|
1.
|
BIOMASS MODIFIED POLYVINYL ALCOHOL POLYMERS AND METHODS
Application Number |
US2024057788 |
Publication Number |
2025/117771 |
Status |
In Force |
Filing Date |
2024-11-27 |
Publication Date |
2025-06-05 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA LLC (USA)
|
Inventor |
Poche, Drew
|
Abstract
A modified PVOH polymer comprises a hydrophobic modification with a triglyceride seed oil, or a hydrophilic modification with a lactate or an amino acid, as well as a process for producing the same.
|
2.
|
BLOCKY POLYVINYL ALCOHOL POLYMERS
Application Number |
18744155 |
Status |
Pending |
Filing Date |
2024-06-14 |
First Publication Date |
2024-12-19 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Vicari, Richard
- Pollock, Regan
- Sawa, Kazuhiro
|
Abstract
A sulfonic acid modified polyvinyl alcohol resin including about 3 mol % to about 12 mol % of a comonomer including a sulfonic acid group, and a blockiness index η of the sulfonic acid group of between about 0.2 to about 0.4 according to the Modified Moritani Method.
|
3.
|
BLOCKY POLYVINYL ALCOHOL POLYMERS
Application Number |
US2024034121 |
Publication Number |
2024/259318 |
Status |
In Force |
Filing Date |
2024-06-14 |
Publication Date |
2024-12-19 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Vicari, Richard
- Pollock, Regan
- Sawa, Kazuhiro
|
Abstract
A sulfonic acid modified polyvinyl alcohol resin including about 3 mol% to about 12 mol% of a comonomer including a sulfonic acid group, and a blockiness index T| of the sulfonic acid group of between about 0.2 to about 0.4 according to the Modified Moritani Method.
|
4.
|
FLUOROCHEMICAL-FREE PVOH POLMERS AND FORMULATIONS FOR CELLULOSIC MATERIALS
Application Number |
18583614 |
Status |
Pending |
Filing Date |
2024-02-21 |
First Publication Date |
2024-09-12 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Nguyen, Vinh
- Vicari, Richard
- Wurm, David B.
- Shitera, George
|
Abstract
A formulation for cellulosic materials comprises a polyvinyl alcohol terpolymer comprising a polyvinyl alcohol modified with about 1 mol % to about 10 mol % of a hydrophilic comonomer, and with about 1 mol % to about 5 mol % of a hydrophobic comonomer, and having a degree of hydrolysis of about 92% to about 98%.
IPC Classes ?
- C08F 261/04 - Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group on to polymers of unsaturated alcohols on to polymers of vinyl alcohol
|
5.
|
FLUOROCHEMICAL-FREE PVOH POLYMERS AND COATING FORMULATIONS FOR CELLULOSIC MATERIALS
Application Number |
US2024016746 |
Publication Number |
2024/178138 |
Status |
In Force |
Filing Date |
2024-02-21 |
Publication Date |
2024-08-29 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Nguyen, Vinh
- Vicari, Richard
- Wurm, David, B.
- Shitera, George
|
Abstract
A formulation for cellulosic materials comprises a polyvinyl alcohol terpolymer comprising a polyvinyl alcohol modified with 1 mol% to 10 mol% of a hydrophilic comonomer, and with 1 mol% to 5 mol% of a hydrophobic comonomer, and having a degree of hydrolysis of 92% to 98%.
IPC Classes ?
- C08F 8/12 - Hydrolysis
- C08F 8/14 - Esterification
- C08F 216/06 - Polyvinyl alcohol
- C09D 129/04 - Polyvinyl alcoholPartially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
- D21H 19/20 - Coatings without pigments applied in a form other than the aqueous solution defined in group comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08F 18/08 - Vinyl acetate
|
6.
|
Mold release for engineered stone and other mold release applications
Application Number |
18412029 |
Grant Number |
12325157 |
Status |
In Force |
Filing Date |
2024-01-12 |
First Publication Date |
2024-07-18 |
Grant Date |
2025-06-10 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Wurm, David B.
- Shitera, George
- Nguyen, Vinh
|
Abstract
A homogeneous, aqueous mold release solution including: 5 to 90 wt % water; 3 to 40 wt % polyvinyl alcohol; 0.01 to 3.2 wt % surfactant; 1 to 20 wt % sugar alcohol; 0.005 to 1.05 wt % defoamer; and up to 50 ppm biocide, where a total of all components adds to 100 wt %. The mold release solutions have a viscosity in a range from 20 to 600 cps when measured at 23° C. In another aspect, embodiments disclosed herein relate to a homogeneous, aqueous mold release solution including: 5 to 85 wt % water; 10.5 to 15 wt % polyvinyl alcohol; 0.56 to 0.8 wt % surfactant; 1 to 8 wt % sugar alcohol; 0.01 to 0.3 wt % defoamer; and up to 50 ppm biocide, wherein a total of all components adds to 100 wt %. Also disclosed are films prepared from the mold release solutions, as well as methods of coating a substrate using such mold release solutions.
IPC Classes ?
- B29C 33/60 - Releasing, lubricating or separating agents
- C10M 173/02 - Lubricating compositions containing more than 10% water not containing mineral or fatty oils
- C10N 30/16 - AntisepticBiocidal
- C10N 30/18 - Anti-foaming property
- C10N 40/36 - Release agents
|
7.
|
MOLD RELEASE FOR ENGINEERED STONE AND OTHER MOLD RELEASE APPLICATIONS
Application Number |
US2024011410 |
Publication Number |
2024/151960 |
Status |
In Force |
Filing Date |
2024-01-12 |
Publication Date |
2024-07-18 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Wurm, David, B.
- Shitera, George
- Nguyen, Vinh
|
Abstract
A homogeneous, aqueous mold release solution including: 5 to 90 wt% water; 3 to 40 wt% polyvinyl alcohol; 0.01 to 3.2 wt% surfactant; 1 to 20 wt% sugar alcohol; 0.005 to 1.05 wt% defoamer; and up to 50 ppm biocide, where a total of all components adds to 100 wt%. The mold release solutions have a viscosity in a range from 20 to 600 cps when measured at 23 °C. In another aspect, embodiments disclosed herein relate to a homogeneous, aqueous mold release solution including: 5 to 85 wt% water; 10.5 to 15 wt% polyvinyl alcohol; 0.56 to 0.8 wt% surfactant; 1 to 8 wt% sugar alcohol; 0.01 to 0.3 wt% defoamer; and up to 50 ppm biocide, wherein a total of all components adds to 100 wt%. Also disclosed are films prepared from the mold release solutions, as well as methods of coating a substrate using such mold release solutions.
IPC Classes ?
- B29C 33/62 - Releasing, lubricating or separating agents based on polymers or oligomers
- B29C 33/58 - Applying the releasing agents
- C10M 103/00 - Lubricating compositions characterised by the base-material being an inorganic material
|
8.
|
MODIFIED POLYVINYL ALCOHOL RESIN WITH IMPROVED SOLUBILITY IN ALCOHOL MIXTURES
Application Number |
18154654 |
Status |
Pending |
Filing Date |
2023-01-13 |
First Publication Date |
2023-07-20 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Sawa, Kazuhiro
- Vicari, Richard
|
Abstract
A sulfonic acid modified polyvinyl alcohol resin comprising up to 15 mol % of a first comonomer comprising sulfonic acid groups. The modified polyvinyl alcohol resin has a hydroxyl unit content of at least 65 mol % and a gel fraction of 3.2 or less. Further, the modified polyvinyl alcohol resin has a disintegration time of 85 seconds or less, as measured in a mixture of 50 vol % water and 50 vol % isopropyl alcohol at 23° C. Additionally, the modified polyvinyl alcohol resin has a hard component present in a component ratio of 10% or greater and 55% or less and having a relaxation time of 0.0091 milliseconds or greater and 0.0104 milliseconds or less, as measured by the pulsed NMR Solid Echo method at 80° C. Also disclosed are methods for producing the sulfonic acid modified polyvinyl alcohol resins, which may advantageously be used in inks, paints, paper coatings, emulsions, or films.
IPC Classes ?
- C08F 216/06 - Polyvinyl alcohol
- C09D 5/02 - Emulsion paints
- C09D 129/04 - Polyvinyl alcoholPartially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
- C09D 11/106 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D 11/023 - Emulsion inks
|
9.
|
MODIFIED POLYVINYL ALCOHOL RESIN WITH IMPROVED SOLUBILITY IN ALCOHOL MIXTURES
Application Number |
US2023010810 |
Publication Number |
2023/137185 |
Status |
In Force |
Filing Date |
2023-01-13 |
Publication Date |
2023-07-20 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Sawa, Kazuhiro
- Vicari, Richard
|
Abstract
A sulfonic acid modified polyvinyl alcohol resin comprising up to 15 mol% of a first comonomer comprising sulfonic acid groups. The modified polyvinyl alcohol resin has a hydroxyl unit content of at least 65 mol% and a gel fraction of 3.2 or less. Further, the modified polyvinyl alcohol resin has a disintegration time of 85 seconds or less, as measured in a mixture of 50 vol% water and 50 vol% isopropyl alcohol at 23°C. Additionally, the modified polyvinyl alcohol resin has a hard component present in a component ratio of 10% or greater and 55% or less and having a relaxation time of 0.0091 milliseconds or greater and 0.0104 milliseconds or less, as measured by the pulsed NMR Solid Echo method at 80°C. Also disclosed are methods for producing the sulfonic acid modified polyvinyl alcohol resins, which may advantageously be used in inks, paints, paper coatings, emulsions, or films.
IPC Classes ?
- C08F 216/06 - Polyvinyl alcohol
- C08F 218/08 - Vinyl acetate
- C09D 129/04 - Polyvinyl alcoholPartially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
|
10.
|
Vinyl alcohol polymer and method for producing vinyl alcohol polymer
Application Number |
17417589 |
Grant Number |
12084526 |
Status |
In Force |
Filing Date |
2019-12-26 |
First Publication Date |
2022-02-24 |
Grant Date |
2024-09-10 |
Owner |
- SEKISUI CHEMICAL CO., LTD. (Japan)
- Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Nishimura, Yohei
- Niino, Junichi
- Kusaka, Yasunari
- Nakajima, Nami
- Yamaguchi, Hidehiro
|
Abstract
(e) integral value of peak confirmed at 7.82 to 8.04 ppm.
|
11.
|
VINYL ALCOHOL POLYMER AND METHOD FOR PRODUCING VINYL ALCOHOL POLYMER
Application Number |
JP2019051248 |
Publication Number |
2020/138341 |
Status |
In Force |
Filing Date |
2019-12-26 |
Publication Date |
2020-07-02 |
Owner |
- SEKISUI CHEMICAL CO., LTD. (Japan)
- SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Nishimura, Yohei
- Niino, Junichi
- Kusaka, Yasunari
- Nakajima, Nami
- Yamaguchi, Hidehiro
|
Abstract
A vinyl alcohol polymer according to one embodiment of the present invention has an integral value (e) of from 0.8 to 20 if the total of the integral values (a)-(e) described below is taken as 100 in the 1H-NMR spectrum. (a) the integral value of peaks observed within the range of 5.70-5.96 ppm (b) the integral value of peaks observed within the range of 5.97-6.63 ppm (c) the integral value of peaks observed within the range of 6.64-7.55 ppm (d) the integral value of peaks observed within the range of 7.56-7.81 ppm (e) the integral value of peaks observed within the range of 7.82-8.04 ppm
|
12.
|
PVP COPOLYMER FOR HARSH CHEMICAL PACKAGING
Application Number |
US2019064199 |
Publication Number |
2020/117777 |
Status |
In Force |
Filing Date |
2019-12-03 |
Publication Date |
2020-06-11 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Carrier, Paula
- Nguyen, Vinh
- Pollock, Regan
- Vicari, Richard
|
Abstract
A water soluble film useful in unit-dose chemical packaging is disclosed. The film may include: a water soluble saccharide and a polyvinyl alcohol copolymer consisting essentially of: (a) from 80 to 99 mole percent of vinyl alcohol and vinyl ester monomer; and (b) from 1 to 20 mole percent of a pyrrolidone comonomer. Such compositions may be used to provide a water-soluble film simultaneously satisfying requirements in regard to water solubility, biodegradability, and physical properties, even when used for packaging a broad range of harsh, oxidizing chemicals.
|
13.
|
Polyvinyl alcohol used as dispersing agents for polyvinyl chloride suspension polymerization, dispersing agents comprising the polyvinyl alcohol, and method for producing polyvinyl chloride using the polyvinyl alcohol
Application Number |
15941104 |
Grant Number |
10647791 |
Status |
In Force |
Filing Date |
2018-03-30 |
First Publication Date |
2019-10-03 |
Grant Date |
2020-05-12 |
Owner |
- SEKISUI CHEMICAL CO., LTD. (Japan)
- SEKISUI SPECIALITY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Nishimura, Yohei
- Kusaka, Yasunari
- Nakajima, Nami
- Yamaguchi, Hidehiro
|
Abstract
(b) An integration value from 5.76 to 5.98 ppm of a peak or peaks observed at 5.86 to 5.90 ppm when an integration value from 3.65 to 4.05 ppm of a peak or peaks observed at 3.83 to 3.87 ppm is assumed to be 100.
IPC Classes ?
- C08F 14/06 - Vinyl chloride
- C08F 16/06 - Polyvinyl alcohol
- C08J 3/05 - Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
|
14.
|
POLYVINYL ALCOHOL USED AS DISPERSANT FOR POLYVINYL CHLORIDE SUSPENSION POLYMERIZATION, DISPERSANT CONTAINING SAID POLYVINYL ALCOHOL, AND METHOD FOR PRODUCING POLYVINYL CHLORIDE USING SAID POLYVINYL ALCOHOL
Application Number |
JP2019013715 |
Publication Number |
2019/189625 |
Status |
In Force |
Filing Date |
2019-03-28 |
Publication Date |
2019-10-03 |
Owner |
- SEKISUI CHEMICAL CO., LTD. (Japan)
- SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Nishimura, Yohei
- Kusaka, Yasunari
- Nakajima, Nami
- Yamaguchi, Hidehiro
|
Abstract
The present invention provides a polyvinyl alcohol used as a dispersant for polyvinyl chloride suspension polymerization, the polyvinyl alcohol having a saponification degree of 60-80 mol% and a block character of 0.4-0.6, wherein the value of (a) below is 0.04-0.1 and the value of (b) below is 0.01-0.2 in a 1H-NMR spectrum, and the UV absorbance of a 0.1 mass% aqueous solution at a wavelength of 320 nm is at least 0.18 and less than 0.3. (a) The integral value from 5.42 to 5.62 ppm of peaks identified as 5.50-5.54 ppm when the integral value from 3.65 to 4.05 ppm of peaks identified as 3.83-3.87 ppm is 100. (b) The integral value from 5.76 to 5.98 ppm of peaks identified as 5.86-5.90 ppm when the integral value from 3.65 to 4.05 ppm of peaks identified as 3.83-3.87 ppm is 100.
|
15.
|
PVOH dispersant for VCM polymerization
Application Number |
15555856 |
Grant Number |
10766983 |
Status |
In Force |
Filing Date |
2016-03-04 |
First Publication Date |
2018-02-15 |
Grant Date |
2020-09-08 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Phung, K. Van
- Nishimura, Yohei
- Ando, Tsutomu
- Yamaguchi, Hidehiro
- Iragorri, Joseba Inaki
- Ghorpade, Kaustubh
|
Abstract
Dispersing agents useful in a suspension polymerization process may be formed based on polyvinyl alcohols and processes discloses herein. The dispersing agent may include, for example: a polyvinyl alcohol having a degree of hydrolysis in the range from 60 to 80 mol %; an absorbance of not less than 0.3 measured at a wavelength of 320 nm with respect to a 0.1 wt % aqueous solution of the polyvinyl alcohol; a block character of remaining ester groups in the range from 0.4 to 0.5; and a cloud point in the range from 35° C. to 50° C. measured with respect to a 1 wt % aqueous solution of the polyvinyl alcohol. Carbonyl groups are theorized to be present along the polymer chain, which may be quantified by 1-H NMR spectra peaks.
|
16.
|
Copolymers for improving color intensity and washfastness of temporary hair dyes
Application Number |
15654269 |
Grant Number |
10588846 |
Status |
In Force |
Filing Date |
2017-07-19 |
First Publication Date |
2018-01-25 |
Grant Date |
2020-03-17 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
Wurm, David B.
|
Abstract
A method for dyeing hair includes applying a polyvinyl amine copolymer solution to the hair; and applying a hair dye composition to the hair. A hair dye composition includes an aqueous base fluid; a polyvinyl amine copolymer; and an anionic or cationic hair dye. A method of making a hair dye composition includes mixing a polyvinyl amine copolymer and an anionic or cationic hair dye into an aqueous base fluid.
IPC Classes ?
- A61Q 5/10 - Preparations for permanently dyeing the hair
- A61K 8/81 - Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61Q 5/06 - Preparations for styling the hair, e.g. by temporary shaping or colouring
|
17.
|
STABILIZER FOR AGGRESSIVE CHEMICALS PACKAGING
Application Number |
US2016050195 |
Publication Number |
2017/040991 |
Status |
In Force |
Filing Date |
2016-09-02 |
Publication Date |
2017-03-09 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Vicari, Richard
- Pollock, Regan
|
Abstract
Water soluble films and coatings herein address the problem of water insolubility, color formation, and brittleness upon exposure to oxidizing chemicals, including strong or aggressive oxidizing chemicals. The water soluble films or coatings may include a water soluble polymer and a reactive precursor, such as an alkanolamine or an alkyl alkanolamine. The reactive precursor is water soluble and reactive with oxidizing compounds. Water soluble films or coatings herein may also include a water soluble polymer and an additive mixture including an alkanolamine or an alkyl alkanolamine. The films or coatings, upon exposure to an oxidizing chemical for 8 weeks at 40°C and ambient humidity, may dissolve fully or achieve 90% dissolution at times of less than 10 minutes. The water soluble films and coatings may advantageously be used with oxidizing chemicals while maintaining water solubility, acceptable color, and flexibility, such as in unit dose packaging, even over extended exposure periods.
IPC Classes ?
- C09D 7/12 - Other additives
- C09D 129/04 - Polyvinyl alcoholPartially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
- B65D 65/46 - Applications of disintegrable, dissolvable or edible materials
- B65D 85/84 - Containers, packaging elements or packages, specially adapted for particular articles or materials for corrosive chemicals
|
18.
|
Stabilizer for aggressive chemicals packaging
Application Number |
15255814 |
Grant Number |
09796870 |
Status |
In Force |
Filing Date |
2016-09-02 |
First Publication Date |
2017-03-02 |
Grant Date |
2017-10-24 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Vicari, Richard
- Pollock, Regan
|
Abstract
Water soluble films and coatings herein address the problem of water insolubility, color formation, and brittleness upon exposure to oxidizing chemicals, including strong or aggressive oxidizing chemicals. The water soluble films or coatings may include a water soluble polymer and a reactive precursor, such as an alkanolamine or an alkyl alkanolamine. The reactive precursor is water soluble and reactive with oxidizing compounds. Water soluble films or coatings herein may also include a water soluble polymer and an additive mixture including an alkanolamine or an alkyl alkanolamine. The films or coatings, upon exposure to an oxidizing chemical for 8 weeks at 40° C. and ambient humidity, may dissolve fully or achieve 90% dissolution at times of less than 10 minutes. The water soluble films and coatings may advantageously be used with oxidizing chemicals while maintaining water solubility, acceptable color, and flexibility, such as in unit dose packaging, even over extended exposure periods.
IPC Classes ?
- C09D 129/04 - Polyvinyl alcoholPartially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
- B65D 81/24 - Adaptations for preventing deterioration or decay of contentsApplications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D 65/46 - Applications of disintegrable, dissolvable or edible materials
- C09D 7/12 - Other additives
- C09D 5/00 - Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects producedFilling pastes
- B65D 23/02 - Linings or internal coatings
- B65D 25/14 - Linings or internal coatings
- C08K 5/17 - AminesQuaternary ammonium compounds
- B65D 85/84 - Containers, packaging elements or packages, specially adapted for particular articles or materials for corrosive chemicals
- C08K 5/05 - AlcoholsMetal alcoholates
|
19.
|
SELVOL ULTALUX
Application Number |
1326857 |
Status |
Registered |
Filing Date |
2016-10-22 |
Registration Date |
2016-10-22 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
NICE Classes ? |
01 - Chemical and biological materials for industrial, scientific and agricultural use
|
Goods & Services
Polymer base compositions used in the manufacture of goods,
namely, clothing, exercise apparel, compression garments,
home furnishing, cosmetics and personal care preparations.
|
20.
|
ULTILOC
Application Number |
1316043 |
Status |
Registered |
Filing Date |
2016-09-08 |
Registration Date |
2016-09-08 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
NICE Classes ? |
01 - Chemical and biological materials for industrial, scientific and agricultural use
|
Goods & Services
Polymer compositions used in the manufacture of commercial
and industrial goods.
|
21.
|
PVOH DISPERSANT FOR VCM POLYMERIZATION
Application Number |
US2016020799 |
Publication Number |
2016/141256 |
Status |
In Force |
Filing Date |
2016-03-04 |
Publication Date |
2016-09-09 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Phung, K., Van
- Nishimura, Yohei
- Ando, Tsutomu
- Yamaguchi, Hidehiro
- Iragorri, Joseba, Inaki
- Ghorpade, Kaustubh
|
Abstract
Dispersing agents useful in a suspension polymerization process may be formed based on polyvinyl alcohols and processes discloses herein. The dispersing agent may include, for example: a polyvinyl alcohol having a degree of hydrolysis in the range from 60 to 80 mol%; an absorbance of not less than 0.3 measured at a wavelength of 320 nm with respect to a 0.1 wt% aqueous solution of the polyvinyl alcohol; a block character of remaining ester groups in the range from 0.4 to 0.5; and a cloud point in the range from 35°C to 50°C measured with respect to a 1 wt% aqueous solution of the polyvinyl alcohol. Carbonyl groups are theorized to be present along the polymer chain, which may be quantified by 1-H NMR spectra peaks.
IPC Classes ?
- C08J 3/02 - Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08F 16/06 - Polyvinyl alcohol
- C08F 2/18 - Suspension polymerisation
|
22.
|
SELVOL ULTALUX
Serial Number |
87125929 |
Status |
Registered |
Filing Date |
2016-08-03 |
Registration Date |
2017-03-14 |
Owner |
Sekisui Specialty Chemicals America LLC ()
|
NICE Classes ? |
01 - Chemical and biological materials for industrial, scientific and agricultural use
|
Goods & Services
Polymer base compositions used in the manufacture of goods, namely, clothing, exercise apparel, compression garments, home furnishing, cosmetics and personal care preparations
|
23.
|
Water soluble high syndiotactic polyvinyl alcohol
Application Number |
14165241 |
Grant Number |
09354357 |
Status |
In Force |
Filing Date |
2014-01-27 |
First Publication Date |
2014-07-31 |
Grant Date |
2016-05-31 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Nishimura, Yohei
- Pollock, Regan
- Vicari, Richard
|
Abstract
A water soluble polyvinyl alcohol copolymer having a diad syndiotacticity of greater than about 60% and less than about 70%. In some embodiments, the water soluble polyvinyl alcohol copolymer is soluble in water at a concentration of at least 1 wt % at a temperature of less than 100° C. In other embodiments, the composition is soluble in water at a concentration of at least 5 wt % at a temperature in the range from about 90° C. to less than 100° C. The high solubility of the high syndiotactic poly vinyl alcohols disclosed herein may provide various advantages as described herein, including ease of processing and decreased use of harmful solvents.
IPC Classes ?
- C08F 16/06 - Polyvinyl alcohol
- B29D 7/01 - Films or sheets
- G02B 1/08 - Optical elements characterised by the material of which they are madeOptical coatings for optical elements made of polarising materials
- C08F 218/12 - Esters of monocarboxylic acids with unsaturated alcohols containing three or more carbon atoms
|
24.
|
WATER SOLUBLE HIGH SYNDIOTACTIC POLYVINYL ALCOHOL
Application Number |
US2014013177 |
Publication Number |
2014/117077 |
Status |
In Force |
Filing Date |
2014-01-27 |
Publication Date |
2014-07-31 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Nishimura, Yohei
- Pollock, Regan
- Vicari, Richard
|
Abstract
A water soluble polyvinyl alcohol copolymer having a diad syndiotacticity of greater than about 60% and less than about 70%. In some embodiments, the water soluble polyvinyl alcohol copolymer is soluble in water at a concentration of at least 1 wt% at a temperature of less than 100°C. In other embodiments, the composition is soluble in water at a concentration of at least 5 wt% at a temperature in the range from about 90°C to less than 100°C. The high solubility of the high syndiotactic poly vinyl alcohols disclosed herein may provide various advantages as described herein, including ease of processing and decreased use of harmful solvents.
|
25.
|
PVOH COPOLYMERS FOR PERSONAL CARE APPLICATIONS
Application Number |
US2013074429 |
Publication Number |
2014/093507 |
Status |
In Force |
Filing Date |
2013-12-11 |
Publication Date |
2014-06-19 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Wurm, David
- Grissom, Christa
- Vicari, Richard
|
Abstract
Various cosmetic compositions are disclosed that may be useful in face masks, epilatories, and pore strips. All the claimed compositions comprise a polyvinyl alcohol copolymer. Also disclosed is a method of designing a cosmetic composition that may include: receiving a request to tailor a cosmetic composition to have a selected property or a selected property set. The method may be used to design and manufacture cosmetic compositions, such as epilatory compositions, face or skin care mask compositions used for cleansing and/or exfoliating the skin, and eyeliners, among others, having advantageous properties.
IPC Classes ?
- A61K 8/34 - Alcohols
- A61Q 19/00 - Preparations for care of the skin
- A61K 8/81 - Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61Q 19/04 - Preparations for care of the skin for chemically tanning the skin
- A61K 8/86 - Polyethers
- A61K 8/02 - Cosmetics or similar toiletry preparations characterised by special physical form
|
26.
|
PVOH COPOLYMERS FOR PERSONAL CARE APPLICATIONS
Application Number |
US2013074431 |
Publication Number |
2014/093509 |
Status |
In Force |
Filing Date |
2013-12-11 |
Publication Date |
2014-06-19 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Wurm, David
- Grissom, Christa
- Vicari, Richard
|
Abstract
Epilatory compositions may be formed from: 40 to 80 wt% water; 5 to 30 wt% of a mixture of at least one polyvinyl alcohol and at least one polyvinyl alcohol copolymer; 1 to 15 wt% plasticizer, where the plasticizer is a linear or branched composition having from 3 to 15 wt% OH; and up to 40 wt% of one or more additives. Pore strip, keratonic plug removal, and other cosmetic applications may be formed from a similar composition, where the plasticizer is a linear, cyclic, or branched composition having greater than 25 wt% OH; and up to 40 wt% of one or more additives. The adhesive properties of the formulations may be tailored, where a low OH content may result in increased adhesion relative to plasticizers having a high OH content.
IPC Classes ?
- A61K 8/34 - Alcohols
- A61Q 19/00 - Preparations for care of the skin
- A61K 8/81 - Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61Q 19/04 - Preparations for care of the skin for chemically tanning the skin
- A61K 8/86 - Polyethers
- A61K 8/02 - Cosmetics or similar toiletry preparations characterised by special physical form
|
27.
|
PVOH copolymers for personal care applications
Application Number |
14103449 |
Grant Number |
09271920 |
Status |
In Force |
Filing Date |
2013-12-11 |
First Publication Date |
2014-06-12 |
Grant Date |
2016-03-01 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Wurm, David
- Grissom, Christa
- Vicari, Richard
|
Abstract
Epilatory compositions may be formed from: 40 to 80 wt % water; 5 to 30 wt % of a mixture of at least one polyvinyl alcohol and at least one polyvinyl alcohol copolymer; 1 to 15 wt % plasticizer, where the plasticizer is a linear or branched composition having from 3 to 15 wt % OH; and up to 40 wt % of one or more additives. Pore strip, keratonic plug removal, and other cosmetic applications may be formed from a similar composition, where the plasticizer is a linear, cyclic, or branched composition having greater than 25 wt % OH; and up to 40 wt % of one or more additives. The adhesive properties of the formulations may be tailored, where a low OH content may result in increased adhesion relative to plasticizers having a high OH content.
IPC Classes ?
- A61K 8/81 - Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61Q 1/10 - Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
- A61Q 19/00 - Preparations for care of the skin
- A61Q 9/00 - Preparations for removing hair or for aiding hair removal
- G06Q 30/06 - Buying, selling or leasing transactions
- A61K 8/34 - Alcohols
- A61K 8/02 - Cosmetics or similar toiletry preparations characterised by special physical form
|
28.
|
PVP COPOLYMER FOR HARSH CHEMICAL PACKAGING
Document Number |
02888799 |
Status |
In Force |
Filing Date |
2013-10-22 |
Open to Public Date |
2014-05-01 |
Grant Date |
2020-04-07 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC. (USA)
|
Inventor |
- Carrier, Paula
- Nguyen, Vinh
- Pollock, Regan
- Vicari, Richard
|
Abstract
A water soluble film useful in unit-dose chemical packaging is disclosed. The film may include: a water soluble saccharide and a polyvinyl alcohol copolymer consisting essentially of: (a) from 80 to 99 mole percent of vinyl alcohol and vinyl ester monomer; and (b) from 1 to 20 mole percent of a pyrrolidone comonomer. Such compositions may be used to provide a water-soluble film simultaneously satisfying requirements in regard to water solubility, biodegradability, and physical properties, even when used for packaging of harsh, oxidizing chemicals.
IPC Classes ?
- B65D 65/46 - Applications of disintegrable, dissolvable or edible materials
- B65D 85/84 - Containers, packaging elements or packages, specially adapted for particular articles or materials for corrosive chemicals
- C08K 5/151 - Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K 5/1545 - Six-membered rings
- C08L 29/04 - Polyvinyl alcoholPartially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
- C08L 33/26 - Homopolymers or copolymers of acrylamide or methacrylamide
- C08L 39/06 - Homopolymers or copolymers of N-vinyl-pyrrolidones
|
29.
|
PVP COPOLYMER FOR HARSH CHEMICAL PACKAGING
Application Number |
US2013066103 |
Publication Number |
2014/066339 |
Status |
In Force |
Filing Date |
2013-10-22 |
Publication Date |
2014-05-01 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC. (USA)
|
Inventor |
- Carrier, Paula
- Nguyen, Vinh
- Pollock, Regan
- Vicari, Richard
|
Abstract
A water soluble film useful in unit-dose chemical packaging is disclosed. The film may include: a water soluble saccharide and a polyvinyl alcohol copolymer consisting essentially of: (a) from 80 to 99 mole percent of vinyl alcohol and vinyl ester monomer; and (b) from 1 to 20 mole percent of a pyrrolidone comonomer. Such compositions may be used to provide a water-soluble film simultaneously satisfying requirements in regard to water solubility, biodegradability, and physical properties, even when used for packaging of harsh, oxidizing chemicals.
IPC Classes ?
- B65D 65/46 - Applications of disintegrable, dissolvable or edible materials
- B65D 85/84 - Containers, packaging elements or packages, specially adapted for particular articles or materials for corrosive chemicals
- C08K 5/151 - Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K 5/1545 - Six-membered rings
- C08L 29/04 - Polyvinyl alcoholPartially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
- C08L 33/26 - Homopolymers or copolymers of acrylamide or methacrylamide
- C08L 39/06 - Homopolymers or copolymers of N-vinyl-pyrrolidones
|
30.
|
PVP copolymer for harsh chemical packaging
Application Number |
14060051 |
Grant Number |
10144810 |
Status |
In Force |
Filing Date |
2013-10-22 |
First Publication Date |
2014-04-24 |
Grant Date |
2018-12-04 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Carrier, Paula
- Nguyen, Vinh
- Pollock, Regan
- Vicari, Richard
|
Abstract
A water soluble film useful in unit-dose chemical packaging is disclosed. The film may include: a water soluble saccharide and a polyvinyl alcohol copolymer consisting essentially of: (a) from 80 to 99 mole percent of vinyl alcohol and vinyl ester monomer; and (b) from 1 to 20 mole percent of a pyrrolidone comonomer. Such compositions may be used to provide a water-soluble film simultaneously satisfying requirements in regard to water solubility, biodegradability, and physical properties, even when used for packaging of harsh, oxidizing chemicals.
IPC Classes ?
- C08J 5/18 - Manufacture of films or sheets
- B65D 85/84 - Containers, packaging elements or packages, specially adapted for particular articles or materials for corrosive chemicals
- B65D 65/46 - Applications of disintegrable, dissolvable or edible materials
- C08L 29/04 - Polyvinyl alcoholPartially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
- C08K 5/151 - Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K 5/1545 - Six-membered rings
- C08L 39/06 - Homopolymers or copolymers of N-vinyl-pyrrolidones
|
31.
|
COLD WATER SOLUBLE POLYVINYL ALCOHOL/ALKYL ACRYLATE COPOLYMERS AND FILMS THEREOF
Application Number |
US2011065473 |
Publication Number |
2012/087821 |
Status |
In Force |
Filing Date |
2011-12-16 |
Publication Date |
2012-06-28 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Vicari, Richard
- Hann, Bret
|
Abstract
Cold water-soluble PVOH/alkyI acrylate copolymers are provided with a substantially random distribution of monomers which is reflected in the polymer's cold water solubility, GPEC chromatograms and may be confirmed by C13 NMR. The product is particularly useful for films used in packaging and for encapsulating particulate products. Encapsulated products which may be provided include fertilizer or other agricultural products, pharmaceutical products, biomedical products and cosmetic products.
IPC Classes ?
- C08F 218/08 - Vinyl acetate
- C08F 220/18 - Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
|
32.
|
SELVOL
Application Number |
1092661 |
Status |
Registered |
Filing Date |
2011-09-01 |
Registration Date |
2011-09-01 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
NICE Classes ? |
01 - Chemical and biological materials for industrial, scientific and agricultural use
|
Goods & Services
Polyvinyl alcohols for use in the manufacture of paper,
adhesives, fiber, textiles, textile treatments, ceramics,
joint compounds, tile mortars, textured coatings, extruded
plastic film, furniture, contact lenses, dispersants,
stabilizers, emulsifiers, and release coatings.
|
33.
|
SELVOL
Serial Number |
85406921 |
Status |
Registered |
Filing Date |
2011-08-25 |
Registration Date |
2013-04-09 |
Owner |
Sekisui Specialty Chemicals America, LLC ()
|
NICE Classes ? |
01 - Chemical and biological materials for industrial, scientific and agricultural use
|
Goods & Services
Polyvinyl alcohols for use in the manufacture of paper, adhesives, fiber, textiles, textile treatments, ceramics, joint compounds, tile mortars, textured coatings, extruded plastic film, furniture, contact lenses, dispersants, stabilizers, emulsifiers, and release coatings
|
34.
|
Polyvinyl alcohol films with improved resistance to oxidizing chemicals
Application Number |
12800576 |
Grant Number |
08728593 |
Status |
In Force |
Filing Date |
2010-05-18 |
First Publication Date |
2010-09-16 |
Grant Date |
2014-05-20 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Vicari, Richard
- Hann, Bret F.
|
Abstract
A water-soluble film which comprises a saccharide component and a vinyl alcohol resin component, where the vinyl alcohol resin may include functional comonomer units such as sulfonic acid functional groups or salts thereof. Preferred are polyvinyl alcohol/2-methylacrylamido-2 methyl propane sulfonic acid resins (PVOH/AMPS) which may be purchased commercially with relatively higher or relatively lower characteristic viscosity. The films exhibit superior resistance to aggressive oxidizing chemicals and remain soluble in water after prolonged exposure thereto. The films are particularly useful for unit-dose packaging of chlorine-containing pool chemicals, such as trichloroisocyanuric acid.
|
35.
|
IMPROVED NVF COPOLYMER PROCESS
Application Number |
US2009005098 |
Publication Number |
2010/030372 |
Status |
In Force |
Filing Date |
2009-09-11 |
Publication Date |
2010-03-18 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA LLC (USA)
|
Inventor |
- Vicari, Richard
- Barsan, Florin
- Phung, Kien, Van
|
Abstract
Disclosed herein is a water-soluble copolymer formed by copolymerizing N-vinylformamide and one or more vinyl C1-C10 alkyl esters, and then hydrolyzing from 30 to 100 mol% of the formyl groups from the copolymerized units to form amino groups and from 30 to 100 mol% of the C1-C10 alkyl ester groups from the copolymerized units to form hydroxyl groups, wherein the copolymer has a unimodal molecular weight distribution as evidenced by essentially one peak in a gel permeation gradient elution chromatographic analysis. A process to produce the polymer is also disclosed.
|
36.
|
IMPROVED BARRIER LAYER
Application Number |
US2009005097 |
Publication Number |
2010/030371 |
Status |
In Force |
Filing Date |
2009-09-11 |
Publication Date |
2010-03-18 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA LLC (USA)
|
Inventor |
- Brondsema, Philip, J.
- Coulson, Nancy, S.
- Cupta, Mark, G.
- Vicari, Richard
|
Abstract
Disclosed herein is a barrier layer comprising a polyvinyl amine-polyvinyl alcohol copolymer applied to a substrate as a water-soluble composition, wherein the polyvinyl amine- polyvinyl alcohol copolymer is formed by copolymerizing: (a) from 99 to 1 mol% of N-vinylformamide and (b) from 1 to 99 mol% of one or more vinyl Ci-Ci0 alkyl esters, and then hydrolyzing from 30 to 100 mol% of the formyl groups from the copolymerized units (a) to form amino groups and from 30 to 100 mol% of the Cj-Cio alkyl ester groups from the copolymerized units (b) to form hydroxyl groups, wherein the copolymer has a unimodal compositional distribution as evidenced by essentially one peak in a gel permeation gradient elution chromatographic analysis. A method of producing a barrier layer is also disclosed.
IPC Classes ?
- C08F 8/12 - Hydrolysis
- B32B 27/00 - Layered products essentially comprising synthetic resin
- C09D 129/04 - Polyvinyl alcoholPartially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
- C09D 139/04 - Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
|
37.
|
PERSONAL CARE PRODUCTS
Application Number |
US2009053704 |
Publication Number |
2010/019766 |
Status |
In Force |
Filing Date |
2009-08-13 |
Publication Date |
2010-02-18 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC. (USA)
|
Inventor |
- Ybarra, Arnold
- Eicken, Dalia
- Nguyen, Vinh
- Vicari, Richard
- Coulson, Jeffrey, Paul
- Brondsema, Philip, Joel
- Nunez De Arce, Patricia
|
Abstract
A hair care product comprising water, a chelating agent, a copolymer, a pH adjusting agent and a hair treatment composition including a polyvinyl alcohol, polyvinyl alcohol copolymer, vinyl acetate emulsion, acrylic emulsion, vinyl acrylic emulsion, vinyl acetate copolymer emulsion or a combination thereof.
IPC Classes ?
- A61K 8/00 - Cosmetics or similar toiletry preparations
|
38.
|
PROCESS FOR MAKING LOW COLOR POLYVINYL ALCOHOL
Application Number |
US2008013929 |
Publication Number |
2009/142616 |
Status |
In Force |
Filing Date |
2008-12-19 |
Publication Date |
2009-11-26 |
Owner |
SEKISUI SPECIALTY CHEMICALS AMERICA, LLC (USA)
|
Inventor |
- Barsan, Florin
- Thompson, Jeffrey, Hunt
- Phung, Kien, Van
|
Abstract
A process is provided for the manufacture of polyvinyl alcohol, having an APHA color of equal to or less than about 10, by polymerizing a vinyl acetate monomer to form polyvinyl acetate and then hydrolyzing the polyvinyl acetate to form polyvinyl alcohol wherein the vinyl acetate monomer is characterized as having an inhibitor level of equal to or less than about 10 ppm, preferably less than about 5 ppm, more preferably less than about 3 ppm, even more preferably less than about 1 ppm.
IPC Classes ?
- B32B 17/00 - Layered products essentially comprising sheet glass, or fibres of glass, slag or the like
- C07C 67/055 - Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
- C08F 8/12 - Hydrolysis
- C08F 16/08 - Allyl alcohol
|
39.
|
ULTILOC
Application Number |
1002467 |
Status |
Registered |
Filing Date |
2009-04-30 |
Registration Date |
2009-04-30 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
NICE Classes ? |
- 01 - Chemical and biological materials for industrial, scientific and agricultural use
- 17 - Rubber and plastic; packing and insulating materials
|
Goods & Services
Polymer compositions used in the manufacture of commercial
and industrial goods. Plastic film for commercial and industrial use.
|
40.
|
Chemical delivery product and process for making the same
Application Number |
11844464 |
Grant Number |
08772220 |
Status |
In Force |
Filing Date |
2007-08-24 |
First Publication Date |
2009-02-26 |
Grant Date |
2014-07-08 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Vicari, Richard
- Wang, Hang
- Hann, Bret
|
Abstract
A chemical delivery product for delivering an oxidizing chemical into an aqueous system is disclosed. For instance, in one embodiment, a substrate containing an oxidizing chemical, such as trichloroisocyanuric acid, is coated with a water soluble polymer in order to prevent the oxidizing chemical from degrading prior to use and in order to facilitate handling. In accordance with the present disclosure, a neutralizing agent is contacted with the substrate in order to prevent the substrate from degrading the water soluble coating. In an alternative embodiment, a package is formed from a water soluble film forming composition combined with a base.
IPC Classes ?
- C11D 7/28 - Organic compounds containing halogen
|
41.
|
Polyvinyl alcohol films with improved resistance to oxidizing chemicals
Application Number |
11415768 |
Grant Number |
07745517 |
Status |
In Force |
Filing Date |
2006-05-02 |
First Publication Date |
2007-11-08 |
Grant Date |
2010-06-29 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
Inventor |
- Vicari, Richard
- Hann, Bret F.
|
Abstract
A water-soluble film which comprises a saceharide component and a vinyl alcohol resin component, where the vinyl alcohol resin may include functional comonomer units such as sulfonic acid functional groups or salts thereof. Preferred are polyvinyl alcohol/2-methylacrylamido-2 methyl propane sulfonic acid resins (PVOH/AMPS) which may be purchased commercially with relatively higher or relatively lower characteristic viscosity. The films exhibit superior resistance to aggressive oxidizing chemicals and remain soluble in water after prolonged exposure thereto. The films are particularly useful for unit-dose packaging of chlorine-containing pool chemicals, such as trichloroisocyanuric acid.
IPC Classes ?
- C08L 5/00 - Compositions of polysaccharides or of their derivatives not provided for in group or
|
42.
|
PREMIOL
Application Number |
873033 |
Status |
Registered |
Filing Date |
2005-11-22 |
Registration Date |
2005-11-22 |
Owner |
Sekisui Specialty Chemicals America, LLC (USA)
|
NICE Classes ? |
01 - Chemical and biological materials for industrial, scientific and agricultural use
|
Goods & Services
Chemicals for use in oilfield applications.
|
|