

  • C08J 3/18 - Plasticising macromolecular compounds
  • C08K 5/101 - EstersEther-esters of monocarboxylic acids
  • C08K 5/103 - EstersEther-esters of monocarboxylic acids with polyalcohols
  • C08L 27/06 - Homopolymers or copolymers of vinyl chloride
  • C09J 11/06 - Non-macromolecular additives organic

6.

IMPROVED REACTIVE POLYURETHANE SYSTEMS

      
Application Number US2019039918
Publication Number 2020/006473
Status In Force
Filing Date 2019-06-28
Publication Date 2020-01-02
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Mcbride, Emily
  • Vaughn-Biege, Julie O.
  • Butt, Jason R.
  • Posselt, Kyle Jeffrey
  • Arendt, William

Abstract

Low hydroxyl value dibenzoate plasticizer for use in a reactive polyurethane composition, including but not limited to thermoplastic and thermoset polyurethanes, wherein the plasticizer is particularly useful in TPU's, a reactive polyurethane adhesive or sealant, or a castable polyurethane article and achieves comparable or improved properties, including without limitation compatibility, color, exudation, optical properties, MVTR, hardness, tensile strength, tear strength, rebound, compression set, and solvent swell, when compared with that achieved with traditional plasticizers, including other benzoate esters, used in polyurethane compositions.

IPC Classes  ?

  • C08G 18/00 - Polymeric products of isocyanates or isothiocyanates
  • C08J 3/18 - Plasticising macromolecular compounds
  • C08K 5/101 - EstersEther-esters of monocarboxylic acids
  • C08K 5/103 - EstersEther-esters of monocarboxylic acids with polyalcohols
  • C09J 11/06 - Non-macromolecular additives organic

7.

IMPROVED REACTIVE POLYURETHANE SYSTEMS

      
Document Number 03104130
Status In Force
Filing Date 2019-06-28
Open to Public Date 2020-01-02
Grant Date 2023-04-11
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Mcbride, Emily
  • Vaughn-Biege, Julie O.
  • Butt, Jason R.
  • Posselt, Kyle Jeffrey
  • Arendt, William

Abstract

Low hydroxyl value dibenzoate plasticizer for use in a reactive polyurethane composition, including but not limited to thermoplastic and thermoset polyurethanes, wherein the plasticizer is particularly useful in TPU's, a reactive polyurethane adhesive or sealant, or a castable polyurethane article and achieves comparable or improved properties, including without limitation compatibility, color, exudation, optical properties, MVTR, hardness, tensile strength, tear strength, rebound, compression set, and solvent swell, when compared with that achieved with traditional plasticizers, including other benzoate esters, used in polyurethane compositions.

IPC Classes  ?

  • C08G 18/00 - Polymeric products of isocyanates or isothiocyanates
  • C08J 3/18 - Plasticising macromolecular compounds
  • C08K 5/101 - EstersEther-esters of monocarboxylic acids
  • C08K 5/103 - EstersEther-esters of monocarboxylic acids with polyalcohols
  • C09J 11/06 - Non-macromolecular additives organic

8.

BOOSTERS FOR ANTIMICROBIAL, PRESERVATIVE AND BIOCIDAL APPLICATIONS

      
Application Number US2018058986
Publication Number 2019/090098
Status In Force
Filing Date 2018-11-02
Publication Date 2019-05-09
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Foster, Stephen Finley
  • Pippine, Kelly Reed
  • Stokes, Rosanna Williamson

Abstract

Antimicrobial compounds for use in boosting the efficacy of known antimicrobial, preservative or biocidal compositions. Methods of boosting antimicrobial activity of known compositions, even at low use concentrations, is achieved through adding a booster compound to the known antimicrobial, preservative or biocidal compositions. Use of boosted antimicrobial compositions in end-use applications or products is also described.

IPC Classes  ?

9.

ANTIMICROBIAL COMPOSITIONS

      
Application Number US2018058995
Publication Number 2019/090105
Status In Force
Filing Date 2018-11-02
Publication Date 2019-05-09
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Foster, Stephen Finley
  • Pippine, Kelly Reed
  • Proestos, James Anthony, Jr.
  • Farrell, Bradley Les
  • Vaughn Biege, Julie O.

Abstract

An antimicrobial composition comprising 3-phenyl propanol or 2-methyl 3-phenylpropanol, or mixtures thereof, alone or in combination with an organic acid or salt thereof, or an alcohol, or mixtures thereof. Methods of preserving products and end-use applications for use of the inventive antimicrobial compositions are also provided.

IPC Classes  ?

  • A61K 8/30 - Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K 8/33 - Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K 8/34 - Alcohols

10.

Monobenzoate analogs useful as plasticizers in plastisol compositions

      
Application Number 15510880
Grant Number 10513595
Status In Force
Filing Date 2015-09-25
First Publication Date 2017-09-07
Grant Date 2019-12-24
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily
  • Roth, Steven D.
  • Andrews, Jerry

Abstract

Unique 3-PPB monobenzoate analogs useful as plasticizers in polymeric dispersions, such as plastisols, melt compounds, and adhesives among other applications. The analogs are structurally similar to and/or derived from 3-phenylpropyl benzoate and heretofore were not known for use in industrial applications, particularly not as a plasticizer in polymeric applications. Depending on the application, the advantages rendered by the use of the inventive monobenzoate analogs include, among other things, excellent solvating properties and rheology, low viscosity and significantly improved viscosity over time, comparable or improved Tg suppression, set and open times, as well as health, safety and environmental advantages, over traditional plasticizers.

IPC Classes  ?

  • C08K 5/101 - EstersEther-esters of monocarboxylic acids
  • C08K 5/00 - Use of organic ingredients
  • C08L 27/06 - Homopolymers or copolymers of vinyl chloride
  • C09J 123/08 - Copolymers of ethene
  • C08L 23/08 - Copolymers of ethene
  • C09J 131/04 - Homopolymers or copolymers of vinyl acetate
  • C08L 31/04 - Homopolymers or copolymers of vinyl acetate
  • C09J 11/06 - Non-macromolecular additives organic
  • C09J 133/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
  • C09J 133/08 - Homopolymers or copolymers of acrylic acid esters
  • C09J 133/00 - Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereofAdhesives based on derivatives of such polymers
  • C08L 33/00 - Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereofCompositions of derivatives of such polymers
  • C08L 33/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
  • C08L 33/08 - Homopolymers or copolymers of acrylic acid esters

11.

Polyester plasticizers with benzoic acid end-caps

      
Application Number 15109339
Grant Number 10519296
Status In Force
Filing Date 2015-01-02
First Publication Date 2016-11-10
Grant Date 2019-12-31
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily
  • Roth, Steven D.
  • Hatcher, Eric

Abstract

Polyester plasticizer compositions for adhesives, caulk, sealants, vinyl and other polymeric compositions comprising low molecular weight oligomeric dibenzoates prepared by end-capping a polyester plasticizer, having alternating units of glycols or diols and dibasic acids, with benzoic acid. Methods for preparing oligomeric dibenzoates include steps to reduce or eliminate residual hydroxyl content and improve plasticizer performance by adding acetic anhydride are also disclosed. Propylene glycol adipate and propylene glycol succinate polyesters with benzoic acid end-caps are particularly useful, as are hybrid benzoate/acetate end-capped polyesters formed in the process with acetic anhydride. Caulks, adhesives, sealants, and vinyl compositions comprising the oligomeric end-capped polyesters of the invention are also contemplated.

IPC Classes  ?

  • C08K 5/11 - EstersEther-esters of acyclic polycarboxylic acids
  • C08L 27/06 - Homopolymers or copolymers of vinyl chloride
  • C08K 5/00 - Use of organic ingredients
  • C07C 67/08 - Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
  • C07C 69/78 - Benzoic acid esters
  • C08G 63/12 - Polyesters derived from hydroxy carboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
  • C08G 63/20 - Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
  • C09J 11/06 - Non-macromolecular additives organic
  • C09K 3/10 - Materials not provided for elsewhere for sealing or packing joints or covers
  • C09J 7/24 - PlasticsMetallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds

12.

MONOBENZOATE ANALOGS USEFUL AS PLASTICIZERS IN PLASTISOL COMPOSITIONS

      
Application Number US2015052265
Publication Number 2016/049479
Status In Force
Filing Date 2015-09-25
Publication Date 2016-03-31
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily
  • Roth, Steven D.
  • Andrews, Jerry

Abstract

Unique 3-PPB monobenzoate analogs useful as plasticizers in polymeric dispersions, such as plastisols, melt compounds, and adhesives among other applications. The analogs are structurally similar to and/or derived from 3-phenylpropyl benzoate and heretofore were not known for use in industrial applications, particularly not as a plasticizer in polymeric applications. Depending on the application, the advantages rendered by the use of the inventive monobenzoate analogs include, among other things, excellent solvating properties and rheology, low viscosity and significantly improved viscosity over time, comparable or improved Tg suppression, set and open times, as well as health, safety and environmental advantages, over traditional plasticizers.

IPC Classes  ?

  • C08K 5/101 - EstersEther-esters of monocarboxylic acids
  • C09J 11/06 - Non-macromolecular additives organic
  • C09J 133/08 - Homopolymers or copolymers of acrylic acid esters

13.

Plasticizer blends and plastisol compositions comprised thereof

      
Application Number 14771347
Grant Number 10214628
Status In Force
Filing Date 2014-03-14
First Publication Date 2016-01-21
Grant Date 2019-02-26
Owner Emerald Kalama Chemical, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily
  • Hanes, Rebecca

Abstract

A novel plasticizer blend(s) useful for plastisol compositions, including organisols, having good solvating properties, good viscosity profiles and compatibility with other plasticizers and solvents traditionally used in plastisols, comprising benzoate ester plasticizer(s) and a compatibilizing plasticizer component. Methods for preparing a plastisol having low viscosity and good rheology characteristics and for rendering a benzoate ester plasticizer, or blends thereof, compatible with organic solvents traditionally used in plastisols, by incorporating the novel plasticizer blend(s), which do not require adjusting the solubility parameters of the solvents to accommodate the plasticizer, are disclosed.

IPC Classes  ?

  • C08K 5/103 - EstersEther-esters of monocarboxylic acids with polyalcohols
  • C08K 5/101 - EstersEther-esters of monocarboxylic acids
  • C08J 3/18 - Plasticising macromolecular compounds

14.

POLYESTER PLASTICIZERS WITH BENZOIC ACID END-CAPS

      
Application Number US2015010019
Publication Number 2015/103460
Status In Force
Filing Date 2015-01-02
Publication Date 2015-07-09
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily
  • Roth, Steven D.
  • Hatcher, Eric

Abstract

Polyester plasticizer compositions for adhesives, caulk, sealants, vinyl and other polymeric compositions comprising low molecular weight oligomeric dibenzoates prepared by end-capping a polyester plasticizer, having alternating units of glycols or diols and dibasic acids, with benzoic acid. Methods for preparing oligomeric dibenzoates include steps to reduce or eliminate residual hydroxyl content and improve plasticizer performance by adding acetic anhydride are also disclosed. Propylene glycol adipate and propylene glycol succinate polyesters with benzoic acid end-caps are particularly useful, as are hybrid benzoate/acetate end-capped polyesters formed in the process with acetic anhydride. Caulks, adhesives, sealants, and vinyl compositions comprising the oligomeric end-capped polyesters of the invention are also contemplated.

IPC Classes  ?

15.

POLYESTER PLASTICIZERS WITH BENZOIC ACID END-CAPS

      
Document Number 02935134
Status In Force
Filing Date 2015-01-02
Open to Public Date 2015-07-09
Grant Date 2019-12-03
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily
  • Roth, Steven D.
  • Hatcher, Eric

Abstract

Polyester plasticizer compositions for adhesives, caulk, sealants, vinyl and other polymeric compositions comprising low molecular weight oligomeric dibenzoates prepared by end-capping a polyester plasticizer, having alternating units of glycols or diols and dibasic acids, with benzoic acid. Methods for preparing oligomeric dibenzoates include steps to reduce or eliminate residual hydroxyl content and improve plasticizer performance by adding acetic anhydride are also disclosed. Propylene glycol adipate and propylene glycol succinate polyesters with benzoic acid end-caps are particularly useful, as are hybrid benzoate/acetate end-capped polyesters formed in the process with acetic anhydride. Caulks, adhesives, sealants, and vinyl compositions comprising the oligomeric end-capped polyesters of the invention are also contemplated.

IPC Classes  ?

  • C08J 3/18 - Plasticising macromolecular compounds
  • C08K 5/11 - EstersEther-esters of acyclic polycarboxylic acids

16.

Monobenzoate useful as a plasticizer in plastisol compositions

      
Application Number 14291660
Grant Number 09725573
Status In Force
Filing Date 2014-05-30
First Publication Date 2014-09-18
Grant Date 2017-08-08
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily

Abstract

A unique monobenzoate useful as a plasticizer in polymeric dispersions, such as plastisols and melt compounds. The monobenzoate comprises 3-phenyl propyl benzoate, a benzoate ester heretofore known as a flavoring and fragrance agent, but not previously utilized as a plasticizer in polymeric applications. Depending on the application, the advantages rendered by the use of the inventive monobenzoate include, among other things, excellent solvating properties, low viscosity, viscosity stability, and improved rheology, as well as health, safety and environmental advantages over traditional plasticizers. The monobenzoate may be used alone or in combination with a variety of plasticizers, including but not limited to phthalates, terephthalates, dibenzoates, other monobenzoates, or 1,2-cyclohexane dicarboxylate esters, and mixtures thereof.

IPC Classes  ?

  • C08K 5/101 - EstersEther-esters of monocarboxylic acids
  • C08K 5/00 - Use of organic ingredients
  • C08K 5/12 - EstersEther-esters of cyclic polycarboxylic acids
  • C08L 91/00 - Compositions of oils, fats or waxesCompositions of derivatives thereof
  • C09D 7/12 - Other additives
  • C09D 11/00 - Inks
  • C09J 131/04 - Homopolymers or copolymers of vinyl acetate

17.

NOVEL PLASTICIZER BLENDS AND PLASTISOL COMPOSITIONS COMPRISED THEREOF

      
Application Number US2014028071
Publication Number 2014/143902
Status In Force
Filing Date 2014-03-14
Publication Date 2014-09-18
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily
  • Hanes, Rebecca

Abstract

A novel plasticizer blend(s) useful for plastisol compositions, including organisols, having good solvating properties, good viscosity profiles and compatibility with other plasticizers and solvents traditionally used in plastisols, comprising benzoate ester plasticizer(s) and a compatibilizing plasticizer component. Methods for preparing a plastisol having low viscosity and good rheology characteristics and for rendering a benzoate ester plasticizer, or blends thereof, compatible with organic solvents traditionally used in plastisols, by incorporating the novel plasticizer blend(s), which do not require adjusting the solubility parameters of the solvents to accommodate the plasticizer, are disclosed.

IPC Classes  ?

  • C08J 3/18 - Plasticising macromolecular compounds

18.

Blends of dibenzoate plasticizers

      
Application Number 13976062
Grant Number 09193843
Status In Force
Filing Date 2011-12-28
First Publication Date 2013-10-17
Grant Date 2015-11-24
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily L.

Abstract

Plasticizer blends comprise a triblend of diethylene glycol dibenzoate, dipropylene glycol dibenzoate, and 1,2-propylene glycol dibenzoate, in specified ratios, useful in combination with a multitude of thermoplastic polymers, thermosetting polymers, and elastomeric polymers and numerous applications, including but not limited to plastisols, adhesives, sealants, caulks, architectural coatings, industrial coatings, OEM coatings, inks, overprint varnishes, polishes, and the like. The advantages rendered by the use of the triblend depend on the type of polymer and application in which it is utilized and include among other advantages higher solvating power and lower processing time, low VOC's, reduced plasticizer freeze point, improved gelation and fusion characteristics, higher tensile strength, superior stain and extraction resistance, and improved rheology over traditional diblends of diethylene glycol dibenzoate and dipropylene glycol dibenzoate.

IPC Classes  ?

  • B60C 1/00 - Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
  • C08K 5/06 - EthersAcetalsKetalsOrtho-esters
  • C08K 5/12 - EstersEther-esters of cyclic polycarboxylic acids
  • C09D 7/12 - Other additives
  • C09D 11/03 - Printing inks characterised by features other than the chemical nature of the binder
  • C09J 11/06 - Non-macromolecular additives organic
  • C08K 5/00 - Use of organic ingredients
  • C08K 5/103 - EstersEther-esters of monocarboxylic acids with polyalcohols

19.

Dibenzoate plasticizers/coalescent blends for low VOC coatings

      
Application Number 13976070
Grant Number 09169372
Status In Force
Filing Date 2011-12-28
First Publication Date 2013-10-17
Grant Date 2015-10-27
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily L.

Abstract

A novel, low volatility, non-phthalate plasticizer/coalescent blend for use in paints and other polymeric coatings comprises a triblend of diethylene glycol dibenzoate, dipropylene glycol dibenzoate, and 1,2-propylene glycol dibenzoate. The triblend when used in a paint or other coatings achieves a low VOC paint or coating having stable viscosity after three freeze/thaw cycles and equivalent or superior wet edge/open time ratings, gloss ratings, scrub resistance and block resistance when compared to traditional coalescents, including without limitation high VOC coalescents, low VOC non-dibenzoate coalescents and other dibenzoate blends. The triblend may be used as a substitute or alternative coalescent in latex and acrylic emulsion coatings, among others, to achieve a lower VOC content without sacrificing performance properties.

IPC Classes  ?

  • C08K 5/06 - EthersAcetalsKetalsOrtho-esters
  • C08K 5/12 - EstersEther-esters of cyclic polycarboxylic acids
  • C09D 7/12 - Other additives
  • C09D 11/03 - Printing inks characterised by features other than the chemical nature of the binder
  • C09J 11/06 - Non-macromolecular additives organic
  • C08K 5/00 - Use of organic ingredients
  • C08K 5/103 - EstersEther-esters of monocarboxylic acids with polyalcohols

20.

MONOBENZOATE USEFUL AS A PLASTICIZER/COALESCENT IN POLYMERIC DISPERSIONS

      
Application Number US2013026083
Publication Number 2013/123149
Status In Force
Filing Date 2013-02-14
Publication Date 2013-08-22
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily

Abstract

A unique monobenzoate useful as a plasticizer or coalescent for polymeric dispersions, including without limitation architectural and other coatings., paints, OEM coatings, special purpose coatings overprint varnishes, inks, nail polish, floor polishes and the like. The monobenzoate comprises 3-pheny propyl benzoate, a benzoate ester previously known as a flavoring and fragrance agent, but not previously utilized as a plasticizer or coalescent in polymeric applications. The inventive monobenzoate provides a suitable non- phthalate, lower VOC content alternative plasticizer or coalescent that is compatible with a wide variety of polymers.

IPC Classes  ?

  • B05D 1/02 - Processes for applying liquids or other fluent materials performed by spraying
  • C08K 5/00 - Use of organic ingredients

21.

MONOBENZOATE USEFUL AS A PLASTICIZER IN ADHESIVE PREPARATIONS

      
Application Number US2013026137
Publication Number 2013/123188
Status In Force
Filing Date 2013-02-14
Publication Date 2013-08-22
Owner EMERALD KALAMA CHEMICAL, LLC. (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily

Abstract

A unique monobenzoate useful as a plasticizer in polymeric dispersions, such as adhesives, comprising 3-phenyl propyl benzoate, a monobenzoate ester used as a flavor and fragrance additive, but not heretofore utilized as a plasticizer for polymeric dispersions, such as adhesives, caulks and sealants. The inventive monobenzoate provides a suitable non-phthalate, lower VOC alternative plasticizer that is compatible with a wide variety of polymers. Advantages rendered by the use of the inventive monobenzoate include, among other things, excellent viscosity response, low viscosity, viscosity stability, improved rheology, good film formation and comparable or better adhesion, peel strength, set time, open time, chalk point and MFFT, compared with that achieved by traditional plasticizers. The inventive monobenzoate also has an excellent health, safety and environmental profile and provides a viable alternative for adhesives used in food contact applications, such as packaging, where migratory concerns are an issue.

IPC Classes  ?

  • C07C 69/74 - Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
  • C08K 5/09 - Carboxylic acidsMetal salts thereofAnhydrides thereof

22.

MONOBENZOATE USEFUL AS A PLASTICIZER IN PLASTISOL COMPOSITIONS

      
Document Number 02863431
Status In Force
Filing Date 2013-02-14
Open to Public Date 2013-08-22
Grant Date 2017-03-21
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily

Abstract

A unique monobenzoate useful as a plasticizer in polymeric dispersions, such as plastisols and melt compounds. The monobenzoate comprises 3-phenyl propyl benzoate, a benzoate ester heretofore known as a flavoring and fragrance agent, but not previously utilized as a plasticizer in polymeric applications. Depending on the application, the advantages rendered by the use of the inventive monobenzoate include, among other things, excellent solvating properties, low viscosity, viscosity stability, and improved rheology, as well as health, safety and environmental advantages over traditional plasticizers.

IPC Classes  ?

  • C08J 3/18 - Plasticising macromolecular compounds
  • C08K 5/101 - EstersEther-esters of monocarboxylic acids

23.

MONOBENZOATE USEFUL AS A PLASTICIZER IN PLASTISOL COMPOSITIONS

      
Application Number US2013026049
Publication Number 2013/123127
Status In Force
Filing Date 2013-02-14
Publication Date 2013-08-22
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily

Abstract

A unique monobenzoate useful as a plasticizer in polymeric dispersions, such as plastisols and melt compounds. The monobenzoate comprises 3-phenyl propyl benzoate, a benzoate ester heretofore known as a flavoring and fragrance agent, but not previously utilized as a plasticizer in polymeric applications. Depending on the application, the advantages rendered by the use of the inventive monobenzoate include, among other things, excellent solvating properties, low viscosity, viscosity stability, and improved rheology, as well as health, safety and environmental advantages over traditional plasticizers.

IPC Classes  ?

24.

BLENDS OF DIBENZOATE PLASTICIZERS

      
Document Number 02823204
Status In Force
Filing Date 2011-12-28
Open to Public Date 2012-07-05
Grant Date 2015-11-24
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily

Abstract

Plasticizer blends comprise a triblend of diethylene glycol dibenzoate, dipropylene glycol dibenzoate, and 1, 2-propylene glycol dibenzoate, in specified ratios, useful in combination with a multitude of thermoplastic polymers, thermosetting polymers, and elastomeric polymers and numerous applications, including but not limited to plastisols, adhesives, sealants, caulks, architectural coatings, industrial coatings, OEM coatings, inks, overprint varnishes, polishes, and the like. The advantages rendered by the use of the triblend depend on the type of polymer and application in which it is utilized and include among other advantages higher solvating power and lower processing time, low VOC's, reduced plasticizer freeze point, improved gelation and fusion characteristics, higher tensile strength, superior stain and extraction resistance, and improved rheology over traditional diblends of diethylene glycol dibenzoate and dipropylene glycol dibenzoate.

IPC Classes  ?

  • C08J 3/18 - Plasticising macromolecular compounds
  • C08K 5/103 - EstersEther-esters of monocarboxylic acids with polyalcohols
  • C09D 11/03 - Printing inks characterised by features other than the chemical nature of the binder
  • C09J 11/06 - Non-macromolecular additives organic
  • C09K 3/10 - Materials not provided for elsewhere for sealing or packing joints or covers

25.

NEW DIBENZOATE PLASTICIZER/COALESCENT BLENDS FOR LOW VOC COATINGS

      
Document Number 02823206
Status In Force
Filing Date 2011-12-28
Open to Public Date 2012-07-05
Grant Date 2016-05-24
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily

Abstract

A novel, low volatility, non-phthalate plasticizer/coalescent blend for use in paints and other polymeric coatings comprises a triblend of diethylene glycol dibenzoate, dipropylene glycol dibenzoate, and 1,2-propylene glycol dibenzoate. The triblend when used in a paint or other coatings achieves a low VOC paint or coating having stable viscosity after three freeze/thaw cycles and equivalent or superior wet edge/open time ratings, gloss ratings, scrub resistance and block resistance when compared to traditional coalescents, including without limitation high VOC coalescents, low VOC non-dibenzoate coalescents and other dibenzoate blends. The triblend may be used as a substitute or alternative coalescent in latex and acrylic emulsion coatings, among others, to achieve a lower VOC content without sacrificing performance properties.

IPC Classes  ?

  • C09D 5/02 - Emulsion paints
  • C09D 101/00 - Coating compositions based on cellulose, modified cellulose, or cellulose derivatives

26.

BLENDS OF DIBENZOATE PLASTICIZERS

      
Application Number US2011067572
Publication Number 2012/092366
Status In Force
Filing Date 2011-12-28
Publication Date 2012-07-05
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily

Abstract

Plasticizer blends comprise a triblend of diethylene glycol dibenzoate, dipropylene glycol dibenzoate, and 1, 2-propylene glycol dibenzoate, in specified ratios, useful in combination with a multitude of thermoplastic polymers, thermosetting polymers, and elastomeric polymers and numerous applications, including but not limited to plastisols, adhesives, sealants, caulks, architectural coatings, industrial coatings, OEM coatings, inks, overprint varnishes, polishes, and the like. The advantages rendered by the use of the triblend depend on the type of polymer and application in which it is utilized and include among other advantages higher solvating power and lower processing time, low VOC's, reduced plasticizer freeze point, improved gelation and fusion characteristics, higher tensile strength, superior stain and extraction resistance, and improved rheology over traditional diblends of diethylene glycol dibenzoate and dipropylene glycol dibenzoate.

IPC Classes  ?

  • B60C 1/00 - Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition

27.

NEW DIBENZOATE PLASTICIZER/COALESCENT BLENDS FOR LOW VOC COATINGS

      
Application Number US2011067584
Publication Number 2012/092370
Status In Force
Filing Date 2011-12-28
Publication Date 2012-07-05
Owner EMERALD KALAMA CHEMICAL, LLC (USA)
Inventor
  • Arendt, William D.
  • Mcbride, Emily

Abstract

A novel, low volatility, non-phthalate plasticizer/coalescent blend for use in paints and other polymeric coatings comprises a triblend of diethylene glycol dibenzoate, dipropylene glycol dibenzoate, and 1,2-propylene glycol dibenzoate. The triblend when used in a paint or other coatings achieves a low VOC paint or coating having stable viscosity after three freeze/thaw cycles and equivalent or superior wet edge/open time ratings, gloss ratings, scrub resistance and block resistance when compared to traditional coalescents, including without limitation high VOC coalescents, low VOC non-dibenzoate coalescents and other dibenzoate blends. The triblend may be used as a substitute or alternative coalescent in latex and acrylic emulsion coatings, among others, to achieve a lower VOC content without sacrificing performance properties.

IPC Classes  ?