The present invention provides high-octane fuel, and a method of producing same. These fuels may be formulated to have a wide range of octane values and energy, and may effectively be used to replace 100 LL aviation fuel (known as AvGas), as well as high-octane, rocket, diesel, turbine engine fuels, as well as two-cycle, spark-ignited engine fuels.
The present invention provides high-octane fuel, and a method of producing same. These fuels may be formulated to have a wide range of octane values and energy, and may effectively be used to replace 100 LL aviation fuel (known as AvGas), as well as high-octane, rocket, diesel, turbine engine fuels, as well as two-cycle, spark-ignited engine fuels.
C07C 1/207 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms from carbonyl compounds
3.
Renewable engine fuel and method of producing same
The present invention provides non-petroleum high-octane fuel which may be derived from biomass sources, and a method of producing same. The method of production involves reducing the biomass feedstocks to sugars, fermenting the sugars using microorganisms or mutagens thereof to produce ethanol or acetic acid, converting the acetic acid or ethanol to acetone, and converting the acetone to mesitylene and isopentane, the major components of the engine fuel. Trimerization of acetone can be carried out in the presence of a catalyst containing at least one metal selected from the group consisting of niobium, iron and manganese. The ethanol can be converted to mesitylene in a dehydration reaction in the presence of a catalyst of zinc oxide/calcium oxide, and unreacted ethanol and water separated from mesitylene by distillation. These ethanol-based fuels may be formulated to have a wide range of octane values and energy, and may effectively be used to replace 100 LL aviation fuel (known as AvGas), as well as high-octane, rocket, diesel, turbine engine fuels, as well as two-cycle, spark-ignited engine fuels.
C10L 1/02 - Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
C07C 1/207 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms from carbonyl compounds
C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
C12P 7/36 - Acetone-containing products produced from substrate containing grain or cereal material
A method of producing from a biomass mesitylene-isopentane fuel is provided. A biomass may be fermented to form acetone. The acetone is converted in a catalytic reactor to mesitylene and mesityl oxide. The mesitylene is separated in a phase separator and the organic face containing mesityl oxide is sent to a dehydration reactor, then to a demethylation reactor, and finally to a hydrogenation reactor from which isopentane is recovered. This isopentane is then mixed with the mesitylene to form the final mesitylene-isopentane fuel. The catalytic reaction with acetone employs catalysts of either niobium, vanadium or tantalum.
C10L 1/02 - Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
C07C 1/207 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms from carbonyl compounds
C07C 4/10 - Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from acyclic hydrocarbons
C07C 5/08 - Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
C10G 45/32 - Selective hydrogenation of the diolefin or acetylene compounds
C10L 1/08 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
C12P 7/36 - Acetone-containing products produced from substrate containing grain or cereal material
C07C 5/03 - Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
The present invention provides fully renewable turbine and diesel fuels created from biomass sources. In one embodiment, the fully renewable turbine fuel is comprised of mesitylene and at least one alkane. Preferably, the turbine fuel comprises from about 50 to 99 wt % mesitylene and from about 1 to 50 wt % of at least one alkane. In another embodiment the diesel fuel comprises mesitylene, octadecane, and optionally octane or nonane. Preferably, the diesel fuel comprises from about 50 to 99 wt % mesitylene, and from about 1 to 50 wt % octadecane. These biomass derived fuels may be formulated to have a wide range of cetane values and differing freezing and boiling points. A preferred biogenic turbine fuel comprises one or more synthetic paraffinic kerosenes (SPK) and/or hydroprocessed renewable jet (HRJ) fuel; and between about 8 to 25 vol % of mesitylene. Another preferred biogenic turbine fuel is a blend of about 50% petroleum-based fuel; and about 50% of one or more of synthetic paraffinic kerosenes (SPK) and/or hydroprocessed renewable jet fuel (HRJ), and mesitylene.
MESITYLENE AS AN OCTANE ENHANCER FOR AUTOMOTIVE GASOLINE, ADDITIVE FOR JET FUEL, AND METHOD OF ENHANCING MOTOR FUEL OCTANE AND LOWERING JET FUEL CARBON EMISSIONS
A motor fuel providing higher gas mileage comprising gasoline produced from petroleum and from about 1 to 30wt% of mesitylene. This fuel can advantageously contain conventional additives used in gasoline. The use of mesitylene in gasoline blend yields a fuel blend with a higher research octane number and motor octane number. In addition, an improved jet fuel is provided, having from 1-10 wt% biomass-derived mesitylene added thereto, having improved carbon emission characteristics while maintaining required specifications. Further, an improved bio-fuel is provided, which may function as a replacement for conventional Jet A/JP-8 fuel and has lowered carbon emission specifications, the bio-fuel comprised of 75-90 wt% synthetic parafinnic kerosene (SPK) and 10-25 wt% mesitylene.
An electrocatalyst composition comprising one or more electrically conductive particles of one or more of carbon black, activated carbon, and graphite with one or more catalysts of a macrocycle and a metal adhered and/or bonded to the outer surface of the particles. The catalyst can be comprised, for example, of one or more of acetylacetonate and phthalocyanine and a metal. The metal component used in the electrocatalyst composition is comprised of one or more of iron, nickel, zinc, scandium, titanium, vanadium, chromium, copper, platinum, ruthenium, rhodium, palladium, silver, osmium, iridum, platinum and gold. An ionic transfer membrane having a layer of the electrocatalyst thereon is disposed in a fuel cell in communication with and between current collectors.
H01B 1/06 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of other non-metallic substances
B01J 23/70 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper
B01J 23/38 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of noble metals
The present invention provides fully renewable turbine and diesel fuels derived completely from biomass sources. In one embodiment the fully renewable turbine fuel is comprised of mesitylene and at least one alkane. Preferably, the turbine fuel comprises from about 50 to 99 wt % mesitylene and from about 1 to 50 wt % of at least one alkane. In another embodiment the diesel fuel comprises mesitylene, octadecane, and optionally octane or nonane. Preferably, the diesel fuel comprises from about 50 to 99 wt % mesitylene, and from about 1 to 50 wt % octadecane. These biomass derived fuels may be formulated to have a wide range of cetane values and differing freezing and boiling points.
The present invention provides non-petroleum high-octane fuel derived from biomass sources, and a method of producing same. The method of production involves reducing the biomass feedstocks to sugars, fermenting the sugars using microorganisms or mutagens thereof to produce ethanol or acetic acid, converting the acetic acid or ethanol to acetone, and converting the acetone to mesitylene and isopentane, the major components of the renewable engine fuel. Trimerization of acetone can be carried out in the presence of a catalyst containing at least one metal selected from the group consisting of niobium, iron and manganese. The ethanol can be converted to mesitylene in a dehydration reaction in the presence of a catalyst of zinc oxide/calcium oxide, and unreacted ethanol and water separated from mesitylene by distillation. These ethanol-based, biomass-derived fuels are fully renewable, may be formulated to have a wide range of octane values and energy, and may effectively be used to replace 100 LL aviation fuel (known as AvGas), as well as high-octane, rocket, diesel, turbine engine fuels, as well as two-cycle, spark-ignited engine fuels.
The present invention provides non-petroleum high octane fuel derived completely from biomass sources, and a method of producing same. The method of production involves reducing the biomass feedstocks to sugars, fermenting the sugars using microorganisms or mutagens thereof to produce ethanol or acetic acid, converting the acetic acid to acetone, and converting the acetone to mesitylene and isopentane, the major components of the renewable engine fuel. These ethanol-based, biomass-derived fuels are fully renewable, may be formulated to have a wide range of octane values and energy, and may effectively be used to replace 100LL aviation fuel (known as AvGas), as well as high octane, rocket, diesel, and turbine engine fuels.
10 straight chain alkanes derivable from polysaccharides, and one or more bio-oils. In addition, the fuel may contain triethanolamine. Such a lower octane renewable fuel may be utilized, for example, in automobile fuel, 100 LL aviation fuel applications, and turbine engine applications. These ethanol-based, fully renewable fuels may be formulated to have a wide range of octane values and energy, and may effectively be used to replace 100 LL aviation fuel (known as AvGas), as well as high octane, rocket, diesel, and turbine engine fuels. In another embodiment, there is provided a synthetic high octane aviation fuel comprising isopentane and mesitylene, and process of producing same from a biomass.
The present invention provides fully renewable engine fuels derived completely from biomass sources. The fully renewable engine fuel is comprised of one or more low carbon number esters, one or more pentosan-derivable furans, one or more aromatic hydrocarbon, one or more C4-C10 straight chain alkanes derivable from polysaccharides, and one or more bio-oils. In addition, the fuel may contain triethanolamine. Such a lower octane renewable fuel may be utilized, for example, in automobile fuel, 100 LL aviation fuel applications, and turbine engine applications. These ethanol-based, fully renewable fuels may be formulated to have a wide range of octane values and energy, and may effectively be used to replace 100LL aviation fuel (known as AvGas), as well as high octane, rocket, diesel, and turbine engine fuels.
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