A method of forming a three-dimensional object is carried out by providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; filling the build region with a polymerizable liquid; irradiating the build region through the optically transparent member to form a solid polymer from the polymerizable liquid and advancing the carrier away from the build surface to form the three-dimensional object from the solid polymer, while also concurrently with the irradiating and/or advancing steps: (i) continuously maintaining a dead zone of polymerizable liquid in contact with the build surface, and (ii) continuously maintaining a gradient of polymerization zone between the dead zone and the solid polymer and in contact with each thereof. The gradient of polymerization zone comprises the polymerizable liquid in partially cured form (e.g., so that the formation of fault or cleavage lines between layers of solid polymer in the three-dimensional object is reduced). Apparatus for carrying out the method is also described.
A61B 90/00 - Instruments, implements or accessories specially adapted for surgery or diagnosis and not covered by any of the groups , e.g. for luxation treatment or for protecting wound edges
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
Provided are dual cure resin compositions useful for additive manufacturing that include an elastomer-producing light polymerizable monomer and/or prepolymer; a monomer and/or prepolymer that is solidified by exposure to heat, microwave irradiation, and/or moisture; a photoinitiator; optionally, one or more additional light polymerizable monomers and/or prepolymers; and optionally, a thiol crosslinker. Methods of forming a polymer and/or three-dimensional object with the resin, and polymers and/or three-dimensional objects produced are also described.
C09J 179/04 - Polycondensates having nitrogen-containing heterocyclic rings in the main chainPolyhydrazidesPolyamide acids or similar polyimide precursors
C09J 115/00 - Adhesives based on rubber derivatives
C08K 5/53 - Phosphorus bound to oxygen bound to oxygen and to carbon only
B29C 64/00 - Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
3.
BRANCHED REACTIVE BLOCKED PREPOLYMERS FOR ADDITIVE MANUFACTURING
Provided according to some embodiments is a polymerizable liquid useful for the production of a three-dimensional object comprised of polyurethane, polyurea, or a copolymer thereof by additive manufacturing, the polymerizable liquid comprising a mixture of: (a) a first blocked or reactive blocked prepolymer comprising a compound of the formula X(A)n, where X is a hydrocarbyl group, n is at least 3, and each A is an independently selected substituent of Formula I:
Provided according to some embodiments is a polymerizable liquid useful for the production of a three-dimensional object comprised of polyurethane, polyurea, or a copolymer thereof by additive manufacturing, the polymerizable liquid comprising a mixture of: (a) a first blocked or reactive blocked prepolymer comprising a compound of the formula X(A)n, where X is a hydrocarbyl group, n is at least 3, and each A is an independently selected substituent of Formula I:
Provided according to some embodiments is a polymerizable liquid useful for the production of a three-dimensional object comprised of polyurethane, polyurea, or a copolymer thereof by additive manufacturing, the polymerizable liquid comprising a mixture of: (a) a first blocked or reactive blocked prepolymer comprising a compound of the formula X(A)n, where X is a hydrocarbyl group, n is at least 3, and each A is an independently selected substituent of Formula I:
where R is a hydrocarbyl group, R′is O or NH, and Z is a blocking group; (b) a polyol and/or polyamine chain extender; (c) optionally a reactive diluent; and (d) a photoinitiator. A method of use of the polymerizable liquid to make a three-dimensional object by additive manufacturing and prepolymer compounds useful for the same are also provided.
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
B33Y 70/00 - Materials specially adapted for additive manufacturing
B33Y 80/00 - Products made by additive manufacturing
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
Provided herein is a resin composition useful for the production of a three-dimensional object by additive manufacturing, said resin composition including one or more of: (a) a reactive blocked prepolymer including at least one ether subunit; (b) a multifunctional amine chain extender including at least one amide subunit; (c) a photoinitiator; and (d) optionally, a reactive and/or non-reactive diluent. Methods of forming a three-dimensional object with the resin composition and three-dimensional objects formed from the resin composition are also provided.
B29C 64/00 - Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
C08G 18/81 - Unsaturated isocyanates or isothiocyanates
C08G 69/40 - Polyamides containing oxygen in the form of ether groups
C08G 81/00 - Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfacesMaterials therefor, e.g. comprising photoresistsApparatus specially adapted therefor
5.
RESINS INCLUDING COVALENTLY BOUND FILLERS AND METHODS OF USING THE SAME IN ADDITIVE MANUFACTURING
Resin compositions are provided for producing a three-dimensional object by additive manufacturing that include at least one reactive compound having a filler moiety covalently attached (bonded) thereto. In some embodiments, the reactive compound may be a monomer, a prepolymer, a chain extender, and/or a reactive diluent. In certain embodiments, more than one type of reactive compound may include a filler moiety covalently attached thereto.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
09 - Scientific and electric apparatus and instruments
12 - Land, air and water vehicles; parts of land vehicles
17 - Rubber and plastic; packing and insulating materials
20 - Furniture and decorative products
25 - Clothing; footwear; headgear
Goods & Services
Helmets. Bicycle and motorcycle saddles; wheelchair cushions;
automobile cushions. Compressible 3-D printed lattices having foam-like
properties for use with helmets, footwear including insoles,
bicycle and motorcycle saddles, seat cushions, and
wheelchair cushions (terms considered too vague by the
International Bureau - Rule 13 (2) (b) of the Regulations). Seat cushions. Footwear including insoles.
7.
HOLLOW DENTAL MOLDS CONFIGURED FOR HIGH THROUGHPUT CLEANING
A method of making a dental appliance thermoforming mold, includes the steps of: (a) providing initial object image data representing a mold in the shape of a dental arch; (b) generating drain channel data, drain channel instructions, or a combination thereof; (c) optionally generating a hollow cavity in the initial object image data if not previously present therein; and (d) combining the initial object image data with the drain channel data, drain channel instructions, or combination thereof to create a modified object image data representing the mold, with the mold now further including: a plurality of drain channels extending from the hollow cavity upward through the upper portion configured for draining of residual polymerizable resin from the hollow cavity.
An additively manufactured product comprises a lattice including repeating unit cells, the repeating unit cells including a hybrid surface lattice unit cell, the hybrid surface lattice unit cell having a configuration represented by an interpolation of a first and second surface lattice unit cell, the hybrid surface lattice unit cell having a characteristic tensile and/or mechanical property (e.g., stiffness, energy absorption, energy return, resilience, toughness) along a predefined axis therein not achieved by either said first or second surface lattice unit cell when formed from the same material as said hybrid surface lattice unit cell.
B33Y 50/00 - Data acquisition or data processing for additive manufacturing
B33Y 80/00 - Products made by additive manufacturing
F16F 9/30 - Springs, vibration-dampers, shock-absorbers, or similarly-constructed movement-dampers using a fluid or the equivalent as damping medium with solid or semi-solid material, e.g. pasty masses, as damping medium
9.
SUSTAINABLE ADDITIVE MANUFACTURING RESINS AND METHODS OF RECYCLING
Provided herein are methods of recycling additively manufactured objects (e.g., stereolithographically produced objects), the additively manufactured objects comprising linear polyurethane, branched polyurethane, linear polyurea, branched polyurea, a copolymer thereof, or a combination thereof. Compositions comprising the same and methods of use thereof are also provided.
A method of forming a three-dimensional object is carried out by providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; filling the build region with a polymerizable liquid; irradiating the build region through the optically transparent member to form a solid polymer from the polymerizable liquid and advancing the carrier away from the build surface to form the three-dimensional object from the solid polymer, while also concurrently with the irradiating and/or advancing steps: (i) continuously maintaining a dead zone of polymerizable liquid in contact with the build surface, and (ii) continuously maintaining a gradient of polymerization zone between the dead zone and the solid polymer and in contact with each thereof. The gradient of polymerization zone comprises the polymerizable liquid in partially cured form (e.g., so that the formation of fault or cleavage lines between layers of solid polymer in the three-dimensional object is reduced). Apparatus for carrying out the method is also described.
A61M 29/02 - Inflatable dilatorsDilators made of swellable materials
A61B 90/00 - Instruments, implements or accessories specially adapted for surgery or diagnosis and not covered by any of the groups , e.g. for luxation treatment or for protecting wound edges
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
Provided according to embodiments of the invention are methods of method of making a three-dimensional object by additive manufacturing that include exposing excess material (13a) on a three-dimensional object to an ablation/laser light (42) at a dosage sufficient to remove said excess material; exposing a build surface of a three-dimensional object to an ablation/laser light to physically and/ or chemically modify the build surface; and/or exposing a portion of a resin coated film to ablation/laser light sufficient to eject resin onto a bottom surface of the three-dimensional object. Related apparatuses are also provided.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/188 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
B29C 64/268 - Arrangements for irradiation using laser beamsArrangements for irradiation using electron beams [EB]
Three-dimensional (3D) lattice objects with multiple zones of different lattice unit cells may be formed by additive manufacturing. Sets of primary unit cells are provided such that cach primary unit cell is configured to smoothly transition to other primary unit cells through a series of intermediate unit cells. A universal unit cell may define the primary and intermediate unit cells.
Described herein is a mold in the shape of a dental arch produced by additive manufacturing from a polymerizable resin. The mold includes: an upper portion configured in the shape of a set of teeth; an intermediate portion having a hollow cavity formed therein; a planar base surface portion, the hollow cavity extending through the base surface portion; and a plurality of drain channels extending from the hollow cavity upward through the upper portion, the drain channels configured for draining of residual polymerizable resin from the hollow cavity.
A method of making a plurality of polymer dental appliances, including the steps of: (a) additively manufacturing a plurality of hollow molds from a polymerizable resin, each mold having an external surface portion configured in the shape of a dental arch and a bottom portion having a hollow cavity therein, and with the additively manufacturing step carried out with the plurality of hollow molds formed on a build platform; (b) centrifugally separating residual resin from both the external surface portion and the bottom portion (including the hollow cavity) of each mold; (c) further curing, concurrently or sequentially, the external surface portion and the bottom portion of each mold with ultraviolet light; then (d) thermoforming a thermoplastic polymer sheet on each hollow mold external surface portion to produce the plurality of polymer dental appliances; and (e) separating the plurality of polymer dental appliances from the plurality of hollow molds.
B29C 33/38 - Moulds or coresDetails thereof or accessories therefor characterised by the material or the manufacturing process
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/194 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control during lay-up
Provided according to embodiments of the invention are methods for the rapid production of a composition that includes a reactive blocked prepolymer. Such methods may include continuously mixing a first precursor composition and a second precursor composition, the first precursor composition including a polyisocyanate oligomer and the second precursor composition including an amine (meth)acrylate to produce the composition that includes a reactive blocked prepolymer.
09 - Scientific and electric apparatus and instruments
12 - Land, air and water vehicles; parts of land vehicles
17 - Rubber and plastic; packing and insulating materials
20 - Furniture and decorative products
25 - Clothing; footwear; headgear
Goods & Services
(1) Helmets.
(2) Bicycle and motorcycle saddles; wheelchair cushions; automobile cushions.
(3) Compressible 3-D printed lattices having foam-like properties for use with helmets, footwear including insoles, bicycle and motorcycle saddles, seat cushions, and wheelchair cushions (terms considered too vague by the International Bureau - Rule 13 (2) (b) of the Regulations).
(4) Seat cushions.
(5) Footwear including insoles.
17.
ONE PART, CATALYST CONTAINING, MOISTURE CURABLE DUAL CURE RESINS FOR ADDITIVE MANUFACTURING
Provided is method of making a three-dimensional object comprising polyurea, which may include: (a) dispensing a one part (1K) dual cure resin into a stereolithography apparatus, the resin comprising or consisting essentially of a photoinitiator, a reactive blocked polyisocyanate, optionally a catalyst such as a polyurethane blowing catalyst, and optionally a polyepoxide; (b) additively manufacturing from said resin an intermediate object comprising the light polymerization product of said reactive blocked polyisocyanate; (c) optionally cleaning said intermediate object; and (d) reacting said polymerization product in said intermediate with water in the presence of a catalyst such as a polyurethane blowing catalyst (which may be included in the resin, the water, or both) to generate polyamine in situ that sequentially reacts with the remainder of the polymerization product to form urea linkages and thereby produce a three-dimensional object comprising polyurea. Dual cure resins useful for the method are also provided.
09 - Scientific and electric apparatus and instruments
12 - Land, air and water vehicles; parts of land vehicles
19 - Non-metallic building materials
20 - Furniture and decorative products
Goods & Services
Footwear containing insoles Safety and protective helmets Bicycle and motorcycle saddles; wheelchair cushions; automobile seat cushions Compressible 3-D printed polymer lattices having foam-like properties for use with helmets, footwear including insoles, bicycle and motorcycle saddles, seat cushions, and wheelchair cushions Seat cushions
A method of separating excess resin from at least one object, includes: (a) stereolithographically producing at least one object on at least one carrier platform, each carrier platform having a planar build surface to which at least one object is connected, each object carrying excess resin on a surface thereof; then (b) mounting each carrier platform to a rotor; (c) centrifugally separating excess resin from each object by spinning the rotor with each carrier platform connected thereto while each object remains connected to each carrier platform; and then (d) removing each carrier platform from the rotor with each object thereon, with excess resin separated therefrom.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid comprising a mixture of: (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the second solidifiable component; and then (d) solidifying and/or curing the second solidifiable component to form from said three-dimensional intermediate the three-dimensional object.
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
B29C 35/08 - Heating or curing, e.g. crosslinking or vulcanising by wave energy or particle radiation
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
B29C 64/255 - Enclosures for the building material, e.g. powder containers
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfacesMaterials therefor, e.g. comprising photoresistsApparatus specially adapted therefor
G03F 7/027 - Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
G03F 7/038 - Macromolecular compounds which are rendered insoluble or differentially wettable
In some embodiments, a method of determining the fill level of a resin pool in a bottom-up additive manufacturing apparatus includes the steps of: (a) providing an additive manufacturing apparatus including a build platform and a light transmissive window, the build platform and the window defining a build region there between, with the window carrying a resin pool, the pool having a resin top surface portion; (b) advancing the build platform and the window towards one another until the build platform contacts the resin top surface portion; (c) detecting the impact of the build platform with the resin top surface portion; and (d) determining the fill level of the resin pool from the detected impact.
An additively manufactured lattice structure includes (a) a first three-dimensional lattice including a repeating interconnected array of a first lattice unit cell, (b) a second three-dimensional lattice including a repeating interconnected array of a second lattice unit cell, wherein the second lattice unit cell is different from the first lattice unit cell, and (c) a first transition segment interconnecting the first three-dimensional lattice and the second three-dimensional lattice. The first transition segment includes (i) a first three-dimensional transitional lattice including a repeating array of the first lattice unit cell and (ii) interleaved with and interconnected to the first three-dimensional transitional lattice, a second three-dimensional transitional lattice including a repeating array of the second lattice unit cell.
Described herein are methods, systems and apparatus (including associated control methods, systems and apparatus), for the production of a three-dimensional object by “bottom up” additive manufacturing, in which a carrier is vertically reciprocated with respect to a build surface, to enhance or speed the refilling of the build region with a solidifiable liquid. In preferred (but not necessarily limiting) embodiments, the three-dimensional object is produced from a liquid interface by continuous liquid interface production (i.e., “CLIP”).
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A method of forming a three-dimensional object is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
B29C 35/08 - Heating or curing, e.g. crosslinking or vulcanising by wave energy or particle radiation
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
B29C 64/255 - Enclosures for the building material, e.g. powder containers
C08G 18/73 - Polyisocyanates or polyisothiocyanates acyclic
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C08G 18/76 - Polyisocyanates or polyisothiocyanates cyclic aromatic
C08G 18/81 - Unsaturated isocyanates or isothiocyanates
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
C08J 5/00 - Manufacture of articles or shaped materials containing macromolecular substances
C08K 3/01 - Use of inorganic substances as compounding ingredients characterised by their specific function
C08K 3/013 - Fillers, pigments or reinforcing additives
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfacesMaterials therefor, e.g. comprising photoresistsApparatus specially adapted therefor
G03F 7/027 - Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
G03F 7/038 - Macromolecular compounds which are rendered insoluble or differentially wettable
A method of forming a three-dimensional object (31) includes the steps of: (a) providing an apparatus including a carrier (15), a light transmissive window (12) having a build surface, polymerizable liquid (21) on the build surface, and a growing object (31) on the carrier, the growing object produced by light polymerization of the polymerizable liquid; (b) vertically reciprocating the carrier (15) with respect to the build surface in an upstroke and a downstroke, the downstroke being shorter than the upstroke, to form a build region between the growing object and the build surface, and to fill the build region with the polymerizable liquid, while also: (i) sensing force exerted between the carrier and the build surface through the growing object (31) and the polymerizable liquid (21) during the upstroke; and (ii) modifying the speed, acceleration, or both speed and acceleration of the upstroke in response to the sensed force so that the sensed force approaches a predetermined target force; then (c) irradiating the build region with light through the light transmissive window to form a new portion of the object from the polymerizable liquid on the growing object; and then (d) repeating steps (b) through (c) to form additional portions on the growing object until the three-dimensional object is formed.
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/232 - Driving means for motion along the axis orthogonal to the plane of a layer
Apparatus for, and associated method of, making a three-dimensional object from a light polymerizable resin by inkjet additive manufacturing are described. The methods and apparatus employ dual precursor resins, including but not limited to dual cure resins having a first component photopolymerizable and a second component polymerizable by a mechanism different from the first component.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
A method of enhancing a performance characteristic of an additive manufacturing apparatus, the method including:
(a) dispensing a batch of a light polymerizable resin into the additive manufacturing apparatus, the batch characterized by at least one physical characteristic;
(b) determining the unique identity of the batch;
(c) sending the unique identity of the batch to a database; then
(d) either: (i) receiving on the controller from the database modified operating instructions for the resin batch, which modified operating instructions have been modified based on the at least one physical characteristic, or (ii) receiving on the controller from the database the at least one physical characteristic for the specific resin batch and modifying the operating instructions based on the at least one physical characteristic; and then
(e) producing the object from the batch of light polymerizable resin on the additive manufacturing apparatus with the modified operating instructions.
A method of forming a three-dimensional object, is carried out by (a) providing a carrier and a build plate, the build plate comprising a semipermeable member, the semipermeable member comprising a build surface with the build surface and the carrier defining a build region therebetween, and with the build surface in fluid communication by way of the semipermeable member with a source of polymerization inhibitor; (b) filling the build region with a polymerizable liquid, the polymerizable liquid contacting the build surface, (c) irradiating the build region through the build plate to produce a solid polymerized region in the build region, while forming or maintaining a liquid film release layer comprised of the polymerizable liquid formed between the solid polymerized region and the build surface, wherein the polymerization of which liquid film is inhibited by the polymerization inhibitor; and (d) advancing the carrier with the polymerized region adhered thereto away from the build surface on the build plate to create a subsequent build region between the polymerized region and the build surface while concurrently filling the subsequent build region with polymerizable liquid as in step (b). Apparatus for carrying out the method is also described.
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B29C 35/08 - Heating or curing, e.g. crosslinking or vulcanising by wave energy or particle radiation
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfacesMaterials therefor, e.g. comprising photoresistsApparatus specially adapted therefor
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
A61M 37/00 - Other apparatus for introducing media into the bodyPercutany, i.e. introducing medicines into the body by diffusion through the skin
A61F 2/82 - Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
B33Y 80/00 - Products made by additive manufacturing
B33Y 30/00 - Apparatus for additive manufacturingDetails thereof or accessories therefor
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
29.
METHOD FOR DIRECT COLORATION OF RESINS FOR ADDITIVE MANUFACTURING
(a) (b) (i) (ii) (iii) (iv) (c) (c) mixing, in a second apparatus, the colored resin concentrate with a second portion of the bulk supply, to produce the pigmented additive manufacturing resin having the predefined color.
B29B 7/08 - MixingKneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices shaking, oscillating or vibrating
B29B 7/10 - MixingKneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary
B29B 7/32 - MixingKneading continuous, with mechanical mixing or kneading devices with non-movable mixing or kneading devices
B29B 7/42 - MixingKneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with screw or helix
B29B 7/48 - MixingKneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
B29C 64/00 - Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
30.
HOLLOW DENTAL MOLDS CONFIGURED FOR HIGH THROUGHPUT CLEANING
Described herein is a mold in the shape of a dental arch produced by additive manufacturing from a polymerizable resin. The mold includes: an upper portion configured in the shape of a set of teeth; an intermediate portion having a hollow cavity formed therein; a planar base surface portion, the hollow cavity extending through the base surface portion; and a plurality of drain channels extending from the hollow cavity upward through the upper portion, the drain channels configured for draining of residual polymerizable resin from the hollow cavity.
A centrifugal separator for separating residual resin from additively manufactured objects, the objects carried on a build surface of a build platform on which the objects were additively manufactured. The separator includes: an outer vessel; a rotor in the vessel, the rotor defining a center axis of rotation; a drive assembly operatively associated with the rotor; and a plurality of build platform mount assemblies operatively associated with the rotor, each mount assembly configured to receive one of the build platforms in (i) a first orientation in which the build surfaces face toward the axis of rotation, and (ii) a second orientation in which the build surfaces face away from the axis of rotation.
A method of cleaning residual resin from an additively manufactured object, the method including: producing by additive manufacturing at least one object on at least one carrier platform, each object including a light polymerized resin with a surface coating of viscous, unpolymerized residual resin; operatively connecting each object to a rotor; separating the residual resin from each object; and removing the at least one object from the rotor with the residual resin separated therefrom. The separating step may include: centrifugally separating the residual resin from each object by spinning the rotor with the at least object operatively connected thereto; and rotating (or tilting) each object about at least one axis during the spinning to enhance the centrifugally separating the residual resin from each object.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 71/00 - After-treatment of articles without altering their shapeApparatus therefor
33.
LIGHT SOURCE VARIABILITY CORRECTION IN ADDITIVE MANUFACTURING
A method of reducing performance deviation in at least one additive manufacturing apparatus during production of parts is provided. Each apparatus has a light source configured for polymerizing a light polymerizable resin with sequential doses of patterned light to produce a 3D object. The light source has an assigned nominal emission data, such as an expected or preset standard emission data, and actual emission data. The method includes modifying at least some of said light doses in said at least one apparatus during production of parts therein to compensate for a deviation of said actual light source emission data from the assigned nominal emission data.
B29C 64/282 - Arrangements for irradiation using multiple radiation means, e.g. micromirrors or multiple light-emitting diodes [LED] of the same type, e.g. using different energy levels
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
The present disclosure describes a polymer mouthguard for protecting the teeth of a wearer. The mouthguard includes a lingual portion, a facial portion, and an occlusal portion connected with one another in the shape of an arch and together defining a trough for receiving the upper (maxillary) or lower (mandibular) teeth of a wearer. At least one, or both, of the facial portion and the occlusal portion have a shock absorbing lattice formed therein. The mouthguard can be produced as a single object by the process of additive manufacturing (e.g., stereolithography).
Provided is method of making a three-dimensional object comprising polyurea, which may include: (a) dispensing a one part (1K) dual cure resin into a stereolithography apparatus, the resin comprising or consisting essentially of a photoinitiator, a reactive blocked polyisocyanate, optionally a catalyst such as a polyurethane blowing catalyst, and optionally a polyepoxide; (b) additively manufacturing from said resin an intermediate object comprising the light polymerization product of said reactive blocked polyisocyanate; (c) optionally cleaning said intermediate object; and (d) reacting said polymerization product in said intermediate with water in the presence of a catalyst such as a polyurethane blowing catalyst (which may be included in the resin, the water, or both) to generate polyamine in situ that sequentially reacts with the remainder of the polymerization product to form urea linkages and thereby produce a three-dimensional object comprising polyurea. Dual cure resins useful for the method are also provided.
The present disclosure describes a method of making a composite product (20) by additive manufacturing. The method includes providing an additive manufacturing apparatus having a build platform, the build platform having a planar face on which the product is formed; securing a fabric (22) sheet to the planar face (11) to provide a planar fabric surface thereon; additively manufacturing an intermediate object on the planar fabric surface in the apparatus (12) by light polymerizing a dual cure resin to produce an intermediate object on the build platform, the intermediate object including the fabric (22) sheet having the three-dimensional object (21) adhered thereto; and concurrently with or following the additively manufacturing step, further curing the intermediate object to produce a composite object including the fabric sheet having the three-dimensional object adhered thereto. Composite object and products are also described herein.
B33Y 70/10 - Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A method of additively manufacturing a plurality of parts in a manner that facilitates efficient collection of metrology data on the parts is described herein. The method includes the steps of: additively manufacturing a construct, the construct comprising: (i) a backing, and (ii) a plurality of parts connected to the backing; inserting the backing into an imaging apparatus in an orientation in which the plurality of parts are positioned for imaging; then imaging the plurality parts in the imaging apparatus to collect image data from each part, and then removing the construct from the imaging apparatus and separating the parts from the backing.
G01N 23/046 - Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups , or by transmitting the radiation through the material and forming images of the material using tomography, e.g. computed tomography [CT]
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
G01N 23/083 - Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups , or by transmitting the radiation through the material and measuring the absorption the radiation being X-rays
38.
ADDITIVE MANUFACTURING FROM A VELOCITY INDUCED DEAD ZONE
Methods of making a three-dimensional object from a light polymerizable resin are described. A method may include: (a) providing a window, a light polymerizable resin, a laterally translatable substrate between said window and said resin to which said resin is adhered, and a carrier platform above said window; (b) irradiating said resin with light through said window and said translatable substrate, and vertically advancing said carrier away from said window, to produce a growing object on said carrier platform and consume resin beneath said growing object; and (c) laterally advancing said translatable substrate with said resin adhered thereto across said window to drag fresh resin beneath said growing object, continue producing said growing object and continue consuming fresh resin, until said three-dimensional object is produced.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
Provided herein according to some embodiments is a dual cure stereolithography resin that includes a Diels-Alder adduct, which adduct is light polymerizable in the first, light, cure to produce an intermediate object, and on heating the intermediate object yields a bis-maleimide that can further react and/or polymerize during the second, heat, cure.
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08L 69/00 - Compositions of polycarbonatesCompositions of derivatives of polycarbonates
C08L 79/08 - PolyimidesPolyester-imidesPolyamide-imidesPolyamide acids or similar polyimide precursors
Provided herein is a method of recycling reactive prepolymers from additively manufactured articles or recovered coating material that comprises a crosslinked polymer formed from a single-cure resin comprising a reactive blocked prepolymer and a crosslinker, by forming and recovering a regenerated reactive prepolymer. Light-polymerizable resins, methods of making recyclable objects from such resins, and methods for sustainable manufacturing are also provided.
C08J 11/08 - Recovery or working-up of waste materials of polymers without chemical reactions using selective solvents for polymer components
C08J 11/18 - Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
41.
SYSTEMS AND METHODS FOR ADDITIVELY MANUFACTURING SEMI-CUSTOM OBJECTS
A computer-implemented method of making a semi-custom product for a user, includes the steps of: (a) providing a set of data files, each data file representing a distinct variant of the product; (b) providing personal data from the user, the personal data including at least first and second distinct user attributes; (c) providing product preference data from the user, the product preference data including at least first and second distinct product attributes; and then (d) ranking the set of data files with (i) the personal data and (ii) the product preference data to identify a best fit data file, the best fit data file representing a variant of the product that most closely meets the product preference data based on the personal data.
Provided herein is an additive manufacturing method of making a three-dimensional object comprising polyurea, comprising: (a) dispensing a one part (1K) dual cure resin into a stereolithography apparatus, the resin comprising or consisting essentially of a photoinitiator, a reactive blocked polyisocyanate, and optionally a polyepoxide, the reactive blocked polyisocyanate comprising the reaction product of a polyisocyanate and an amine or hydroxyl (meth)acrylate or (meth)acrylamide monomer blocking agent; (b) additively manufacturing from said resin an intermediate object comprising the light polymerization product of said reactive blocked polyisocyanate; (c) optionally cleaning said intermediate object; and (d) reacting said polymerization product in said intermediate with water to generate polyamine in situ that sequentially reacts with the remainder of the polymerization product to form urea linkages and hereby produce a three-dimensional object comprising polyurea. One part (1K) dual cure resins useful for the method are also provided.
B29C 64/112 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
The present invention concerns methods of forming a three-dimensional object, and polymerizable liquids such as dual cure resins useful for making a three-dimensional object by sterolithography, such as by continuous liquid interface production (CLIP).
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
Provided herein is a method of making a three-dimensional object (31) by bottom-up additive manufacturing, which method may include: providing a carrier platform (14), a light source (13), and a light transmissive window (11) therebetween, the light transmissive window comprising a gas permeable member having a top surface and a bottom surface; depositing a liquid resin (21) on the window, the resin comprising a cyclic olefin monomer and a ring-opening metathesis polymerization (ROMP) photocatalyst; contacting a gas to said gas permeable member bottom surface; and exposing said resin to light from said light source while advancing aid carrier platform away from said window to form said three-dimensional object on said carrier platform. An apparatus useful for carrying out the method and a method useful for recycling the object are also provided.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
Provided herein according to some embodiments is a dual cure additive manufacturing resin, comprising: (i) a light polymerizable component, (ii) a photoinitiator, (iii) a heat polymerizable component, and (iv) a non-reactive diluent, which resin is useful for the production of three-dimensional objects by additive manufacturing. Methods of using the same are also provided.
B29C 35/02 - Heating or curing, e.g. crosslinking or vulcanising
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
Three-dimensional (3D) lattice objects with multiple zones of different lattice unit cells may be formed by additive manufacturing. Sets of primary unit cells are provided such that each primary unit cell is configured to smoothly transition to other primary unit cells through a series of intermediate unit cells. A universal unit cell may define the primary and intermediate unit cells.
In some embodiments, a method of determining the fill level of a resin pool in a bottom-up additive manufacturing apparatus includes the steps of: (a) providing an additive manufacturing apparatus including a build platform and a light transmissive window (12), the build platform (15) and the window (12) defining a build region therebetween, with the window (12) carrying a resin pool, the pool having a resin top surface portion; (b) advancing the build platform (15) and the window (12) towards one another until the build platform (15) contacts the resin top surface portion; (c) detecting the impact of the build platform (15) with the resin top surface portion; and (d) determining the fill level of the resin pool from the detected impact.
Methods, systems, and/or apparatuses for making an object on a bottom-up stereolithography apparatus that includes a light source, a drive assembly, optionally a heater and/or cooler, and a controller. The light source, optional heater and/or cooler, and/or the drive assembly have at least one adjustable parameter that is adjustable by said controller. An example method comprises (a) installing a removable window cassette on said apparatus in a configuration through which said light source projects, said window cassette comprising an optically transparent member having a build surface on which an object can be produced, and with said optically transparent member having at least one thermal profile associated therewith; and then (b) modifying said at least one adjustable parameter by said controller based on said at least one thermal profile of said optically transparent member; and then (c) producing the object on said build surface from a light-polymerizable liquid by bottom-up stereolithography.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
Provided is a method of recycling an additively manufactured object into a reusable thermoplastic polymer, which method in some embodiments may include: (a) providing at least one additively manufactured object produced by stereolithography from a dual cure resin, the object comprising (i) a light polymerized polymer, and (ii) a heat polymerized polymer intermixed with said light polymerized polymer; (b) comminuting the object to produce a particulate material therefrom; (c) contacting the particulate material to a polar, aprotic solvent for a time and at a temperature sufficient to extract the heat polymerized polymer from the particulate material into said solvent, leaving residual particulate material comprising said light polymerized polymer in solid form; (d) separating the residual particulate material from said solvent; and then (e) separating the heat polymerized polymer from said solvent to provide a reusable thermoplastic polymer material in solid form.
A method of cleaning residual resin from an additively manufactured object, includes: (a) enclosing an additively manufactured object in an inner chamber of a centrifugal separator, the additively manufactured object including a light polymerized resin with a surface coating of viscous, unpolymerized, residual resin; (b) flooding the chamber with a volatile organic solvent vapor without contacting liquid organic solvent to the object, the vapor present in an amount sufficient to reduce the viscosity of the residual resin; and (c) spinning the additively manufactured object in the chamber to centrifugally separate at least a first portion of the residual resin from the object.
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
B08B 3/08 - Cleaning involving contact with liquid the liquid having chemical or dissolving effect
B08B 5/00 - Cleaning by methods involving the use of air flow or gas flow
B08B 7/02 - Cleaning by methods not provided for in a single other subclass or a single group in this subclass by distortion, beating, or vibration of the surface to be cleaned
B08B 7/04 - Cleaning by methods not provided for in a single other subclass or a single group in this subclass by a combination of operations
An integrated additive manufacturing system includes: (a) at least one resin supply; (b) a plurality of additive manufacturing machines on which parts may be produced, each of the additive manufacturing machines operatively associated with the at least one resin supply; and (c) at least one peripheral machine operatively associated with each of the additive manufacturing machines and the at least one resin supply.
B33Y 30/00 - Apparatus for additive manufacturingDetails thereof or accessories therefor
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/188 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
B29C 64/255 - Enclosures for the building material, e.g. powder containers
B29C 64/371 - Conditioning of environment using an environment other than air, e.g. inert gas
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
Provided herein according to aspects of the present invention are resins that: (a) are suitable for use in additive manufacturing techniques such as bottom-up and top-down stereolithography, (b) produce objects that are bioresorbable, and (c) produce objects that are flexible or elastic (preferably at at least typical room temperatures of 25° C., and in some embodiments at typical human body temperatures of 37° C.). Such resins may include: (a) a bioresorbable polyester oligomer having reactive end groups; (b) non-reactive diluent; (c) optionally reactive diluent; and (d) a photoinitiator.
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A resin composition useful for additive manufacturing is provided, which resin composition may exhibit improved shelf life through inhibition of crystallization. Such resin composition may include a crystallization inhibitor as taught herein, and/or a prepolymer produced by reaction of an isocyanate with multiple isomers and comprising a lower percentage of the structurally symmetric isomer. Methods of forming a three-dimensional object using such resin composition are also provided.
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A resin useful for producing objects is provided, which resin contains a photoinitiator of low cytotoxicity. The resins may be suitable for use in additive manufacturing techniques such as bottom-up and top-down stereolithography, produce objects that are bioresorbable and non-cytotoxic, and/or produce objects that are flexible or elastic. Methods of use of the resin and objects produced therefrom are also provided.
A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
B29C 35/08 - Heating or curing, e.g. crosslinking or vulcanising by wave energy or particle radiation
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B29C 64/255 - Enclosures for the building material, e.g. powder containers
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfacesMaterials therefor, e.g. comprising photoresistsApparatus specially adapted therefor
G03F 7/027 - Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
G03F 7/038 - Macromolecular compounds which are rendered insoluble or differentially wettable
Provided herein are methods of making (meth)acrylate blocked polyurethanes with zirconium catalysts, dual cure resins containing (meth)acrylate blocked polyurethanes and zirconium catalysts, methods of using the same in additive manufacturing, and products made therefrom.
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
C08F 299/06 - Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
C08G 18/10 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
A method of making a three-dimensional object, including the steps of: (a) providing a carrier platform; (b) producing the three-dimensional object adhered to the carrier platform; (c) immersing the object in a wash liquid with the object remaining adhered to the carrier platform; (d) agitating the object in the wash liquid and/or the wash liquid with the object immersed therein to at least partially remove residual resin from the object; (e) separating the object from the wash liquid, with the object remaining adhered to the carrier platform; (f) agitating the object at least partially remove residual wash liquid; and (g) repeating steps (c) through (f) at least once to remove additional polymerizable resin, steps (c) through (f) are carried out in the same vessel, the immersing step (c) includes filling the vessel with the wash liquid, and the separating step (e) includes draining the wash liquid from the vessel.
B08B 3/04 - Cleaning involving contact with liquid
B08B 3/10 - Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
B08B 3/12 - Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
B29C 64/20 - Apparatus for additive manufacturingDetails thereof or accessories therefor
B08B 3/08 - Cleaning involving contact with liquid the liquid having chemical or dissolving effect
B08B 3/14 - Removing waste, e.g. labels, from cleaning liquid
58.
MECHANICALLY ANISOTROPIC 3D PRINTED FLEXIBLE POLYMERIC SHEATH
A connective or supportive sheath comprising, consisting of, or consisting essentially of a hollow tube having a circumferential or perimeter wall, the wall having an inner surface and an outer surface, the wall comprising interconnected, radially projecting, partitions, the partitions forming radially extending pores, the pores extending from said inner surface through said outer surface, and wherein the tube is comprised of, consists of, or consists essentially of a flexible or elastic polymer.
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
A method of making a three-dimensional object by additive manufacturing from a blended resin including (i) at least one light polymerizable first component and, (ii) at least one, or a plurality of, second solidifiable components that are different from said first component, the method including: providing a first resin and a second resin, where the resins produce three-dimensional objects having different mechanical properties from one another when all are produced under the same process conditions; mixing the first and second resins with one another to produce the blended resin, the blended resin producing a three-dimensional object having mechanical properties intermediate between that of objects produced by the first and second resins when all are produced under the same process conditions; and dispensing the blended resin to the build region of an additive manufacturing apparatus; and then optionally but preferably producing a three-dimensional object from the blended resin in the apparatus.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
C08K 3/013 - Fillers, pigments or reinforcing additives
C08K 3/01 - Use of inorganic substances as compounding ingredients characterised by their specific function
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfacesMaterials therefor, e.g. comprising photoresistsApparatus specially adapted therefor
G03F 7/027 - Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
G03F 7/038 - Macromolecular compounds which are rendered insoluble or differentially wettable
G03F 7/38 - Treatment before imagewise removal, e.g. prebaking
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B29C 64/386 - Data acquisition or data processing for additive manufacturing
C08G 18/81 - Unsaturated isocyanates or isothiocyanates
C08G 18/10 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
C08G 18/76 - Polyisocyanates or polyisothiocyanates cyclic aromatic
B29C 64/255 - Enclosures for the building material, e.g. powder containers
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
B33Y 30/00 - Apparatus for additive manufacturingDetails thereof or accessories therefor
C08J 5/00 - Manufacture of articles or shaped materials containing macromolecular substances
C08L 75/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 33/00 - Moulds or coresDetails thereof or accessories therefor
B29K 105/00 - Condition, form or state of moulded material
B29K 75/00 - Use of polyureas or polyurethanes as moulding material
B29K 105/04 - Condition, form or state of moulded material cellular or porous
B29L 11/00 - Optical elements, e.g. lenses, prisms
B29L 31/10 - Building elements, e.g. bricks, blocks, tiles, panels, posts, beams
Provided are methods of making an additively manufactured object having an outer surface coating thereon. Also provided are additively manufactured objects having an outer surface coating thereon.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/188 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B05D 1/18 - Processes for applying liquids or other fluent materials performed by dipping
B05D 7/02 - Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
A method of making a plurality of polymer dental appliances, including the steps of: (a) additively manufacturing a plurality of hollow molds from a polymerizable resin, each mold having an external surface portion configured in the shape of a dental arch and a bottom portion having a hollow cavity therein, and with the additively manufacturing step carried out with the plurality of hollow molds formed on a build platform; (b) centrifugally separating residual resin from both the external surface portion and the bottom portion (including the hollow cavity) of each mold; (c) further curing, concurrently or sequentially, the external surface portion and the bottom portion of each mold with ultraviolet light; then (d) thermoforming a thermoplastic polymer sheet on each hollow mold external surface portion to produce the plurality of polymer dental appliances; and (e) separating the plurality of polymer dental appliances from the plurality of hollow molds.
A61C 7/00 - Orthodontics, i.e. obtaining or maintaining the desired position of teeth, e.g. by straightening, evening, regulating, separating, or by correcting malocclusions
An additively manufactured lattice includes a plurality of symmetrically oriented repeating unit cells. Each of the unit cells is comprised of a vertically oriented tubular structure having a top edge and bottom edge, said tubular structure defined by a circumferential side wall extending from said top edge to said bottom edge. The side wall has a lower portion, an intermediate portion, and an upper portion, with the lower portion terminating at the bottom edge, the upper portion terminating at the top edge, and the intermediate portion positioned between the lower portion and the upper portion. A plurality of spaced legs is included with each unit cell, with each leg formed as an outfolding of the side wall, each outfolding beginning at the side wall intermediate portion and extending progressively further outward through the side wall lower portion to the bottom edge.
A41D 13/015 - Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches with shock-absorbing means
B33Y 80/00 - Products made by additive manufacturing
64.
Methods for producing three-dimensional objects with apparatus having feed channels
A method of forming a three-dimensional object (e.g. comprised of polyurethane, polyurea, or copolymer thereof) is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid comprising a mixture of: (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the second solidifiable component; and then (d) contacting the three-dimensional intermediate to water to form the three-dimensional object.
B29C 71/04 - After-treatment of articles without altering their shapeApparatus therefor by wave energy or particle radiation
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
C08K 3/013 - Fillers, pigments or reinforcing additives
C08K 3/01 - Use of inorganic substances as compounding ingredients characterised by their specific function
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfacesMaterials therefor, e.g. comprising photoresistsApparatus specially adapted therefor
G03F 7/027 - Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
G03F 7/038 - Macromolecular compounds which are rendered insoluble or differentially wettable
G03F 7/38 - Treatment before imagewise removal, e.g. prebaking
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B29C 64/386 - Data acquisition or data processing for additive manufacturing
C08G 18/81 - Unsaturated isocyanates or isothiocyanates
C08G 18/10 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
C08G 18/76 - Polyisocyanates or polyisothiocyanates cyclic aromatic
B29C 64/255 - Enclosures for the building material, e.g. powder containers
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
B33Y 30/00 - Apparatus for additive manufacturingDetails thereof or accessories therefor
C08J 5/00 - Manufacture of articles or shaped materials containing macromolecular substances
C08L 75/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 33/00 - Moulds or coresDetails thereof or accessories therefor
B29K 105/00 - Condition, form or state of moulded material
B29K 75/00 - Use of polyureas or polyurethanes as moulding material
B29K 105/04 - Condition, form or state of moulded material cellular or porous
B29L 11/00 - Optical elements, e.g. lenses, prisms
B29L 31/10 - Building elements, e.g. bricks, blocks, tiles, panels, posts, beams
Provided according to embodiments of the invention are methods for the rapid production of a composition that includes a reactive blocked prepolymer. Such methods may include continuously mixing a first precursor composition and a second precursor composition, the first precursor composition including a polyisocyanate oligomer and the second precursor composition including an amine (meth)acrylate to produce the composition that includes a reactive blocked prepolymer.
C08G 18/10 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
B29C 64/00 - Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
B33Y 70/00 - Materials specially adapted for additive manufacturing
C08G 18/81 - Unsaturated isocyanates or isothiocyanates
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfacesMaterials therefor, e.g. comprising photoresistsApparatus specially adapted therefor
66.
PARTICLE COATING METHODS FOR ADDITIVELY MANUFACTURED PRODUCTS
Provided herein according to aspects of the present invention is a method of additively manufacturing an object having a particle surface coating thereon, using an intermediate object produced in an additive manufacturing process by light polymerization of a dual cure resin, said intermediate object having residual dual cure resin from which it was produced remaining on a surface portion thereof in unpolymerized form; forming a solid particle coating adhered to the resin coating film; and then further curing the intermediate object.
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
67.
Reduction of polymerization inhibitor irregularity on additive manufacturing windows
An apparatus for producing a three-dimensional object by additive manufacturing includes a drive assembly operatively associated with a carrier and a window mount and configured to advance the carrier and the window mount away from one another. A first fluid switch is connected to a first fluid orifice when a window is present, or connected to the window mount and configured for connection to the window when the window is absent. A second fluid switch is connected to a second fluid orifice when the window is present, or connected to the window mount and configured for connection to the window when the window is absent. A fluid supply is connected to both the first and second fluid switch, and the fluid includes a polymerization inhibitor.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A method of forming a three-dimensional object includes: providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; filling the build region with a polymerizable liquid, irradiating the build region with light through the optically transparent member to form a solid polymer from the polymerizable liquid, and advancing said carrier away from said build surface to form said three-dimensional object from said solid polymer. The irradiating step includes projecting focused light at the build region, and the advancing step is carried out at a rate that is dependent on an average light intensity of the focused light.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/112 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
A dental model, includes (a) an upper segment, the upper segment having a shape corresponding to at least a portion of a dental arch of a human patient; (b) a base segment having an external surface and a bottom surface; (c) at least one internal cavity formed in the base segment, and optionally the upper segment, the at least one internal cavity extending through the bottom surface; and (d) at least one wash channel extending from the external surface of the base segment through the base segment and into the at least one internal cavity.
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
The present invention concerns methods of forming a three-dimensional object, and polymerizable liquids such as dual cure resins useful for making a three-dimensional object by sterolithography, such as by continuous liquid interface production (CLIP), wherein the three-dimensional object is flame retardant.
B29C 64/00 - Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
C08L 51/00 - Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bondsCompositions of derivatives of such polymers
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
Tdd symmetry); and then (c) filling said tetrahedral mesh with the tetrahedral unit cell to thereby construct a 3D object comprising repeating interconnected unit cells of the selected primary lattice. In some embodiments the method further includes the step of (d) additively manufacturing the 3D object.
e.g.,e.g., stiffness, energy absorption, energy return, resilience, toughness) along a predefined axis therein not achieved by either said first or second surface lattice unit cell when formed from the same material as said hybrid surface lattice unit cell.
B29C 64/00 - Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
B33Y 50/00 - Data acquisition or data processing for additive manufacturing
G06F 111/06 - Multi-objective optimisation, e.g. Pareto optimisation using simulated annealing [SA], ant colony algorithms or genetic algorithms [GA]
G06F 113/10 - Additive manufacturing, e.g. 3D printing
G06F 119/14 - Force analysis or force optimisation, e.g. static or dynamic forces
73.
SYSTEMS AND METHODS FOR SURFACE TEXTURING OBJECTS DURING ADDITIVE MANUFACTURING
Surface texturing of objects during additive manufacturing, including systems and methods thereof. For example, a method of surface texturing a three-dimensional (3D) object during additive manufacturing of the object: (a) irradiating a resin segment with patterned light at a build plane to polymerize said resin and grow said 3D object, then (b) advancing said object away from said build plane to bring a new segment of said resin in contact with said growing 3D object and establish a new build plane, and then repeating steps (a) through (b) until said 3D object is formed. For resin segments that correspond to portions of said 3D object to which surface texture is applied, said irradiating step is carried out by sequentially irradiating each resin segment with: (i) a first sub-exposure pattern and (ii) a second sub-exposure pattern, one of which is modified to include a texture pattern on a surface thereof.
B29C 64/282 - Arrangements for irradiation using multiple radiation means, e.g. micromirrors or multiple light-emitting diodes [LED] of the same type, e.g. using different energy levels
f) each configured to produce three-dimensional objects (13), each printer including: (i) a plurality of subsystems; and (ii) at least one sensor; and (b) processor(s) (41, 42) and memory resource(s) (21) storing an inventory of available replacement components for at least some of said subsystems. The one or more memory resources may (21) store instructions that may cause the one or more processors to: (i) identify a predetermined pattern in data sensed during a process of producing a three-dimensional object by a sensor of a printer as an indicator of likely failure of a subsystem or component thereof; and (ii) assign a component in inventory to said printer based on a unique identifier of the printer and the indicator of likely failure identified in the signal.
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
An additively manufactured cushion includes an array of interconnected surface lattice unit cells. The surface lattice unit cells are comprised of a unit cell surface portion configured as a Schoen F-RD minimal surface unit cell, and the unit cell surface portion is comprised of a rigid, flexible, or elastic polymer. In some embodiments, the surface lattice unit cells have an average width of from 1 to 100 millimeters and an average volume fraction of from 5 or 10 percent to 50 or 60 percent.
Provided herein according to aspects of the present invention are resins that: (a) are suitable for use in additive manufacturing techniques such as bottom-up and top-down stereolithography, (b) produce objects that are bioresorbable, and (c) produce objects that are flexible or elastic (preferably at at least typical room temperatures of 25° C., and in some embodiments at typical human body temperatures of 37° C.). Such resins may include: (a) a bioresorbable polyester oligomer having reactive end groups; (b) non-reactive diluent; (c) optionally reactive diluent; and (d) a photoinitiator.
B29C 35/08 - Heating or curing, e.g. crosslinking or vulcanising by wave energy or particle radiation
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
B33Y 70/00 - Materials specially adapted for additive manufacturing
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
C08G 63/91 - Polymers modified by chemical after-treatment
A method of forming a three-dimensional object is carried out by: providing a carrier and a pool of immiscible liquid, the pool having a liquid build surface, the carrier and the liquid build surface defining a build region therebetween; filling the build region with a polymerizable liquid, wherein the immiscible liquid is immiscible with the polymerizable liquid (in some embodiments wherein the immiscible liquid has a density greater than the polymerizable liquid); irradiating the build region through at least a portion of the pool of immiscible liquid to form a solid polymer from the polymerizable liquid and advancing the carrier away from the liquid build surface to form the three-dimensional object comprised of the solid polymer from the polymerizable liquid. Optionally, but in some embodiments preferably, the method is carried out while also continuously maintaining a gradient of polymerization zone between the liquid build surface and the solid polymer and in contact with each thereof, the gradient of polymerization zone comprising the polymerizable liquid in partially cured form.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B29C 64/188 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
B29C 64/20 - Apparatus for additive manufacturingDetails thereof or accessories therefor
78.
Divided resin cassettes for enhanced work flow in additive manufacturing of dental products and the like
The present disclosure describes a resin cassette for an additive manufacturing apparatus. The resin cassette includes a light-transmissive window, a frame connected to and surrounding the window, and at least one dame connected to the frame. The frame and window form a well for receiving a light polymerizable resin. The dam extends over and continuously contacts the window and partitions the well into a plurality of independent build regions, each independent build region configured for receiving different light polymerizable resins. Additive manufacturing apparatuses and methods of concurrently making three-dimensional objects are also described.
B29C 64/259 - Enclosures for the building material, e.g. powder containers interchangeable
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/171 - Processes of additive manufacturing specially adapted for manufacturing multiple 3D objects
Described herein are methods, systems and apparatus (including associated control methods, systems and apparatus), for the production of a three-dimensional object by “bottom up” additive manufacturing, in which a carrier is vertically reciprocated with respect to a build surface, to enhance or speed the refilling of the build region with a solidifiable liquid. In preferred (but not necessarily limiting) embodiments, the three-dimensional object is produced from a liquid interface by continuous liquid interface production (i.e., “CLIP”).
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A method of producing multiple batches of objects by stereolithography, includes the steps of: (a) dispensing an initial or subsequent batch of dual cure resin into a stereolithography apparatus, the resin including a light polymerizable component and a heat polymerizable component; (b) producing an intermediate object by light polymerization of the resin in the apparatus, wherein the intermediate object retains excess resin on a surface thereof; then (c) separating excess resin from the intermediate object; (d) blending the excess resin with additional dual cure resin to produce a subsequent batch of dual cure resin; (e) repeating steps (a) through (c), and optionally repeating step (d), to produce additional object(s); and (f) baking the objects, together or separately, to produce multiple batches of objects.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A method of cleaning residual resin from an additively manufactured object, includes: (a) enclosing an additively manufactured object in an inner chamber of a centrifugal separator, the additively manufactured object including a light polymerized resin with a surface coating of viscous, unpolymerized, residual resin; (b) flooding the chamber with a volatile organic solvent vapor without contacting liquid organic solvent to the object, the vapor present in an amount sufficient to reduce the viscosity of the residual resin; and (c) spinning the additively manufactured object in the chamber to centrifugally separate at least a first portion of the residual resin from the object.
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
B08B 3/08 - Cleaning involving contact with liquid the liquid having chemical or dissolving effect
B08B 5/00 - Cleaning by methods involving the use of air flow or gas flow
B08B 7/02 - Cleaning by methods not provided for in a single other subclass or a single group in this subclass by distortion, beating, or vibration of the surface to be cleaned
82.
Dual precursor resin systems for additive manufacturing with dual cure resins
A method of forming a dual cure three-dimensional object by additive manufacturing may be carried out by mixing a first precursor liquid and a second precursor liquid to produce a polymerizable liquid comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component (e.g., a second reactive component) that is different from the first component (e.g., that does not contain a cationic photoinitiator, or is further solidified by a different physical mechanism, or further reacted, polymerized or chain extended by a different chemical reaction). In the foregoing: (i′) at least one reactant of the second solidifiable component is contained in the first precursor liquid, and (ii′) at least one reactant or catalyst of the second solidifiable component is contained in the second precursor liquid. Once mixed, the three-dimensional object may be formed from the resin by a dual cure additive manufacturing process.
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfacesMaterials therefor, e.g. comprising photoresistsApparatus specially adapted therefor
A helmet liner includes: (a) an open lattice body portion comprised of a polymer, the body portion having opposite face portions and a circumferential side portion; (b) a helmet contact surface portion formed on one of the face portions; and (c) a skin contact portion formed on the other of the face portions, the skin contact portion configured with the lattice body portion so air can circulate through both the body portion and the skin contact portion.
A method of separating excess resin from at least one object, includes: (a) stereolithographically producing at least one object on at least one carrier platform, each carrier platform having a planar build surface to which at least one object is connected, each object carrying excess resin on a surface thereof; then (b) mounting each carrier platform to a rotor; (c) centrifugally separating excess resin from each object by spinning the rotor with each carrier platform connected thereto while each object remains connected to each carrier platform; and then (d) removing each carrier platform from the rotor with each object thereon, with excess resin separated therefrom.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A method of forming a three-dimensional object (31) includes the steps of: (a) providing an apparatus including a carrier (15), a light transmissive window (12) having a build surface, polymerizable liquid (21) on the build surface, and a growing object (31) on the carrier, the growing object produced by light polymerization of the polymerizable liquid; (b) vertically reciprocating the carrier (15) with respect to the build surface in an upstroke and a downstroke, the downstroke being shorter than the upstroke, to form a build region between the growing object and the build surface, and to fill the build region with the polymerizable liquid, while also: (i) sensing force exerted between the carrier and the build surface through the growing object (31) and the polymerizable liquid (21) during the upstroke; and (ii) modifying the speed, acceleration, or both speed and acceleration of the upstroke in response to the sensed force so that the sensed force approaches a predetermined target force; then (c) irradiating the build region with light through the light transmissive window to form a new portion of the object from the polymerizable liquid on the growing object; and then (d) repeating steps (b) through (c) to form additional portions on the growing object until the three-dimensional object is formed.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/232 - Driving means for motion along the axis orthogonal to the plane of a layer
Provided herein is a method of making a flexible partial denture, which may include: (a) producing a partial denture base by additive manufacturing (e.g., bottom-up or top-down stereolithography) from a dual cure resin, with the dual cure resin comprising a light polymerizable component and a heat polymerizable component, with the denture base including at least one tooth socket; (b) inserting an acrylic artificial tooth into each at least one tooth socket to produce an assembled intermediate product; and then (c) baking said assembled intermediate product for a time sufficient to cure said heat polymerizable component in said denture base and retained dual cure resin, bond said tooth into each at least one socket with said retained dual cure resin, and produce said flexible partial denture. A flexible partial denture produced and resin formulations useful for the same are also provided.
An adhesion barrier is comprised of, consists of, or consists essentially of a sheet having a top surface and a bottom surface. The sheet includes either (i) interconnected links or (ii) interconnected, vertically aligned, partitions. The links form pores or the partitions form pores, with the pores extending from the top surface through the bottom surface. The sheet is comprised of, consists of, or consists essentially of a flexible or elastic polymer.
A61B 90/00 - Instruments, implements or accessories specially adapted for surgery or diagnosis and not covered by any of the groups , e.g. for luxation treatment or for protecting wound edges
A61L 31/12 - Composite materials, i.e. layered or containing one material dispersed in a matrix of the same or different material
A61L 31/14 - Materials characterised by their function or physical properties
Provided herein according to some embodiments is a dual cure additive manufacturing resin, comprising: (i) a light polymerizable component, (ii) a photoinitiator, (iii) a heat polymerizable component, and (iv) a non-reactive diluent, which resin is useful for the production of three-dimensional objects by additive manufacturing. Methods of using the same are also provided.
B29C 45/14 - Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mouldApparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
A method for the production of an object by additive manufacturing includes inputting a boundary shape and desired mechanical properties for said object, subdividing said boundary shape into work cells, providing lattices in a database, each lattice including a geometry and a mechanical property, filling a first one of said work cells with a lattice from the database, the lattice selected based on the correspondence of the mechanical properties of said lattice to said desired mechanical properties of said object, filling the remaining ones of said work cells with lattices from said database to produce a filled boundary shape, each said lattice selected based on the correspondence of the mechanical properties of said lattice to the desired mechanical properties of the object and the compatibility of adjacent lattices in adjacent work cells with one another, then performing a modification operation on the lattice of a work cell.
Provided herein is a dual cure resin useful for the production of objects by stereolithography, said resin comprising a mixture of: (a) a light-polymerizable component; and (b) a heat-polymerizable component, said heat-polymerizable component comprising: (i) a dicyclopentadiene-containing polyepoxide resin; (ii) a cyanate ester resin; (iii) an epoxy-reactive toughening agent; and (iv) a core shell rubber toughener.
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
C08F 283/10 - Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass on to polymers containing more than one epoxy radical per molecule
Provided herein according to some embodiments is polymerizable liquid useful for the production of a three-dimensional object by additive manufacturing, said polymerizable liquid comprising a mixture of: (a) at least one photopolymerizable component; (b) a photoinitiator; (c) at least one heat polymerizable component; and (d) heat expandable microspheres. A method of making a three-dimensional object from such a polymerizable liquid by additive manufacturing and objects so produced are also provided.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/188 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
Provided herein is a resin product useful for the production of three-dimensional objects by additive manufacturing, and methods using the same. The resin may include a reactive blocked prepolymer comprising a prepolymer blocked with reactive blocking groups; a polyol; a photoinitiator; and at least one organometallic catalyst. A packaged product useful for the production of three-dimensional objects by additive manufacturing, the product comprising a single container having a single chamber and a resin in the chamber with all components mixed together, is also provided.
B29C 35/04 - Heating or curing, e.g. crosslinking or vulcanising using liquids, gas or steam
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B33Y 70/00 - Materials specially adapted for additive manufacturing
B01J 31/12 - Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
C08F 2/44 - Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
C08F 4/50 - MetalsMetal hydridesMetallo-organic compoundsUse thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper, or silver
A method of cleaning residual resin from an additively manufactured object, includes: (a) enclosing an additively manufactured object in an inner chamber of a centrifugal separator, the additively manufactured object including a light polymerized resin with a surface coating of viscous, unpolymerized, residual resin; (b) flooding the chamber with a volatile organic solvent vapor without contacting liquid organic solvent to the object, the vapor present in an amount sufficient to reduce the viscosity of the residual resin; and (c) spinning the additively manufactured object in the chamber to centrifugally separate at least a first portion of the residual resin from the object.
A method of measuring the viscosity of a resin in a bottom-up additive manufacturing apparatus, includes the steps of: (a) providing an additive manufacturing apparatus including a build platform and a light transmissive window, said build platform and said window defining a build region there between, with said window carrying a resin; (b) advancing said build platform and said window towards one another until said build platform contacts said resin; (c) detecting the force exerted on said build platform by said resin; and (d) generating in a processor a viscosity measure of said resin from said detected force.
B29C 64/232 - Driving means for motion along the axis orthogonal to the plane of a layer
G01N 11/10 - Investigating flow properties of materials, e.g. viscosity or plasticityAnalysing materials by determining flow properties by moving a body within the material
G01L 5/00 - Apparatus for, or methods of, measuring force, work, mechanical power, or torque, specially adapted for specific purposes
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
Various embodiments described herein provide a method of making an object from a three-dimensional geometry file and a light polymerizable resin on a light-transmissive window by projection of light through the window in a bottom-up stereolithography process. The method may comprise: slicing the file into a series of sequential images. Temperature fluctuations in the resin may be calculated for at least some of the sequential images upon light polymerization thereof based on sequential exposure of the resin to light, the light corresponding to the series of sequential images. During producing of the object, the production may be modified based on the calculated temperature fluctuations by: (i) reducing production speed during at least a portion of the production; (ii) activating a window cooler during at least a portion of the production; or (iii) increasing production speed during at least a portion of the production.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
The present disclosure describes an additive manufacturing apparatus. The apparatus includes a chamber (11) having a planar circumferential top edge portion (12) defining a chamber orifice (13); a stage (15) movably positioned in the chamber (11), the two together configured to receive a viscous resin; a dispenser (30) facing the stage (15) and operatively associated therewith, the dispenser (30) configured to apply a planar coating of viscous resin; a primary drive (22) operatively associated with the dispenser (30) and chamber (11), the primary drive (22) configured to move the dispenser (30) across the chamber orifice (13); a light engine (40) facing the stage (15) and operatively associated therewith, the light engine (40) configured to expose a coating of resin on the stage (15) planar top surface (12) to patterned light; and a stage drive (24) operatively associated with the stage (15) and configured to retract the stage (15) into the chamber (11), following exposure of a coating of resin. Methods of making a three-dimensional object by additive manufacturing are also described.
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
Provided is a method of making a cured object having a surface coating bonded thereto, which may include: providing an intermediate object produced in an additive manufacturing process such as stereolithography by light polymerization of a dual cure resin, the resin comprising a mixture of (i) a light polymerizable first component, and (ii) a second component that is different from the first component; applying a first reactive coating composition to a surface portion of the object to form a first coating thereon; optionally, but in some embodiments preferably, applying a second reactive coating composition to the first coating to form a second coating thereon; and heating the object at (and for) a time and to a temperature sufficient to bond the first coating to the surface portion, and bond the second coating when present to the first coating, and form the cured object having a surface coating bonded thereto.
B29C 64/307 - Handling of material to be used in additive manufacturing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/188 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
B29C 64/194 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control during lay-up
B33Y 70/10 - Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
The present disclosure describes an apparatus for additively manufacturing a three-dimensional object. The apparatus includes a radiation source, a carrier on which the three-dimensional object is made, an applicator assembly configured to apply a polymerizable liquid, and a frame, with the applicator assembly and the radiation source connected to the frame. A first drive assembly interconnects the applicator assembly and the frame and a second drive assembly interconnects the carrier and the frame. The frame defines a build region between the applicator assembly and the carrier. The applicator assembly includes a polymerizable liquid supply chamber, an application roller, and a metering roller. The applicator assembly may optionally include a post-metering roller. An apparatus comprising a first and a second applicator assembly and a smaller scale version of the apparatus are also described.
An additive manufacturing system may include an additive manufacturing apparatus on which a process of producing a three-dimensional object from a material can be performed; an additive manufacturing process controller operatively associated with the additive manufacturing apparatus; and a first memory device operatively associated with the additive manufacturing process controller. The first memory device may include first and second stable release process programs each comprising a first subset of operations executable by said process controller. The system may include a second memory device comprising another stable release process program comprising a second subset of operations executable by said process controller. The system may include a selector configured to choose one of the stable release process programs to run on said process controller when producing a three-dimensional object on the additive manufacturing apparatus.
